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Volumn 118, Issue 47, 1996, Pages 11831-11843

Syntheses and structures of alkyl and aryl halide complexes of the type [(PiPr3)2PtH(η1-XR)]BAr(f) and analogues with Et2O, THF, and H2 ligands, halide-to-metal π bonding in halocarbon complexes

Author keywords

[No Author keywords available]

Indexed keywords

METAL COMPLEX; PLATINUM COMPLEX;

EID: 0029949643     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja961836y     Document Type: Article
Times cited : (122)

References (98)
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    • note
    • 2O had taken place.
  • 38
    • 0001319672 scopus 로고
    • See, for example: (a) Dick, D. G.; Stephan, D. W. Organometallics 1990, 9, 1910. (b) Davies, C. E.; Gardines, I. M.; Green, J. C.; Green, M. L. H.; Hazel, N. J.; Grebenik, P. D.; Mtetwa, V. S. B.; Prout, K. J. Chem. Soc., Dalton Trans. 1985, 669. (c) Churchill, M. R.; Wasserman, H. J. Inorg. Chem. 1982, 21, 223. (d) Cotton, F. A.; Lewis, G. F.; Mott, G. N. Inorg. Chem. 1982, 21, 3127.
    • (1990) Organometallics , vol.9 , pp. 1910
    • Dick, D.G.1    Stephan, D.W.2
  • 40
    • 0000630124 scopus 로고
    • See, for example: (a) Dick, D. G.; Stephan, D. W. Organometallics 1990, 9, 1910. (b) Davies, C. E.; Gardines, I. M.; Green, J. C.; Green, M. L. H.; Hazel, N. J.; Grebenik, P. D.; Mtetwa, V. S. B.; Prout, K. J. Chem. Soc., Dalton Trans. 1985, 669. (c) Churchill, M. R.; Wasserman, H. J. Inorg. Chem. 1982, 21, 223. (d) Cotton, F. A.; Lewis, G. F.; Mott, G. N. Inorg. Chem. 1982, 21, 3127.
    • (1982) J. Inorg. Chem. , vol.21 , pp. 223
    • Churchill, M.R.1    Wasserman, H.2
  • 41
    • 0000544569 scopus 로고
    • See, for example: (a) Dick, D. G.; Stephan, D. W. Organometallics 1990, 9, 1910. (b) Davies, C. E.; Gardines, I. M.; Green, J. C.; Green, M. L. H.; Hazel, N. J.; Grebenik, P. D.; Mtetwa, V. S. B.; Prout, K. J. Chem. Soc., Dalton Trans. 1985, 669. (c) Churchill, M. R.; Wasserman, H. J. Inorg. Chem. 1982, 21, 223. (d) Cotton, F. A.; Lewis, G. F.; Mott, G. N. Inorg. Chem. 1982, 21, 3127.
    • (1982) Inorg. Chem. , vol.21 , pp. 3127
    • Cotton, F.A.1    Lewis, G.F.2    Mott, G.N.3
  • 51
    • 10544222989 scopus 로고    scopus 로고
    • note
    • PPt = 2391).
  • 58
    • 10544223912 scopus 로고    scopus 로고
    • note
    • Structures of complexes containing chelating M⋯Br interactions have, however, been reported. See ref 8.
  • 66
    • 10544236274 scopus 로고    scopus 로고
    • note
    • Discover 95.0 is a product of Molecular Simulations Inc., 9685 Scranton Rd., San Diego, CA 92121-3752.
  • 83
    • 0008453330 scopus 로고    scopus 로고
    • Reference 7
    • For examples of neutral chelating halocarbon compounds, see: (a) Reference 7. (b) Lahuerta, P.; Latorre, J.; Martinez-Manez, R.; Sanz, F. J. Organomet. Chem. 1988, 356, 355. (c) Solans, X.; Font-Albana, M.; Aguilo, M.; Miravitlles, C.; Besteiro, J. C.; Lahuerta, P. Acta Crystallogr., C 1985, 41, 841.
  • 84
    • 0008453330 scopus 로고    scopus 로고
    • For examples of neutral chelating halocarbon compounds, see: (a) Reference 7. (b) Lahuerta, P.; Latorre, J.; Martinez-Manez, R.; Sanz, F. J. Organomet. Chem. 1988, 356, 355. (c) Solans, X.; Font-Albana, M.; Aguilo, M.; Miravitlles, C.; Besteiro, J. C.; Lahuerta, P. Acta Crystallogr., C 1985, 41, 841.
    • (1988) J. Organomet. Chem. , vol.356 , pp. 355
    • Lahuerta, P.1    Latorre, J.2    Martinez-Manez, R.3    Sanz, F.4
  • 86
    • 1542776400 scopus 로고
    • If 6 were an adduct of these discrete molecules, the significantly different Pt-I bond distances would be expected as is most often observed in infinite chains of repeating mixed valent bridging iodide complexes due to the Peierls effect. The type of disorder in the position of the bridging iodide that would be expected for random crystallization of a Pt-I⋯Pt species was not observed. See, for example: (a) Weinrach, J. B.; Ekberg, S. A.; Conradson, S. D.; Swanson, B. I. Inorg. Chem. 1990, 29, 981. (b) Matsumoto, N.; Yamashita, M.; Kida, S. Acta Crystallogr. 1979, B35, 1458.
    • (1990) Inorg. Chem. , vol.29 , pp. 981
    • Weinrach, J.B.1    Ekberg, S.A.2    Conradson, S.D.3    Swanson, B.I.4
  • 87
    • 1542776400 scopus 로고
    • If 6 were an adduct of these discrete molecules, the significantly different Pt-I bond distances would be expected as is most often observed in infinite chains of repeating mixed valent bridging iodide complexes due to the Peierls effect. The type of disorder in the position of the bridging iodide that would be expected for random crystallization of a Pt-I⋯Pt species was not observed. See, for example: (a) Weinrach, J. B.; Ekberg, S. A.; Conradson, S. D.; Swanson, B. I. Inorg. Chem. 1990, 29, 981. (b) Matsumoto, N.; Yamashita, M.; Kida, S. Acta Crystallogr. 1979, B35, 1458.
    • (1979) Acta Crystallogr. , vol.B35 , pp. 1458
    • Matsumoto, N.1    Yamashita, M.2    Kida, S.3
  • 97
    • 10544245192 scopus 로고    scopus 로고
    • note
    • XSCANS and SHELXTL PC are products of Siemens Analytical X-ray Instruments, Inc., 6300 Enterprise Lane, Madison, WI 53719. SHELX-93 is a program for crystal structure refinement written by G. M. Sheldrick University of Göttingen, Germany, 1993.
  • 98
    • 10544236656 scopus 로고    scopus 로고
    • note
    • 2)/3.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.