(η3-Allyl)palladium(II) and palladium(II) nitrile catalysts for the addition polymerization of norbornene derivatives with functional groups

Macromolecules

Volumn 29, Issue 8, 1996, Pages 2755-2763

  Mathew, Joice P ^a   Reinmuth, Annette ^a   Melia, Jennifer ^a   Swords, Noeleen ^a   Risse, Wilhelm ^a  

^a UNIVERSITY COLLEGE DUBLIN   (Ireland)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC HYDROCARBONS; CATALYSTS; COPOLYMERIZATION; COPOLYMERS; DERIVATIVES; MOLECULAR WEIGHT; MONOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PALLADIUM; POLYOLEFINS;

ADDITION POLYMERIZATION; FUNCTIONAL GROUP; NORBORNENE DERIVATIVES; PALLADIUM CATALYSTS; PALLADIUM NITRILE CATALYSTS;

POLYMERIZATION;

EID: 0030574993     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9515285     Document Type: Article

References (64)

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11. Leading references: (a) Grubbe, R. H. Lecture presented at ISOM 11. International Symposium on Olefin Metathesis and Related Chemistry, Durham, England, July 1995. (b) Kanaoka, S.; Grubbs, R. H. Macromolecules 1995, 28, 4707. (c) Hillmyer, M. A.: Lepetit, C.; McGrath, D. V.; Novak, B. M.; Grubbs, R. H. Macromolecules 1992, 25, 3345. (d) Bazan, G. C.; Sehrock, R. R; Cho, H-N.; Gibson, V. C. Macromolecules 1991, 24, 4495. (e) Mortell, K. H.; Gingras, M.; Kiessling, L L. J. Am Chem. Soc. 1994, 116, 12053. (f) Sehrock, R. R. Acc. Chem. Res. 1990, 23, 158. (g) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542. (h) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 960. (i) Amir-Ebrahimi, V.;Byrne, D.; Hamilton, J. G.; Rooney, J. J. Macromol. Chem. Phys. 1995, 796, 327. (j) Bell, B.; Hamilton, J. G.; Law, E. E.; Rooney, J. J. Macromol. Rapid. Commun. 1994, 15, 543. (k) Feast, W. J.; Harrison, D. B. Polymer 1991, 32, 558. (l) Zenkl, E.; Stelzer, F. J. Mol. Catal. 1992, 76, 1. (m) TbornCsanyi, E.; Harder. C.; Dahlke, B. J. Mol. Catal. 1992, 76, 93. (n) Castner, K. F.; Calderon, N. J. Mol. Catal. 1982, 15, 47. (o) Porri, L.; Diversi, P.; Lucherini, A.; Rossi, R. Makromol. Chem. 1975, 176, 3131. (p) Porri, L.; Rossi, R.; Diverai, P.; Lucherini, A. Makromol. Chem. 1974, 175, 3075. (q) Matanmoto, S.; Kumatsu, K.; Igarashi, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1977, 18, 110. (r) Charbonage de France, French Patent 1,556,215; Chem. Abstr. 1969, 71, 71703h. (s) Rinehart, R. H.; Smith, H. P. J. Polym. Sci., Polym. Lett. 1965, 3, 1049.
12. Leading references: (a) Grubbe, R. H. Lecture presented at ISOM 11. International Symposium on Olefin Metathesis and Related Chemistry, Durham, England, July 1995. (b) Kanaoka, S.; Grubbs, R. H. Macromolecules 1995, 28, 4707. (c) Hillmyer, M. A.: Lepetit, C.; McGrath, D. V.; Novak, B. M.; Grubbs, R. H. Macromolecules 1992, 25, 3345. (d) Bazan, G. C.; Sehrock, R. R; Cho, H-N.; Gibson, V. C. Macromolecules 1991, 24, 4495. (e) Mortell, K. H.; Gingras, M.; Kiessling, L L. J. Am Chem. Soc. 1994, 116, 12053. (f) Sehrock, R. R. Acc. Chem. Res. 1990, 23, 158. (g) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542. (h) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 960. (i) Amir-Ebrahimi, V.;Byrne, D.; Hamilton, J. G.; Rooney, J. J. Macromol. Chem. Phys. 1995, 796, 327. (j) Bell, B.; Hamilton, J. G.; Law, E. E.; Rooney, J. J. Macromol. Rapid. Commun. 1994, 15, 543. (k) Feast, W. J.; Harrison, D. B. Polymer 1991, 32, 558. (l) Zenkl, E.; Stelzer, F. J. Mol. Catal. 1992, 76, 1. (m) TbornCsanyi, E.; Harder. C.; Dahlke, B. J. Mol. Catal. 1992, 76, 93. (n) Castner, K. F.; Calderon, N. J. Mol. Catal. 1982, 15, 47. (o) Porri, L.; Diversi, P.; Lucherini, A.; Rossi, R. Makromol. Chem. 1975, 176, 3131. (p) Porri, L.; Rossi, R.; Diverai, P.; Lucherini, A. Makromol. Chem. 1974, 175, 3075. (q) Matanmoto, S.; Kumatsu, K.; Igarashi, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1977, 18, 110. (r) Charbonage de France, French Patent 1,556,215; Chem. Abstr. 1969, 71, 71703h. (s) Rinehart, R. H.; Smith, H. P. J. Polym. Sci., Polym. Lett. 1965, 3, 1049.
13. Leading references: (a) Grubbe, R. H. Lecture presented at ISOM 11. International Symposium on Olefin Metathesis and Related Chemistry, Durham, England, July 1995. (b) Kanaoka, S.; Grubbs, R. H. Macromolecules 1995, 28, 4707. (c) Hillmyer, M. A.: Lepetit, C.; McGrath, D. V.; Novak, B. M.; Grubbs, R. H. Macromolecules 1992, 25, 3345. (d) Bazan, G. C.; Sehrock, R. R; Cho, H-N.; Gibson, V. C. Macromolecules 1991, 24, 4495. (e) Mortell, K. H.; Gingras, M.; Kiessling, L L. J. Am Chem. Soc. 1994, 116, 12053. (f) Sehrock, R. R. Acc. Chem. Res. 1990, 23, 158. (g) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542. (h) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 960. (i) Amir-Ebrahimi, V.;Byrne, D.; Hamilton, J. G.; Rooney, J. J. Macromol. Chem. Phys. 1995, 796, 327. (j) Bell, B.; Hamilton, J. G.; Law, E. E.; Rooney, J. J. Macromol. Rapid. Commun. 1994, 15, 543. (k) Feast, W. J.; Harrison, D. B. Polymer 1991, 32, 558. (l) Zenkl, E.; Stelzer, F. J. Mol. Catal. 1992, 76, 1. (m) TbornCsanyi, E.; Harder. C.; Dahlke, B. J. Mol. Catal. 1992, 76, 93. (n) Castner, K. F.; Calderon, N. J. Mol. Catal. 1982, 15, 47. (o) Porri, L.; Diversi, P.; Lucherini, A.; Rossi, R. Makromol. Chem. 1975, 176, 3131. (p) Porri, L.; Rossi, R.; Diverai, P.; Lucherini, A. Makromol. Chem. 1974, 175, 3075. (q) Matanmoto, S.; Kumatsu, K.; Igarashi, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1977, 18, 110. (r) Charbonage de France, French Patent 1,556,215; Chem. Abstr. 1969, 71, 71703h. (s) Rinehart, R. H.; Smith, H. P. J. Polym. Sci., Polym. Lett. 1965, 3, 1049.
