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Volumn 46, Issue 16, 2007, Pages 6252-6260

Synthesis, luminescence, and electrochemical studies of tris(homoleptic) ruthenium(ll) and osmium(ll) complexes of 6′-tolyl-2,2′:4′, 2″-terpyridine

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EID: 34548051373     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0700093     Document Type: Article
Times cited : (16)

References (160)
  • 8
    • 0002014982 scopus 로고    scopus 로고
    • For a review on electronic absorption spectra of charge transfer states of transition metal complexes, see ref 2a. UV light absorption by these complexes is dominated by intense ligand-centered π-π* bands and in the visible region by MLCT bands.2b-e (a) Brunschwig, B. S, Creutz, C, Sutin, N. Coord. Chem. Rev. 1998, 177, 61-79
    • 2b-e (a) Brunschwig, B. S.; Creutz, C.; Sutin, N. Coord. Chem. Rev. 1998, 177, 61-79.
  • 13
    • 57249085642 scopus 로고    scopus 로고
    • For an excellent account of the design principles of polypyridine complexes of Ru(II) for manipulating the properties of MLCT excited states, see: Anderson, P. A.; Keene, F. R.; Meyer, T. J.; Moss, J. A.; Strouse, G. F.; Treadway, J. A. J. Chem. Soc., Dalton Trans. 2002, 3820-3831.
    • (a) For an excellent account of the design principles of polypyridine complexes of Ru(II) for manipulating the properties of MLCT excited states, see: Anderson, P. A.; Keene, F. R.; Meyer, T. J.; Moss, J. A.; Strouse, G. F.; Treadway, J. A. J. Chem. Soc., Dalton Trans. 2002, 3820-3831.
  • 20
    • 0032178285 scopus 로고    scopus 로고
    • For a review on solvent effects on MLCT excitation, see
    • (h) For a review on solvent effects on MLCT excitation, see: Hush, N. S.; Reimers, J. R. Coord. Chem. Rev. 1998, 177, 37-60.
    • (1998) Coord. Chem. Rev , vol.177 , pp. 37-60
    • Hush, N.S.1    Reimers, J.R.2
  • 25
    • 0032178344 scopus 로고    scopus 로고
    • For a review on the photoreactivity of MLCT excited states, see
    • For a review on the photoreactivity of MLCT excited states, see: Vogler, A.; Kunkely, H. Coord. Chem. Rev. 1998, 177, 81-96.
    • (1998) Coord. Chem. Rev , vol.177 , pp. 81-96
    • Vogler, A.1    Kunkely, H.2
  • 32
    • 0003837875 scopus 로고
    • Balzani, V, De Cola, L, Eds, Kluwer: Dordrecht, Holland
    • (g) Supramolecular Chemistry; Balzani, V., De Cola, L., Eds.; Kluwer: Dordrecht, Holland, 1992.
    • (1992) Supramolecular Chemistry
  • 39
    • 0003666147 scopus 로고
    • Fabbrizzi, L, Poggi, A, Eds, Kluwer: Dordrecht, The Netherlands
    • (n) Transition Metals in Supramolecular Chemistry; Fabbrizzi, L., Poggi, A., Eds.; Kluwer: Dordrecht, The Netherlands, 1994.
    • (1994) Transition Metals in Supramolecular Chemistry
  • 59
    • 34548038551 scopus 로고    scopus 로고
    • Struct. Bonding (Berlin) 2001, 99, 1-281 (special on Molecular Machines and Motors),
    • (c) Struct. Bonding (Berlin) 2001, 99, 1-281 (special volume on "Molecular Machines and Motors"),
  • 63
    • 34548018699 scopus 로고    scopus 로고
    • Stoddart, J. F., Ed. Acc. Chem. Res. 2001, 34, 409-522 (special issue on Molecular Machines).
    • (g) Stoddart, J. F., Ed. Acc. Chem. Res. 2001, 34, 409-522 (special issue on "Molecular Machines").
  • 70
    • 33745492375 scopus 로고    scopus 로고
    • For an excellent account of the optical-based molecular devices and their actions molecular manipulation of information based on optical read-out, see: de
    • (n) For an excellent account of the optical-based molecular devices and their actions (molecular manipulation of information based on optical read-out), see: de Silva, A. P.; McCaughan, B.; McKinney, B. O. F.; Querol, M. Dalton Trans. 2003, 1902-1913.
    • (2003) Dalton Trans , pp. 1902-1913
    • Silva, A.P.1    McCaughan, B.2    McKinney, B.O.F.3    Querol, M.4
  • 71
    • 26944495269 scopus 로고    scopus 로고
    • and references cited therein
    • (a) Gratzel, M. Inorg. Chem. 2005, 44, 6841-6851 and references cited therein,
    • (2005) Inorg. Chem , vol.44 , pp. 6841-6851
    • Gratzel, M.1
  • 72
    • 26944446128 scopus 로고    scopus 로고
    • and references cited therein
    • (b) Meyer, G. J. Inorg. Chem. 2005, 44, 6852-6864 and references cited therein.
    • (2005) Inorg. Chem , vol.44 , pp. 6852-6864
    • Meyer, G.J.1
  • 76
    • 34548019159 scopus 로고    scopus 로고
    • Nazeeruddin, M. K. Ed.; Coord. Chem. Rev. 2004, 248, 1161-1530 (special on Dye Sensitized Solar Cells).
    • (f) Nazeeruddin, M. K. Ed.; Coord. Chem. Rev. 2004, 248, 1161-1530 (special volume on "Dye Sensitized Solar Cells").
  • 79
    • 26944488990 scopus 로고    scopus 로고
    • and references cited therein
