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At the present time a total of 18 transition metal dichloromethane complexes are listed in the Cambridge Structural Database,33c mostly complexes of Ag (9, Rh (3, Ru (2, and Re 2
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33c mostly complexes of Ag (9), Rh (3), Ru (2), and Re (2).
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Several ionic or neutral, seemingly three-coordinate 14e NiII- and PdII-organyl complexes that feature an additional β-H agostic interaction have been described in recent years, a, tBu2PC2H4PtBu 2)NiC2H5, BF4, Conroy-Lewis, F. M, Mole, L, Redhouse, A. D, Litster, S. A, Spencer, J. L. J. Chem. Soc, Chem. Commun. 1991, 1601
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A detailed NMR investigation of the ion pairing was beyond the scope of this work
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(b) A detailed NMR investigation of the ion pairing was beyond the scope of this work.
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112
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34347330975
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