14. Leading references: (a) Grubbe, R. H. Lecture presented at ISOM 11. International Symposium on Olefin Metathesis and Related Chemistry, Durham, England, July 1995. (b) Kanaoka, S.; Grubbs, R. H. Macromolecules 1995, 28, 4707. (c) Hillmyer, M. A.: Lepetit, C.; McGrath, D. V.; Novak, B. M.; Grubbs, R. H. Macromolecules 1992, 25, 3345. (d) Bazan, G. C.; Sehrock, R. R; Cho, H-N.; Gibson, V. C. Macromolecules 1991, 24, 4495. (e) Mortell, K. H.; Gingras, M.; Kiessling, L L. J. Am Chem. Soc. 1994, 116, 12053. (f) Sehrock, R. R. Acc. Chem. Res. 1990, 23, 158. (g) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542. (h) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 960. (i) Amir-Ebrahimi, V.;Byrne, D.; Hamilton, J. G.; Rooney, J. J. Macromol. Chem. Phys. 1995, 796, 327. (j) Bell, B.; Hamilton, J. G.; Law, E. E.; Rooney, J. J. Macromol. Rapid. Commun. 1994, 15, 543. (k) Feast, W. J.; Harrison, D. B. Polymer 1991, 32, 558. (l) Zenkl, E.; Stelzer, F. J. Mol. Catal. 1992, 76, 1. (m) TbornCsanyi, E.; Harder. C.; Dahlke, B. J. Mol. Catal. 1992, 76, 93. (n) Castner, K. F.; Calderon, N. J. Mol. Catal. 1982, 15, 47. (o) Porri, L.; Diversi, P.; Lucherini, A.; Rossi, R. Makromol. Chem. 1975, 176, 3131. (p) Porri, L.; Rossi, R.; Diverai, P.; Lucherini, A. Makromol. Chem. 1974, 175, 3075. (q) Matanmoto, S.; Kumatsu, K.; Igarashi, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1977, 18, 110. (r) Charbonage de France, French Patent 1,556,215; Chem. Abstr. 1969, 71, 71703h. (s) Rinehart, R. H.; Smith, H. P. J. Polym. Sci., Polym. Lett. 1965, 3, 1049.
15. Leading references: (a) Grubbe, R. H. Lecture presented at ISOM 11. International Symposium on Olefin Metathesis and Related Chemistry, Durham, England, July 1995. (b) Kanaoka, S.; Grubbs, R. H. Macromolecules 1995, 28, 4707. (c) Hillmyer, M. A.: Lepetit, C.; McGrath, D. V.; Novak, B. M.; Grubbs, R. H. Macromolecules 1992, 25, 3345. (d) Bazan, G. C.; Sehrock, R. R; Cho, H-N.; Gibson, V. C. Macromolecules 1991, 24, 4495. (e) Mortell, K. H.; Gingras, M.; Kiessling, L L. J. Am Chem. Soc. 1994, 116, 12053. (f) Sehrock, R. R. Acc. Chem. Res. 1990, 23, 158. (g) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542. (h) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 960. (i) Amir-Ebrahimi, V.;Byrne, D.; Hamilton, J. G.; Rooney, J. J. Macromol. Chem. Phys. 1995, 796, 327. (j) Bell, B.; Hamilton, J. G.; Law, E. E.; Rooney, J. J. Macromol. Rapid. Commun. 1994, 15, 543. (k) Feast, W. J.; Harrison, D. B. Polymer 1991, 32, 558. (l) Zenkl, E.; Stelzer, F. J. Mol. Catal. 1992, 76, 1. (m) TbornCsanyi, E.; Harder. C.; Dahlke, B. J. Mol. Catal. 1992, 76, 93. (n) Castner, K. F.; Calderon, N. J. Mol. Catal. 1982, 15, 47. (o) Porri, L.; Diversi, P.; Lucherini, A.; Rossi, R. Makromol. Chem. 1975, 176, 3131. (p) Porri, L.; Rossi, R.; Diverai, P.; Lucherini, A. Makromol. Chem. 1974, 175, 3075. (q) Matanmoto, S.; Kumatsu, K.; Igarashi, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1977, 18, 110. (r) Charbonage de France, French Patent 1,556,215; Chem. Abstr. 1969, 71, 71703h. (s) Rinehart, R. H.; Smith, H. P. J. Polym. Sci., Polym. Lett. 1965, 3, 1049.
16. Leading references: (a) Grubbe, R. H. Lecture presented at ISOM 11. International Symposium on Olefin Metathesis and Related Chemistry, Durham, England, July 1995. (b) Kanaoka, S.; Grubbs, R. H. Macromolecules 1995, 28, 4707. (c) Hillmyer, M. A.: Lepetit, C.; McGrath, D. V.; Novak, B. M.; Grubbs, R. H. Macromolecules 1992, 25, 3345. (d) Bazan, G. C.; Sehrock, R. R; Cho, H-N.; Gibson, V. C. Macromolecules 1991, 24, 4495. (e) Mortell, K. H.; Gingras, M.; Kiessling, L L. J. Am Chem. Soc. 1994, 116, 12053. (f) Sehrock, R. R. Acc. Chem. Res. 1990, 23, 158. (g) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542. (h) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 960. (i) Amir-Ebrahimi, V.;Byrne, D.; Hamilton, J. G.; Rooney, J. J. Macromol. Chem. Phys. 1995, 796, 327. (j) Bell, B.; Hamilton, J. G.; Law, E. E.; Rooney, J. J. Macromol. Rapid. Commun. 1994, 15, 543. (k) Feast, W. J.; Harrison, D. B. Polymer 1991, 32, 558. (l) Zenkl, E.; Stelzer, F. J. Mol. Catal. 1992, 76, 1. (m) TbornCsanyi, E.; Harder. C.; Dahlke, B. J. Mol. Catal. 1992, 76, 93. (n) Castner, K. F.; Calderon, N. J. Mol. Catal. 1982, 15, 47. (o) Porri, L.; Diversi, P.; Lucherini, A.; Rossi, R. Makromol. Chem. 1975, 176, 3131. (p) Porri, L.; Rossi, R.; Diverai, P.; Lucherini, A. Makromol. Chem. 1974, 175, 3075. (q) Matanmoto, S.; Kumatsu, K.; Igarashi, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1977, 18, 110. (r) Charbonage de France, French Patent 1,556,215; Chem. Abstr. 1969, 71, 71703h. (s) Rinehart, R. H.; Smith, H. P. J. Polym. Sci., Polym. Lett. 1965, 3, 1049.