    • Hoertz, P. G.; Mallouk, T. E. Inorg. Chem. 2005, 44, 6828-6840 and references cited therein.
    • (2005) Inorg. Chem , vol.44 , pp. 6828-6840
    • Hoertz, P.G.1    Mallouk, T.E.2
  • 85
    • 0032844072 scopus 로고    scopus 로고
    • (b) Coe, B. J. Chem.-Eur. J. 1999, 5, 2464-2471.
    • (1999) Chem.-Eur. J , vol.5 , pp. 2464-2471
    • Coe, B.J.1
  • 100
    • 0003713545 scopus 로고    scopus 로고
    • 3MLCT: (a) Crosby, G. A.; Perkins, W. G.; Klassen, D. M. J. Chem. Phys. 1965, 43, 1498-1503.
    • 3MLCT: (a) Crosby, G. A.; Perkins, W. G.; Klassen, D. M. J. Chem. Phys. 1965, 43, 1498-1503.
  • 102
    • 0001312842 scopus 로고    scopus 로고
    • For an extensive literature on the MLCT excited states, see:, and references cited therein
    • (c) For an extensive literature on the MLCT excited states, see: Treadway, J. A.; Loeb, B.; Lopez, R.; Anderson, P. A.; Keene, F. R.; Meyer, T. J. Inorg. Chem. 1996, 35, 2242-2246 and references cited therein.
    • (1996) Inorg. Chem , vol.35 , pp. 2242-2246
    • Treadway, J.A.1    Loeb, B.2    Lopez, R.3    Anderson, P.A.4    Keene, F.R.5    Meyer, T.J.6
  • 103
    • 0000548599 scopus 로고    scopus 로고
    • For excited-state electronic structures in polypyridine complexes containing unsymmetrical ligands, see:, and references cited therein
    • (d) For excited-state electronic structures in polypyridine complexes containing unsymmetrical ligands, see: Omberg, K. M.; Smith, G. D.; Kavalinuas, D. A.; Chen, P.; Treadway, J. A.; Schoonover, J. R.; Palmer, R. A.; Meyer, T. J. Inorg. Chem. 1999, 38, 951-956 and references cited therein.
    • (1999) Inorg. Chem , vol.38 , pp. 951-956
    • Omberg, K.M.1    Smith, G.D.2    Kavalinuas, D.A.3    Chen, P.4    Treadway, J.A.5    Schoonover, J.R.6    Palmer, R.A.7    Meyer, T.J.8
  • 104
    • 0004122810 scopus 로고    scopus 로고
    • Balzani, V, Ed, Wiley-VCH: Weinheim, Germany, Vols
    • (a) Electron Transfer in Chemistry; Balzani, V., Ed.; Wiley-VCH: Weinheim, Germany, 2001; Vols. 1-5.
    • (2001) Electron Transfer in Chemistry , vol.1-5
  • 109
    • 0000472834 scopus 로고
    • Wilkinson, G, Gillard, R. D, McCleverty, J, Eds, Pergamon: Oxford, England
    • (e) Meyer, T. J.; Taube, H. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J., Eds.; Pergamon: Oxford, England, 1987; Vol. 7, p 331.
    • (1987) Comprehensive Coordination Chemistry , vol.7 , pp. 331
    • Meyer, T.J.1    Taube, H.2
  • 112
    • 0001227498 scopus 로고    scopus 로고
    • Balzani, V, Ed, Wiley-VCH: Weinheim, Germany
    • (h) Gratzel, M.; Moser, J.-E. In Electron Transfer in Chemistry; Balzani, V., Ed.; Wiley-VCH: Weinheim, Germany, 2001; Vol. 5, p 589.
    • (2001) Electron Transfer in Chemistry , vol.5 , pp. 589
    • Gratzel, M.1    Moser, J.-E.2
  • 114
    • 0033815574 scopus 로고    scopus 로고
    • For a review on photochemistry induced by MLCT excitation, see
    • (j) For a review on photochemistry induced by MLCT excitation, see: Vogler, A.; Kunkely, H. Coord. Chem. Rev. 2000, 208, 321-329.
    • (2000) Coord. Chem. Rev , vol.208 , pp. 321-329
    • Vogler, A.1    Kunkely, H.2
  • 115
    • 0002853494 scopus 로고    scopus 로고
    • 6 metal ions having isoenergetic MLCT and ligand localized excited states, see: Baba, A. I.; Shaw, J. R.; Simon, J. A.; Thummel, R. P.; Schmehl, R. H. Coord. Chem. Rev. 1998, 171, 43-59.
    • 6 metal ions having isoenergetic MLCT and ligand localized excited states, see: Baba, A. I.; Shaw, J. R.; Simon, J. A.; Thummel, R. P.; Schmehl, R. H. Coord. Chem. Rev. 1998, 171, 43-59.
  • 145
    • 0037357051 scopus 로고    scopus 로고
    • A variety of terpyridines functionalized at different positions have been reported over the years and reviewed.35a,b For more recent examples of 4′-functionalized terpyridines, see ref 35c. For a review on the coupling of alkynes with bromoterpyridines, see the review by Ziessel. 35d For an account of the common functionalization to the most frequently used 4′-functionalized terpyridines and for recent developments in the supramolecular chemistry of terpyridine-metal complexes, see ref 35e. For a review on the synthesis of terpyridine ligands and their use as building blocks for supramolecular assemblies, see ref 35f. For a review on triads based on bis(tpy) complexes which act as photoactive centers and as electron rely, see, ref 35g. For prolonged luminescence lifetime of Ru(II)-tpy complexes with bichromophoric units, see, ref 35h. For an account of designing functionalized terpyridine ligands for Ru(II) complexes with prolonged room temperat
    • 35J-m (a) Heller, M.; Schubert, U. S. Eur. J. Org. Chem. 2003, 947-961.


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