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3MLCT-triplet anthracene energy gap has been evaluated by assuming the 77 K emission maxima of Os-6A and of Ru-6A (Table 2) as the energy levels of the two states, respectively.
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38
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note
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A similar result has been obtained for another mixed anthracene-Os(II) complex (El-ghayoury, A.; Harriman, A.; Ziessel, R. Chem. Commun. 1999, 2027). Alternatively, it could be suggested that partial mixing between MLCT and anthracene triplets could occur. However, this seems to be less probable considering that the ethyl bridges only allow for small couplings.
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