17. Leading references: (a) Grubbe, R. H. Lecture presented at ISOM 11. International Symposium on Olefin Metathesis and Related Chemistry, Durham, England, July 1995. (b) Kanaoka, S.; Grubbs, R. H. Macromolecules 1995, 28, 4707. (c) Hillmyer, M. A.: Lepetit, C.; McGrath, D. V.; Novak, B. M.; Grubbs, R. H. Macromolecules 1992, 25, 3345. (d) Bazan, G. C.; Sehrock, R. R; Cho, H-N.; Gibson, V. C. Macromolecules 1991, 24, 4495. (e) Mortell, K. H.; Gingras, M.; Kiessling, L L. J. Am Chem. Soc. 1994, 116, 12053. (f) Sehrock, R. R. Acc. Chem. Res. 1990, 23, 158. (g) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542. (h) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 960. (i) Amir-Ebrahimi, V.;Byrne, D.; Hamilton, J. G.; Rooney, J. J. Macromol. Chem. Phys. 1995, 796, 327. (j) Bell, B.; Hamilton, J. G.; Law, E. E.; Rooney, J. J. Macromol. Rapid. Commun. 1994, 15, 543. (k) Feast, W. J.; Harrison, D. B. Polymer 1991, 32, 558. (l) Zenkl, E.; Stelzer, F. J. Mol. Catal. 1992, 76, 1. (m) TbornCsanyi, E.; Harder. C.; Dahlke, B. J. Mol. Catal. 1992, 76, 93. (n) Castner, K. F.; Calderon, N. J. Mol. Catal. 1982, 15, 47. (o) Porri, L.; Diversi, P.; Lucherini, A.; Rossi, R. Makromol. Chem. 1975, 176, 3131. (p) Porri, L.; Rossi, R.; Diverai, P.; Lucherini, A. Makromol. Chem. 1974, 175, 3075. (q) Matanmoto, S.; Kumatsu, K.; Igarashi, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1977, 18, 110. (r) Charbonage de France, French Patent 1,556,215; Chem. Abstr. 1969, 71, 71703h. (s) Rinehart, R. H.; Smith, H. P. J. Polym. Sci., Polym. Lett. 1965, 3, 1049.
18. Leading references: (a) Grubbe, R. H. Lecture presented at ISOM 11. International Symposium on Olefin Metathesis and Related Chemistry, Durham, England, July 1995. (b) Kanaoka, S.; Grubbs, R. H. Macromolecules 1995, 28, 4707. (c) Hillmyer, M. A.: Lepetit, C.; McGrath, D. V.; Novak, B. M.; Grubbs, R. H. Macromolecules 1992, 25, 3345. (d) Bazan, G. C.; Sehrock, R. R; Cho, H-N.; Gibson, V. C. Macromolecules 1991, 24, 4495. (e) Mortell, K. H.; Gingras, M.; Kiessling, L L. J. Am Chem. Soc. 1994, 116, 12053. (f) Sehrock, R. R. Acc. Chem. Res. 1990, 23, 158. (g) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542. (h) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 960. (i) Amir-Ebrahimi, V.;Byrne, D.; Hamilton, J. G.; Rooney, J. J. Macromol. Chem. Phys. 1995, 796, 327. (j) Bell, B.; Hamilton, J. G.; Law, E. E.; Rooney, J. J. Macromol. Rapid. Commun. 1994, 15, 543. (k) Feast, W. J.; Harrison, D. B. Polymer 1991, 32, 558. (l) Zenkl, E.; Stelzer, F. J. Mol. Catal. 1992, 76, 1. (m) TbornCsanyi, E.; Harder. C.; Dahlke, B. J. Mol. Catal. 1992, 76, 93. (n) Castner, K. F.; Calderon, N. J. Mol. Catal. 1982, 15, 47. (o) Porri, L.; Diversi, P.; Lucherini, A.; Rossi, R. Makromol. Chem. 1975, 176, 3131. (p) Porri, L.; Rossi, R.; Diverai, P.; Lucherini, A. Makromol. Chem. 1974, 175, 3075. (q) Matanmoto, S.; Kumatsu, K.; Igarashi, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1977, 18, 110. (r) Charbonage de France, French Patent 1,556,215; Chem. Abstr. 1969, 71, 71703h. (s) Rinehart, R. H.; Smith, H. P. J. Polym. Sci., Polym. Lett. 1965, 3, 1049.
19. Leading references: (a) Grubbe, R. H. Lecture presented at ISOM 11. International Symposium on Olefin Metathesis and Related Chemistry, Durham, England, July 1995. (b) Kanaoka, S.; Grubbs, R. H. Macromolecules 1995, 28, 4707. (c) Hillmyer, M. A.: Lepetit, C.; McGrath, D. V.; Novak, B. M.; Grubbs, R. H. Macromolecules 1992, 25, 3345. (d) Bazan, G. C.; Sehrock, R. R; Cho, H-N.; Gibson, V. C. Macromolecules 1991, 24, 4495. (e) Mortell, K. H.; Gingras, M.; Kiessling, L L. J. Am Chem. Soc. 1994, 116, 12053. (f) Sehrock, R. R. Acc. Chem. Res. 1990, 23, 158. (g) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542. (h) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 960. (i) Amir-Ebrahimi, V.;Byrne, D.; Hamilton, J. G.; Rooney, J. J. Macromol. Chem. Phys. 1995, 796, 327. (j) Bell, B.; Hamilton, J. G.; Law, E. E.; Rooney, J. J. Macromol. Rapid. Commun. 1994, 15, 543. (k) Feast, W. J.; Harrison, D. B. Polymer 1991, 32, 558. (l) Zenkl, E.; Stelzer, F. J. Mol. Catal. 1992, 76, 1. (m) TbornCsanyi, E.; Harder. C.; Dahlke, B. J. Mol. Catal. 1992, 76, 93. (n) Castner, K. F.; Calderon, N. J. Mol. Catal. 1982, 15, 47. (o) Porri, L.; Diversi, P.; Lucherini, A.; Rossi, R. Makromol. Chem. 1975, 176, 3131. (p) Porri, L.; Rossi, R.; Diverai, P.; Lucherini, A. Makromol. Chem. 1974, 175, 3075. (q) Matanmoto, S.; Kumatsu, K.; Igarashi, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1977, 18, 110. (r) Charbonage de France, French Patent 1,556,215; Chem. Abstr. 1969, 71, 71703h. (s) Rinehart, R. H.; Smith, H. P. J. Polym. Sci., Polym. Lett. 1965, 3, 1049.
