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For examples of neutral chelating halocarbon compounds, see: (a) Reference 7. (b) Lahuerta, P.; Latorre, J.; Martinez-Manez, R.; Sanz, F. J. Organomet. Chem. 1988, 356, 355. (c) Solans, X.; Font-Albana, M.; Aguilo, M.; Miravitlles, C.; Besteiro, J. C.; Lahuerta, P. Acta Crystallogr., C 1985, 41, 841.
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If 6 were an adduct of these discrete molecules, the significantly different Pt-I bond distances would be expected as is most often observed in infinite chains of repeating mixed valent bridging iodide complexes due to the Peierls effect. The type of disorder in the position of the bridging iodide that would be expected for random crystallization of a Pt-I⋯Pt species was not observed. See, for example: (a) Weinrach, J. B.; Ekberg, S. A.; Conradson, S. D.; Swanson, B. I. Inorg. Chem. 1990, 29, 981. (b) Matsumoto, N.; Yamashita, M.; Kida, S. Acta Crystallogr. 1979, B35, 1458.
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note
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XSCANS and SHELXTL PC are products of Siemens Analytical X-ray Instruments, Inc., 6300 Enterprise Lane, Madison, WI 53719. SHELX-93 is a program for crystal structure refinement written by G. M. Sheldrick University of Göttingen, Germany, 1993.
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note
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