Reaction of a palladium(II) complex chelated by a tridentate PNC ligand with water to produce a [(PN)Pd(μ-OH)]22+ dimer: A rare observation of a well-defined hydrolysis of a Pd(II)-aryl compound

Organometallics

Volumn 20, Issue 12, 2001, Pages 2545-2551

  Getty, April D ^a   Goldberg, Karen I ^a  

^a UNIVERSITY OF WASHINGTON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ABSTRACTION; DIBENZYLIDENEACETONE; ELEMENTAL ANALYSIS; HYDROCARBYL GROUP; METAL BOUND ARYL GROUP; PROTONATION; TRIDENTATE LIGAND;

ACETONE; BENZENE; CHEMICAL ANALYSIS; CHEMICAL BONDS; COMPLEXATION; CONDENSATION REACTIONS; DIMERS; HYDROLYSIS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; WATER; X RAY CRYSTALLOGRAPHY;

ORGANOMETALLICS;

EID: 0035844923     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om001030d     Document Type: Article

References (39)

1. (a) Bryndza, H. E.; Tam, W. Chem. Rev. 1988, 88, 1163.
2. Fryzuk, M. D.; Montgomery, C. D. Coord. Chem. Rev. 1989, 95, 1.
3. Roundhill, D. M. Chem. Rev. 1992, 92, 1.
4. (d) Bergman, R. G. Polyhedron 1995, 14, 3227.
5. (a) Deeming, A. J.; Johnson, B. F. G.; Lewis, J. J. Chem. Soc., Dalton Trans. 1973, 1848.
6. (b) Bennett, M. A.; Robertson, G. B.; Whimp, P. O.; Yoshida, T. J. Am. Chem. Soc. 1973, 95, 3028.
7. (c) Bennett, M. A.; Yoshida, T. J. Am. Chem. Soc. 1978, 100, 1750.
8. (d) Bennett, M. A.; Rokicki, A. Aust. J. Chem. 1985, 38, 1307.
9. (e) Paterniti, D. P.; Atwood, J. D. Chem. Commun. 1997, 1665.
10. (f) Paterniti, D. P.; Atwood, J. D. Polyhedron 1998, 17, 1177.
11. (a) Ganguly, S.; Roundhill, D. M. J. Chem. Soc., Chem. Commun. 1991, 639.
12. (b) Ganguly, S.; Roundhill, D. M. Organometallics 1993, 12, 4825.
13. For preparation of phosphine-containing ligands by Schiff base condensation see: Lavery, A.; Nelson, S. M. J. Chem. Soc., Dalton Trans. 1984, 615.
14. Rülke, R. E.; Kaasjager, V. E.; Wehman, P.; Elsevier, C. J.; van Leeuwen, P. W. N. M.; Vrieze, K. Organometallics 1996, 15, 3022.
15. Details of the X-ray crystal structure determination are provided in the Supporting Information.
16. Examples of Pd-μ-OH dimers that contain phosphine or nitrogen ligands in which the crystal structure has been determined: (a) Pisano, C.; Consiglio, G.; Sironi, A.; Moret, M. J. Chem. Soc., Chem. Commun. 1991, 421.
17. (b) Grushin, V. V.; Alper, H. Organometallics 1993, 12, 1890.
18. (c) Pieri, G.; Pasquali, M.; Leoni, P.; Engleert, U. J. Organomet. Chem. 1995, 491, 27.
19. (d) Ruiz, J.; Cutillas, N.; Sampedro, J.; Lopez, G.; Hermoso, J. A.; Martinez-Ripoll, M. J. Organomet. Chem. 1996, 526, 67.
20. (e) Fujii, A.; Hagiwara, E.; Sodeoka, M. J. Am. Chem. Soc. 1999, 121, 5450.
21. (a) Bushnell, G. W.; Dixon, K. R.; Hunter, R. G.; McFarland, J. J. Can. J. Chem. 1972, 50, 3694.
22. (b) Wimmer, S.; Castan, P.; Wimmer, F. L.; Johnson, N. P. J. Chem. Soc., Dalton Trans. 1989, 403.
23. (c) Lopez, G.; Ruiz, J.; Garcia, G.; Vicente, C.; Marti, J. M.; Santana, M. D. J. Orgamomet. Chem. 1990, 393, C53.
24. (d) Lopez, G.; Ruiz, J.; Garcia, G.; Marti, J. M.; Sanchez, G.; Garcia, J. J. Organomet. Chem. 1991, 412, 435.
25. (e) Lopez, G.; Ruiz, J.; Garcia, G.; Vicente, C.; Casabo, J.; Molins, E.; Miravitlles, C. Inorg. Chem. 1991, 30, 2605.
26. (f) Strukul, G.; Varagnolo, A.; Pinna, F. J. Mol. Catal. A 1997, 117, 413.
27. (g) Gavagnin, R.; Catalodo, M.; Pinna, F.; Strukul, G. Organometallics 1998, 17, 661.
28. (a) Belluco, U.; Giustiniani, M.; Graziani, M. J. Am. Chem. Soc. 1967, 89, 6494.
29. (b) Stahl, S. S.; Labinger, J. A.; Bercaw, J. E. J. Am. Chem. Soc. 1996, 118, 5961, and references therein.
30. (c) Bennett, B. L.; Hoerter, J. M.; Houlis, J. F.; Roddick, D. M. Organometallics 2000, 19, 615, and references therein.
31. (a) Kegley, S. E.; Schaverien, C. J.; Freudenberger, J. H.; Bergman, R. G.; Nolan, S. P.; Hoff, C. D. J. Am. Chem. Soc. 1987, 109, 6563.
32. (b) Kim, Y.-J.; Osakada, K.; Takenaka, A.; Yamamoto, A. J. Am. Chem. Soc. 1990, 112, 1096.
33. (c) Kapteijn, G. M.; Dervisi, A.; Grove, D. M.; Kooijman, H.; Lakin, M. T.; Spek, A. L.; van Koten, G. J. Am. Chem. Soc. 1995, 117, 10939.
34. (d) Kapteijn, G. M.; Spee, M. P. R.; Grove, D. M.; Kooijman, H.; Spek, A. L.; van Koten, G. Organometallics 1996, 15, 1405.
35. Cotton, F. A.; Wilkinson, G. Advanced Inorganic Chemistry A Comprehensive Text, 4th ed.; Wiley & Sons: New York, 1988; p 104.
36. (a) Driver, M. S.; Hartwig, J. F. J. Am. Chem. Soc. 1996, 118, 4206.
37. (b) Driver, M. S.; Hartwig, J. F. Organometallics 1997, 16, 5706.
38. (c) Ruiz, J.; Rodriguez, V.; Lopez, G.; Casabo, J.; Molins, E.; Miravitlles, C. Organometallics 1999, 18, 1177.
39. (d) Li, J. J.; Li, W.; James, A. J.; Holbert, T.; Sharp, T.; Sharp, P. R. Inorg. Chem. 1999, 38, 1563.