20. Leading references: (a) Grubbe, R. H. Lecture presented at ISOM 11. International Symposium on Olefin Metathesis and Related Chemistry, Durham, England, July 1995. (b) Kanaoka, S.; Grubbs, R. H. Macromolecules 1995, 28, 4707. (c) Hillmyer, M. A.: Lepetit, C.; McGrath, D. V.; Novak, B. M.; Grubbs, R. H. Macromolecules 1992, 25, 3345. (d) Bazan, G. C.; Sehrock, R. R; Cho, H-N.; Gibson, V. C. Macromolecules 1991, 24, 4495. (e) Mortell, K. H.; Gingras, M.; Kiessling, L L. J. Am Chem. Soc. 1994, 116, 12053. (f) Sehrock, R. R. Acc. Chem. Res. 1990, 23, 158. (g) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542. (h) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 960. (i) Amir-Ebrahimi, V.;Byrne, D.; Hamilton, J. G.; Rooney, J. J. Macromol. Chem. Phys. 1995, 796, 327. (j) Bell, B.; Hamilton, J. G.; Law, E. E.; Rooney, J. J. Macromol. Rapid. Commun. 1994, 15, 543. (k) Feast, W. J.; Harrison, D. B. Polymer 1991, 32, 558. (l) Zenkl, E.; Stelzer, F. J. Mol. Catal. 1992, 76, 1. (m) TbornCsanyi, E.; Harder. C.; Dahlke, B. J. Mol. Catal. 1992, 76, 93. (n) Castner, K. F.; Calderon, N. J. Mol. Catal. 1982, 15, 47. (o) Porri, L.; Diversi, P.; Lucherini, A.; Rossi, R. Makromol. Chem. 1975, 176, 3131. (p) Porri, L.; Rossi, R.; Diverai, P.; Lucherini, A. Makromol. Chem. 1974, 175, 3075. (q) Matanmoto, S.; Kumatsu, K.; Igarashi, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1977, 18, 110. (r) Charbonage de France, French Patent 1,556,215; Chem. Abstr. 1969, 71, 71703h. (s) Rinehart, R. H.; Smith, H. P. J. Polym. Sci., Polym. Lett. 1965, 3, 1049.
21. Leading references: (a) Grubbe, R. H. Lecture presented at ISOM 11. International Symposium on Olefin Metathesis and Related Chemistry, Durham, England, July 1995. (b) Kanaoka, S.; Grubbs, R. H. Macromolecules 1995, 28, 4707. (c) Hillmyer, M. A.: Lepetit, C.; McGrath, D. V.; Novak, B. M.; Grubbs, R. H. Macromolecules 1992, 25, 3345. (d) Bazan, G. C.; Sehrock, R. R; Cho, H-N.; Gibson, V. C. Macromolecules 1991, 24, 4495. (e) Mortell, K. H.; Gingras, M.; Kiessling, L L. J. Am Chem. Soc. 1994, 116, 12053. (f) Sehrock, R. R. Acc. Chem. Res. 1990, 23, 158. (g) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542. (h) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 960. (i) Amir-Ebrahimi, V.;Byrne, D.; Hamilton, J. G.; Rooney, J. J. Macromol. Chem. Phys. 1995, 796, 327. (j) Bell, B.; Hamilton, J. G.; Law, E. E.; Rooney, J. J. Macromol. Rapid. Commun. 1994, 15, 543. (k) Feast, W. J.; Harrison, D. B. Polymer 1991, 32, 558. (l) Zenkl, E.; Stelzer, F. J. Mol. Catal. 1992, 76, 1. (m) TbornCsanyi, E.; Harder. C.; Dahlke, B. J. Mol. Catal. 1992, 76, 93. (n) Castner, K. F.; Calderon, N. J. Mol. Catal. 1982, 15, 47. (o) Porri, L.; Diversi, P.; Lucherini, A.; Rossi, R. Makromol. Chem. 1975, 176, 3131. (p) Porri, L.; Rossi, R.; Diverai, P.; Lucherini, A. Makromol. Chem. 1974, 175, 3075. (q) Matanmoto, S.; Kumatsu, K.; Igarashi, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1977, 18, 110. (r) Charbonage de France, French Patent 1,556,215; Chem. Abstr. 1969, 71, 71703h. (s) Rinehart, R. H.; Smith, H. P. J. Polym. Sci., Polym. Lett. 1965, 3, 1049.
22. Leading references: (a) Grubbe, R. H. Lecture presented at ISOM 11. International Symposium on Olefin Metathesis and Related Chemistry, Durham, England, July 1995. (b) Kanaoka, S.; Grubbs, R. H. Macromolecules 1995, 28, 4707. (c) Hillmyer, M. A.: Lepetit, C.; McGrath, D. V.; Novak, B. M.; Grubbs, R. H. Macromolecules 1992, 25, 3345. (d) Bazan, G. C.; Sehrock, R. R; Cho, H-N.; Gibson, V. C. Macromolecules 1991, 24, 4495. (e) Mortell, K. H.; Gingras, M.; Kiessling, L L. J. Am Chem. Soc. 1994, 116, 12053. (f) Sehrock, R. R. Acc. Chem. Res. 1990, 23, 158. (g) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542. (h) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 960. (i) Amir-Ebrahimi, V.;Byrne, D.; Hamilton, J. G.; Rooney, J. J. Macromol. Chem. Phys. 1995, 796, 327. (j) Bell, B.; Hamilton, J. G.; Law, E. E.; Rooney, J. J. Macromol. Rapid. Commun. 1994, 15, 543. (k) Feast, W. J.; Harrison, D. B. Polymer 1991, 32, 558. (l) Zenkl, E.; Stelzer, F. J. Mol. Catal. 1992, 76, 1. (m) TbornCsanyi, E.; Harder. C.; Dahlke, B. J. Mol. Catal. 1992, 76, 93. (n) Castner, K. F.; Calderon, N. J. Mol. Catal. 1982, 15, 47. (o) Porri, L.; Diversi, P.; Lucherini, A.; Rossi, R. Makromol. Chem. 1975, 176, 3131. (p) Porri, L.; Rossi, R.; Diverai, P.; Lucherini, A. Makromol. Chem. 1974, 175, 3075. (q) Matanmoto, S.; Kumatsu, K.; Igarashi, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1977, 18, 110. (r) Charbonage de France, French Patent 1,556,215; Chem. Abstr. 1969, 71, 71703h. (s) Rinehart, R. H.; Smith, H. P. J. Polym. Sci., Polym. Lett. 1965, 3, 1049.
