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27744507693
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note
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3I was found to be reversible.
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11
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27744466289
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note
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This complex has been characterized crystallographically: see the Supporting Information.
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12
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37049106100
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(a) Appleton, T. G.; Bennett, M. A.; Tomkins, B. J. Chem. Soc., Dalton Trans. 1976, 439.
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Zahl, A.1
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27744481135
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See the Supporting Information
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See the Supporting Information.
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16
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27744474038
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note
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1H NMR data can be found in the Supporting Information.
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17
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0000604488
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SIR-92-Program Package for Solvine Crystal Structures by Direct Methods
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Altomare, A.; Cascarano, G.; Giacovazzo, C.; Gagliardi, A.; Burla, M. C.; Polidori, G.; Cavalli, M. SIR-92-Program Package for Solvine Crystal Structures by Direct Methods. J. Appl. Crystallogr. 1994, 27, 435.
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18
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0004150157
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University of Göttingen: Göttingen, Germany
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Sheldrick, G. M. SHELXL-97; University of Göttingen: Göttingen, Germany, 1997.
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Sheldrick, G.M.1
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22
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27744564071
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note
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The NMR data for 2a is in the Supporting Information.
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23
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27744550967
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note
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See the Supporting Information for a complete listing of bond lengths and angles, atomic coordinates, and displacement parameters.
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24
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0003197770
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3(OTf)]. Hill, G. S.; Yap, G. P. A.; Puddephatt, R. J. Organometallics 1999, 18, 1408.
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Hill, G.S.1
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0001445415
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Drljaca, A.; Hubbard, C. D.; van Eldik, R. Chem. Rev. 1998, 98, 2167.
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0000853446
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-1: Venter, J. A.; Leipoldt, J. G.; van Eldik, R. Inorg. Chem. 1991, 30, 2207.
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27
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27744591384
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note
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2 calculated according to eq 3 from the slope of the concentration dependence at different temperatures (Figure S5a in the Supporting Information) were found to be within the error range of those calculated for the selected pyridine concentration in Figure 5a (see Figure S2 and Table S14 in the Supporting Information).
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28
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27744529160
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note
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6), can be attributed to the low solubility of the starting complex.
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-
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33
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27744514176
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see ref 21, p 213
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BH+) = 8.47 at 25°C in a mixture of 50% ethanol and water is quite different; see ref 21, p 213.
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34
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33847088851
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A related five-coordinate silyl(dihydrido)platinum(IV) complex has also been structurally characterized: Reinartz, S.; White, P.; Brookhart, M.; Templeton, J. L. J. Am. Chem. Soc. 2001, 123, 6425.
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