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For other approaches to the construction of functionalized terpyridine-based metal complexes see a) J.-P. Sauvage, J.-P. Collin, J.-C. Chambron, S. Guillerez, C. Coudret, V. Balzani, F. Barigelletti, L. De Cola, L. Flamigni, Chem. Rev. 1994, 94, 993; b) M. Maestri, N. Armaroli, V. Balzani, E. C. Constable, A. M. W. Cargill Thompson, Inorg. Chem. 1995, 34, 2759; c) F. Barigelletti, L. Flamigni, M. Guardigli, A. Juris, M. Beley, S. Chodorowsky-Kimmes, J.-P. Collin, J.-P. Sauvage, Inorg. Chem. 1996, 35, 136; d) A. Harriman, J.-P. Sauvage, Chem. Soc. Rev. 1996, 41.
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For other approaches to the construction of functionalized terpyridine-based metal complexes see a) J.-P. Sauvage, J.-P. Collin, J.-C. Chambron, S. Guillerez, C. Coudret, V. Balzani, F. Barigelletti, L. De Cola, L. Flamigni, Chem. Rev. 1994, 94, 993; b) M. Maestri, N. Armaroli, V. Balzani, E. C. Constable, A. M. W. Cargill Thompson, Inorg. Chem. 1995, 34, 2759; c) F. Barigelletti, L. Flamigni, M. Guardigli, A. Juris, M. Beley, S. Chodorowsky-Kimmes, J.-P. Collin, J.-P. Sauvage, Inorg. Chem. 1996, 35, 136; d) A. Harriman, J.-P. Sauvage, Chem. Soc. Rev. 1996, 41.
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For other approaches to the construction of functionalized terpyridine-based metal complexes see a) J.-P. Sauvage, J.-P. Collin, J.-C. Chambron, S. Guillerez, C. Coudret, V. Balzani, F. Barigelletti, L. De Cola, L. Flamigni, Chem. Rev. 1994, 94, 993; b) M. Maestri, N. Armaroli, V. Balzani, E. C. Constable, A. M. W. Cargill Thompson, Inorg. Chem. 1995, 34, 2759; c) F. Barigelletti, L. Flamigni, M. Guardigli, A. Juris, M. Beley, S. Chodorowsky-Kimmes, J.-P. Collin, J.-P. Sauvage, Inorg. Chem. 1996, 35, 136; d) A. Harriman, J.-P. Sauvage, Chem. Soc. Rev. 1996, 41.
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0344016171
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note
-
The thermodynamic driving force for light-induced electron transfer from the triplet state of a Ru(terpy)-based chromophore to the central viologen-like acceptor is ΔG° ≈ -0.07 eV, as calculated from the redox potentials with the triplet energy estimated for 2. For subsequent charge recombination. ΔG° ≈ -1.83 eV.
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