23. Leading references: (a) Grubbe, R. H. Lecture presented at ISOM 11. International Symposium on Olefin Metathesis and Related Chemistry, Durham, England, July 1995. (b) Kanaoka, S.; Grubbs, R. H. Macromolecules 1995, 28, 4707. (c) Hillmyer, M. A.: Lepetit, C.; McGrath, D. V.; Novak, B. M.; Grubbs, R. H. Macromolecules 1992, 25, 3345. (d) Bazan, G. C.; Sehrock, R. R; Cho, H-N.; Gibson, V. C. Macromolecules 1991, 24, 4495. (e) Mortell, K. H.; Gingras, M.; Kiessling, L L. J. Am Chem. Soc. 1994, 116, 12053. (f) Sehrock, R. R. Acc. Chem. Res. 1990, 23, 158. (g) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542. (h) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 960. (i) Amir-Ebrahimi, V.;Byrne, D.; Hamilton, J. G.; Rooney, J. J. Macromol. Chem. Phys. 1995, 796, 327. (j) Bell, B.; Hamilton, J. G.; Law, E. E.; Rooney, J. J. Macromol. Rapid. Commun. 1994, 15, 543. (k) Feast, W. J.; Harrison, D. B. Polymer 1991, 32, 558. (l) Zenkl, E.; Stelzer, F. J. Mol. Catal. 1992, 76, 1. (m) TbornCsanyi, E.; Harder. C.; Dahlke, B. J. Mol. Catal. 1992, 76, 93. (n) Castner, K. F.; Calderon, N. J. Mol. Catal. 1982, 15, 47. (o) Porri, L.; Diversi, P.; Lucherini, A.; Rossi, R. Makromol. Chem. 1975, 176, 3131. (p) Porri, L.; Rossi, R.; Diverai, P.; Lucherini, A. Makromol. Chem. 1974, 175, 3075. (q) Matanmoto, S.; Kumatsu, K.; Igarashi, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1977, 18, 110. (r) Charbonage de France, French Patent 1,556,215; Chem. Abstr. 1969, 71, 71703h. (s) Rinehart, R. H.; Smith, H. P. J. Polym. Sci., Polym. Lett. 1965, 3, 1049.
24. Leading references: (a) Grubbe, R. H. Lecture presented at ISOM 11. International Symposium on Olefin Metathesis and Related Chemistry, Durham, England, July 1995. (b) Kanaoka, S.; Grubbs, R. H. Macromolecules 1995, 28, 4707. (c) Hillmyer, M. A.: Lepetit, C.; McGrath, D. V.; Novak, B. M.; Grubbs, R. H. Macromolecules 1992, 25, 3345. (d) Bazan, G. C.; Sehrock, R. R; Cho, H-N.; Gibson, V. C. Macromolecules 1991, 24, 4495. (e) Mortell, K. H.; Gingras, M.; Kiessling, L L. J. Am Chem. Soc. 1994, 116, 12053. (f) Sehrock, R. R. Acc. Chem. Res. 1990, 23, 158. (g) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542. (h) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 960. (i) Amir-Ebrahimi, V.;Byrne, D.; Hamilton, J. G.; Rooney, J. J. Macromol. Chem. Phys. 1995, 796, 327. (j) Bell, B.; Hamilton, J. G.; Law, E. E.; Rooney, J. J. Macromol. Rapid. Commun. 1994, 15, 543. (k) Feast, W. J.; Harrison, D. B. Polymer 1991, 32, 558. (l) Zenkl, E.; Stelzer, F. J. Mol. Catal. 1992, 76, 1. (m) TbornCsanyi, E.; Harder. C.; Dahlke, B. J. Mol. Catal. 1992, 76, 93. (n) Castner, K. F.; Calderon, N. J. Mol. Catal. 1982, 15, 47. (o) Porri, L.; Diversi, P.; Lucherini, A.; Rossi, R. Makromol. Chem. 1975, 176, 3131. (p) Porri, L.; Rossi, R.; Diverai, P.; Lucherini, A. Makromol. Chem. 1974, 175, 3075. (q) Matanmoto, S.; Kumatsu, K.; Igarashi, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1977, 18, 110. (r) Charbonage de France, French Patent 1,556,215; Chem. Abstr. 1969, 71, 71703h. (s) Rinehart, R. H.; Smith, H. P. J. Polym. Sci., Polym. Lett. 1965, 3, 1049.
25. Leading references: (a) Grubbe, R. H. Lecture presented at ISOM 11. International Symposium on Olefin Metathesis and Related Chemistry, Durham, England, July 1995. (b) Kanaoka, S.; Grubbs, R. H. Macromolecules 1995, 28, 4707. (c) Hillmyer, M. A.: Lepetit, C.; McGrath, D. V.; Novak, B. M.; Grubbs, R. H. Macromolecules 1992, 25, 3345. (d) Bazan, G. C.; Sehrock, R. R; Cho, H-N.; Gibson, V. C. Macromolecules 1991, 24, 4495. (e) Mortell, K. H.; Gingras, M.; Kiessling, L L. J. Am Chem. Soc. 1994, 116, 12053. (f) Sehrock, R. R. Acc. Chem. Res. 1990, 23, 158. (g) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542. (h) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 960. (i) Amir-Ebrahimi, V.;Byrne, D.; Hamilton, J. G.; Rooney, J. J. Macromol. Chem. Phys. 1995, 796, 327. (j) Bell, B.; Hamilton, J. G.; Law, E. E.; Rooney, J. J. Macromol. Rapid. Commun. 1994, 15, 543. (k) Feast, W. J.; Harrison, D. B. Polymer 1991, 32, 558. (l) Zenkl, E.; Stelzer, F. J. Mol. Catal. 1992, 76, 1. (m) TbornCsanyi, E.; Harder. C.; Dahlke, B. J. Mol. Catal. 1992, 76, 93. (n) Castner, K. F.; Calderon, N. J. Mol. Catal. 1982, 15, 47. (o) Porri, L.; Diversi, P.; Lucherini, A.; Rossi, R. Makromol. Chem. 1975, 176, 3131. (p) Porri, L.; Rossi, R.; Diverai, P.; Lucherini, A. Makromol. Chem. 1974, 175, 3075. (q) Matanmoto, S.; Kumatsu, K.; Igarashi, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1977, 18, 110. (r) Charbonage de France, French Patent 1,556,215; Chem. Abstr. 1969, 71, 71703h. (s) Rinehart, R. H.; Smith, H. P. J. Polym. Sci., Polym. Lett. 1965, 3, 1049.
