Phenylpyruvate tautomerase activity of trans-3-chloroacrylic acid dehalogenase: Evidence for an enol intermediate in the dehalogenase reaction?

Biochemistry

Volumn 46, Issue 33, 2007, Pages 9596-9604

  Poelarends, Gerrit J ^a   Johnson Jr , William H ^b   Serrano, Hector ^b   Whitman, Christian P ^b  

^a UNIVERSITY OF GRONINGEN   (Netherlands)

^b UNIVERSITY OF TEXAS AT AUSTIN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ENZYMATIC CONVERSION; HYDROLYTIC DEHALOGENASES; PARTIAL REACTIONS; PHENYLPYRUVATE TAUTOMERASE (PPT) ACTIVITY;

ACRYLICS; ALDEHYDES; BACTERIA; BIOCONVERSION; DEGRADATION; ISOMERS; PROPYLENE;

ENZYME ACTIVITY;

3 CHLOROACRYLATE; 3 CHLOROACRYLIC ACID DEHALOGENASE; ACRYLIC ACID DERIVATIVE; ISOMERASE; MACROPHAGE MIGRATION INHIBITION FACTOR; MALONIC ACID; MUTANT PROTEIN; PHENYLPYRUVATE TAUTOMERASE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; DEHALOGENATION; ENZYME ACTIVE SITE; ENZYME ACTIVITY; ENZYME MECHANISM; NONHUMAN; PRIORITY JOURNAL; STEREOCHEMISTRY; STEREOSPECIFICITY;

ACRYLATES; ANIMALS; BINDING SITES; CATALYSIS; HYDROLASES; INTRAMOLECULAR OXIDOREDUCTASES; KINETICS; MACROPHAGE MIGRATION-INHIBITORY FACTORS; MUTATION; PHENYLPYRUVIC ACIDS; STEREOISOMERISM; SUBSTRATE SPECIFICITY;

BACTERIA (MICROORGANISMS); EUKARYOTA;

EID: 34548090241     PISSN: 00062960     EISSN: None     Source Type: Journal    
DOI: 10.1021/bi7007189     Document Type: Article

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