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Volumn 121, Issue 26, 1999, Pages 6290-6298

Dendrimers with a photoactive and redox-active [Ru(bpy)3]2+-type core: Photophysical properties, electrochemical behavior, and excited-state electron-transfer reactions

Author keywords

[No Author keywords available]

Indexed keywords

ARTICLE; CHEMICAL COMPOSITION; COMPLEX FORMATION; DRUG SYNTHESIS; ELECTROCHEMICAL DETECTION; ELECTRON TRANSPORT; LIGAND BINDING; LUMINESCENCE; OXIDATION REDUCTION REACTION; STRUCTURE ANALYSIS;

EID: 0033532923     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja990430t     Document Type: Article
Times cited : (246)

References (79)
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    • 3
    • 3
  • 63
    • 0344020004 scopus 로고    scopus 로고
    • - salt, oxidation of the anion was also present at ca. +1.0 V vs SCE, but it did not interfere with the other processes
    • - salt, oxidation of the anion was also present at ca. +1.0 V vs SCE, but it did not interfere with the other processes.
  • 66
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    • note
    • Since in deaerated solution the excited-state lifetime is longer than in air-equilibrated solution (Table 1), it would appear that quenching can be more profitably investigated in the former condition. It should be noted, however, that the quenching constants are calculated from correlations of results obtained from sets of experiments. A not uniform deaeration of the various solutions is likely to introduce errors that are not present when the experiments are performed in air-equilibrated solution.
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    • 29a by the energy of the emission maximum at 77 K
    • 29a by the energy of the emission maximum at 77 K.
  • 77
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    • ○/τ plot showed some upward curvature. In such conditions, the very weak luminescence intensity, along with strong spectral interference of the quencher, prevented a more accurate analysis
    • ○/τ plot showed some upward curvature. In such conditions, the very weak luminescence intensity, along with strong spectral interference of the quencher, prevented a more accurate analysis.


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