26. Leading references: (a) Grubbe, R. H. Lecture presented at ISOM 11. International Symposium on Olefin Metathesis and Related Chemistry, Durham, England, July 1995. (b) Kanaoka, S.; Grubbs, R. H. Macromolecules 1995, 28, 4707. (c) Hillmyer, M. A.: Lepetit, C.; McGrath, D. V.; Novak, B. M.; Grubbs, R. H. Macromolecules 1992, 25, 3345. (d) Bazan, G. C.; Sehrock, R. R; Cho, H-N.; Gibson, V. C. Macromolecules 1991, 24, 4495. (e) Mortell, K. H.; Gingras, M.; Kiessling, L L. J. Am Chem. Soc. 1994, 116, 12053. (f) Sehrock, R. R. Acc. Chem. Res. 1990, 23, 158. (g) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542. (h) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 960. (i) Amir-Ebrahimi, V.;Byrne, D.; Hamilton, J. G.; Rooney, J. J. Macromol. Chem. Phys. 1995, 796, 327. (j) Bell, B.; Hamilton, J. G.; Law, E. E.; Rooney, J. J. Macromol. Rapid. Commun. 1994, 15, 543. (k) Feast, W. J.; Harrison, D. B. Polymer 1991, 32, 558. (l) Zenkl, E.; Stelzer, F. J. Mol. Catal. 1992, 76, 1. (m) TbornCsanyi, E.; Harder. C.; Dahlke, B. J. Mol. Catal. 1992, 76, 93. (n) Castner, K. F.; Calderon, N. J. Mol. Catal. 1982, 15, 47. (o) Porri, L.; Diversi, P.; Lucherini, A.; Rossi, R. Makromol. Chem. 1975, 176, 3131. (p) Porri, L.; Rossi, R.; Diverai, P.; Lucherini, A. Makromol. Chem. 1974, 175, 3075. (q) Matanmoto, S.; Kumatsu, K.; Igarashi, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1977, 18, 110. (r) Charbonage de France, French Patent 1,556,215; Chem. Abstr. 1969, 71, 71703h. (s) Rinehart, R. H.; Smith, H. P. J. Polym. Sci., Polym. Lett. 1965, 3, 1049.
27. Leading references: (a) Grubbe, R. H. Lecture presented at ISOM 11. International Symposium on Olefin Metathesis and Related Chemistry, Durham, England, July 1995. (b) Kanaoka, S.; Grubbs, R. H. Macromolecules 1995, 28, 4707. (c) Hillmyer, M. A.: Lepetit, C.; McGrath, D. V.; Novak, B. M.; Grubbs, R. H. Macromolecules 1992, 25, 3345. (d) Bazan, G. C.; Sehrock, R. R; Cho, H-N.; Gibson, V. C. Macromolecules 1991, 24, 4495. (e) Mortell, K. H.; Gingras, M.; Kiessling, L L. J. Am Chem. Soc. 1994, 116, 12053. (f) Sehrock, R. R. Acc. Chem. Res. 1990, 23, 158. (g) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542. (h) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 960. (i) Amir-Ebrahimi, V.;Byrne, D.; Hamilton, J. G.; Rooney, J. J. Macromol. Chem. Phys. 1995, 796, 327. (j) Bell, B.; Hamilton, J. G.; Law, E. E.; Rooney, J. J. Macromol. Rapid. Commun. 1994, 15, 543. (k) Feast, W. J.; Harrison, D. B. Polymer 1991, 32, 558. (l) Zenkl, E.; Stelzer, F. J. Mol. Catal. 1992, 76, 1. (m) TbornCsanyi, E.; Harder. C.; Dahlke, B. J. Mol. Catal. 1992, 76, 93. (n) Castner, K. F.; Calderon, N. J. Mol. Catal. 1982, 15, 47. (o) Porri, L.; Diversi, P.; Lucherini, A.; Rossi, R. Makromol. Chem. 1975, 176, 3131. (p) Porri, L.; Rossi, R.; Diverai, P.; Lucherini, A. Makromol. Chem. 1974, 175, 3075. (q) Matanmoto, S.; Kumatsu, K.; Igarashi, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1977, 18, 110. (r) Charbonage de France, French Patent 1,556,215; Chem. Abstr. 1969, 71, 71703h. (s) Rinehart, R. H.; Smith, H. P. J. Polym. Sci., Polym. Lett. 1965, 3, 1049.
28. Leading references: (a) Grubbe, R. H. Lecture presented at ISOM 11. International Symposium on Olefin Metathesis and Related Chemistry, Durham, England, July 1995. (b) Kanaoka, S.; Grubbs, R. H. Macromolecules 1995, 28, 4707. (c) Hillmyer, M. A.: Lepetit, C.; McGrath, D. V.; Novak, B. M.; Grubbs, R. H. Macromolecules 1992, 25, 3345. (d) Bazan, G. C.; Sehrock, R. R; Cho, H-N.; Gibson, V. C. Macromolecules 1991, 24, 4495. (e) Mortell, K. H.; Gingras, M.; Kiessling, L L. J. Am Chem. Soc. 1994, 116, 12053. (f) Sehrock, R. R. Acc. Chem. Res. 1990, 23, 158. (g) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542. (h) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 960. (i) Amir-Ebrahimi, V.;Byrne, D.; Hamilton, J. G.; Rooney, J. J. Macromol. Chem. Phys. 1995, 796, 327. (j) Bell, B.; Hamilton, J. G.; Law, E. E.; Rooney, J. J. Macromol. Rapid. Commun. 1994, 15, 543. (k) Feast, W. J.; Harrison, D. B. Polymer 1991, 32, 558. (l) Zenkl, E.; Stelzer, F. J. Mol. Catal. 1992, 76, 1. (m) TbornCsanyi, E.; Harder. C.; Dahlke, B. J. Mol. Catal. 1992, 76, 93. (n) Castner, K. F.; Calderon, N. J. Mol. Catal. 1982, 15, 47. (o) Porri, L.; Diversi, P.; Lucherini, A.; Rossi, R. Makromol. Chem. 1975, 176, 3131. (p) Porri, L.; Rossi, R.; Diverai, P.; Lucherini, A. Makromol. Chem. 1974, 175, 3075. (q) Matanmoto, S.; Kumatsu, K.; Igarashi, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1977, 18, 110. (r) Charbonage de France, French Patent 1,556,215; Chem. Abstr. 1969, 71, 71703h. (s) Rinehart, R. H.; Smith, H. P. J. Polym. Sci., Polym. Lett. 1965, 3, 1049.
29. Leading references: (a) Grubbe, R. H. Lecture presented at ISOM 11. International Symposium on Olefin Metathesis and Related Chemistry, Durham, England, July 1995. (b) Kanaoka, S.; Grubbs, R. H. Macromolecules 1995, 28, 4707. (c) Hillmyer, M. A.: Lepetit, C.; McGrath, D. V.; Novak, B. M.; Grubbs, R. H. Macromolecules 1992, 25, 3345. (d) Bazan, G. C.; Sehrock, R. R; Cho, H-N.; Gibson, V. C. Macromolecules 1991, 24, 4495. (e) Mortell, K. H.; Gingras, M.; Kiessling, L L. J. Am Chem. Soc. 1994, 116, 12053. (f) Sehrock, R. R. Acc. Chem. Res. 1990, 23, 158. (g) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542. (h) Novak, B. M., Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 960. (i) Amir-Ebrahimi, V.;Byrne, D.; Hamilton, J. G.; Rooney, J. J. Macromol. Chem. Phys. 1995, 796, 327. (j) Bell, B.; Hamilton, J. G.; Law, E. E.; Rooney, J. J. Macromol. Rapid. Commun. 1994, 15, 543. (k) Feast, W. J.; Harrison, D. B. Polymer 1991, 32, 558. (l) Zenkl, E.; Stelzer, F. J. Mol. Catal. 1992, 76, 1. (m) TbornCsanyi, E.; Harder. C.; Dahlke, B. J. Mol. Catal. 1992, 76, 93. (n) Castner, K. F.; Calderon, N. J. Mol. Catal. 1982, 15, 47. (o) Porri, L.; Diversi, P.; Lucherini, A.; Rossi, R. Makromol. Chem. 1975, 176, 3131. (p) Porri, L.; Rossi, R.; Diverai, P.; Lucherini, A. Makromol. Chem. 1974, 175, 3075. (q) Matanmoto, S.; Kumatsu, K.; Igarashi, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1977, 18, 110. (r) Charbonage de France, French Patent 1,556,215; Chem. Abstr. 1969, 71, 71703h. (s) Rinehart, R. H.; Smith, H. P. J. Polym. Sci., Polym. Lett. 1965, 3, 1049.
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36. Addition homopolymers and block copolymers of diethyrl-7-oxabicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylates serving as precursor polymers to polyacetylenes have been prepared with π-stabilized Pd(II) alkyl complexes: (a) Safir, A. L.; Novak, B. M. Macromolecules 1995, 28, 5396. (b) Safir, A L.; Novak, B. M. Macromolecules 1993, 26, 4072. Ni- and Pd-catalyzed polymerization of predominantly alkyl-substituted norbornene derivatives have recently been described in the following: (c) Maezawa, H.; Mataoawto, J.; Aiura, H.; Asahi, S. (Idemitsu Kosan Co. Ltd., Jpn.). Eur. Pat. Appl. 445 755 A2, 1991. (d) Goodall, B. L.; Benedikt, L. H.; McIntosh, L. H., III; Barnes, D. A.; Rhodes, L. F. (BFGoodrich). Patent WO 95/14048, 1995. (e) Goodall, B. L.; Benedikt, G. M.; McIntosh, L. H., III; Barnes, D. A. (BFGoodrich) U.S. Patent 5 468 819, 1995
37. Addition homopolymers and block copolymers of diethyrl-7-oxabicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylates serving as precursor polymers to polyacetylenes have been prepared with π-stabilized Pd(II) alkyl complexes: (a) Safir, A. L.; Novak, B. M. Macromolecules 1995, 28, 5396. (b) Safir, A L.; Novak, B. M. Macromolecules 1993, 26, 4072. Ni- and Pd-catalyzed polymerization of predominantly alkyl-substituted norbornene derivatives have recently been described in the following: (c) Maezawa, H.; Mataoawto, J.; Aiura, H.; Asahi, S. (Idemitsu Kosan Co. Ltd., Jpn.). Eur. Pat. Appl. 445 755 A2, 1991. (d) Goodall, B. L.; Benedikt, L. H.; McIntosh, L. H., III; Barnes, D. A.; Rhodes, L. F. (BFGoodrich). Patent WO 95/14048, 1995. (e) Goodall, B. L.; Benedikt, G. M.; McIntosh, L. H., III; Barnes, D. A. (BFGoodrich) U.S. Patent 5 468 819, 1995
38. Addition homopolymers and block copolymers of diethyrl-7-oxabicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylates serving as precursor polymers to polyacetylenes have been prepared with π-stabilized Pd(II) alkyl complexes: (a) Safir, A. L.; Novak, B. M. Macromolecules 1995, 28, 5396. (b) Safir, A L.; Novak, B. M. Macromolecules 1993, 26, 4072. Ni- and Pd-catalyzed polymerization of predominantly alkyl-substituted norbornene derivatives have recently been described in the following: (c) Maezawa, H.; Mataoawto, J.; Aiura, H.; Asahi, S. (Idemitsu Kosan Co. Ltd., Jpn.). Eur. Pat. Appl. 445 755 A2, 1991. (d) Goodall, B. L.; Benedikt, L. H.; McIntosh, L. H., III; Barnes, D. A.; Rhodes, L. F. (BFGoodrich). Patent WO 95/14048, 1995. (e) Goodall, B. L.; Benedikt, G. M.; McIntosh, L. H., III; Barnes, D. A. (BFGoodrich) U.S. Patent 5 468 819, 1995
39. Addition homopolymers and block copolymers of diethyrl-7-oxabicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylates serving as precursor polymers to polyacetylenes have been prepared with π-stabilized Pd(II) alkyl complexes: (a) Safir, A. L.; Novak, B. M. Macromolecules 1995, 28, 5396. (b) Safir, A L.; Novak, B. M. Macromolecules 1993, 26, 4072. Ni- and Pd-catalyzed polymerization of predominantly alkyl-substituted norbornene derivatives have recently been described in the following: (c) Maezawa, H.; Mataoawto, J.; Aiura, H.; Asahi, S. (Idemitsu Kosan Co. Ltd., Jpn.). Eur. Pat. Appl. 445 755 A2, 1991. (d) Goodall, B. L.; Benedikt, L. H.; McIntosh, L. H., III; Barnes, D. A.; Rhodes, L. F. (BFGoodrich). Patent WO 95/14048, 1995. (e) Goodall, B. L.; Benedikt, G. M.; McIntosh, L. H., III; Barnes, D. A. (BFGoodrich) U.S. Patent 5 468 819, 1995
40. Addition homopolymers and block copolymers of diethyrl-7-oxabicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylates serving as precursor polymers to polyacetylenes have been prepared with π-stabilized Pd(II) alkyl complexes: (a) Safir, A. L.; Novak, B. M. Macromolecules 1995, 28, 5396. (b) Safir, A L.; Novak, B. M. Macromolecules 1993, 26, 4072. Ni- and Pd-catalyzed polymerization of predominantly alkyl-substituted norbornene derivatives have recently been described in the following: (c) Maezawa, H.; Mataoawto, J.; Aiura, H.; Asahi, S. (Idemitsu Kosan Co. Ltd., Jpn.). Eur. Pat. Appl. 445 755 A2, 1991. (d) Goodall, B. L.; Benedikt, L. H.; McIntosh, L. H., III; Barnes, D. A.; Rhodes, L. F. (BFGoodrich). Patent WO 95/14048, 1995. (e) Goodall, B. L.; Benedikt, G. M.; McIntosh, L. H., III; Barnes, D. A. (BFGoodrich) U.S. Patent 5 468 819, 1995
41. 1H NMR signals are shifted from δ = 3.61 and 3.81 to 3.92 and 4.07 ppm, respectively.
42. (a) Robert, J. D.; Trumbull, E. R, Jr.; Bennett, R.; Armstrong, R. J. Am. Chem. Soc. 1950, 72, 3116.
43. (b) Ver Nooy, C. D.; Rondeatvedt, C. S., Jr. J. Am. Chem. Soc. 1955, 77, 3586.
44. (c) Arjona, O.; de la Pradilla, R. F.; Plumet, J.; Viso, A. J. Org. Chem. 1991, 56, 6227.
45. (d) Nelson, G. L.; Kuo, C.-L. Syatheasis 1975, 105.
46. (e) Magoon, E. F.; Slaugh, L. H. J. Organomet. Chem. 1973, 55, 409
47. 3-ally)palladium cholride dimer with silver salts, eg.: Akermark, B.; Krakenberger, B.; Hansson, S.; Vitagliano, A. Organometallics 1987, 6, 620.
48. 1H NMR data show that the Pd-F interaction is stroonger in complex IIb.
49. Stable transition metal complexes containing tetrafluoroborate or hexafluoroantimonate as weakly coordinating ligands have been isolated and characterized by X-ray crystallography and NMR and IR spectroscopy, e.g.: (a) Hersh, W. H. Inorg. Chem. 1990, 29, 713. (b) Honeychuck, R. V.; Hersh, W. H. Inorg. Chem. 1989, 28, 2869. (c) Beck, W.; Sünkel, K. Chem. Rev. 1988, 88, 1405. (d) Horn, E.; Snow, M. R.; Tiekink, E. Aust. J. Chem. 1987, 40, 761 (e) Hersh, W. H. J. Am. Chem. Soc. 1985, 107, 4599. (f) Shelly, K.; Bartczak, T.; Scheidt, W. R.; Reed. C. A. Inorg. Chem. 1985, 24, 4325. (g) Yamamoto, Y.; Aoki, K.; Yamazaki, H. Inorg. Chem. Acta 1982, 68. 75. (h) Mattaon, B. M.; Graham, W. A. G. Inorg. Chem. 1981, 20, 3186. (i) Roulet, R.; Vouillamoz, R. Helv. Chim. Acta 1974, 57, 2139.
50. Stable transition metal complexes containing tetrafluoroborate or hexafluoroantimonate as weakly coordinating ligands have been isolated and characterized by X-ray crystallography and NMR and IR spectroscopy, e.g.: (a) Hersh, W. H. Inorg. Chem. 1990, 29, 713. (b) Honeychuck, R. V.; Hersh, W. H. Inorg. Chem. 1989, 28, 2869. (c) Beck, W.; Sünkel, K. Chem. Rev. 1988, 88, 1405. (d) Horn, E.; Snow, M. R.; Tiekink, E. Aust. J. Chem. 1987, 40, 761 (e) Hersh, W. H. J. Am. Chem. Soc. 1985, 107, 4599. (f) Shelly, K.; Bartczak, T.; Scheidt, W. R.; Reed. C. A. Inorg. Chem. 1985, 24, 4325. (g) Yamamoto, Y.; Aoki, K.; Yamazaki, H. Inorg. Chem. Acta 1982, 68. 75. (h) Mattaon, B. M.; Graham, W. A. G. Inorg. Chem. 1981, 20, 3186. (i) Roulet, R.; Vouillamoz, R. Helv. Chim. Acta 1974, 57, 2139.
51. Stable transition metal complexes containing tetrafluoroborate or hexafluoroantimonate as weakly coordinating ligands have been isolated and characterized by X-ray crystallography and NMR and IR spectroscopy, e.g.: (a) Hersh, W. H. Inorg. Chem. 1990, 29, 713. (b) Honeychuck, R. V.; Hersh, W. H. Inorg. Chem. 1989, 28, 2869. (c) Beck, W.; Sünkel, K. Chem. Rev. 1988, 88, 1405. (d) Horn, E.; Snow, M. R.; Tiekink, E. Aust. J. Chem. 1987, 40, 761 (e) Hersh, W. H. J. Am. Chem. Soc. 1985, 107, 4599. (f) Shelly, K.; Bartczak, T.; Scheidt, W. R.; Reed. C. A. Inorg. Chem. 1985, 24, 4325. (g) Yamamoto, Y.; Aoki, K.; Yamazaki, H. Inorg. Chem. Acta 1982, 68. 75. (h) Mattaon, B. M.; Graham, W. A. G. Inorg. Chem. 1981, 20, 3186. (i) Roulet, R.; Vouillamoz, R. Helv. Chim. Acta 1974, 57, 2139.
52. Stable transition metal complexes containing tetrafluoroborate or hexafluoroantimonate as weakly coordinating ligands have been isolated and characterized by X-ray crystallography and NMR and IR spectroscopy, e.g.: (a) Hersh, W. H. Inorg. Chem. 1990, 29, 713. (b) Honeychuck, R. V.; Hersh, W. H. Inorg. Chem. 1989, 28, 2869. (c) Beck, W.; Sünkel, K. Chem. Rev. 1988, 88, 1405. (d) Horn, E.; Snow, M. R.; Tiekink, E. Aust. J. Chem. 1987, 40, 761 (e) Hersh, W. H. J. Am. Chem. Soc. 1985, 107, 4599. (f) Shelly, K.; Bartczak, T.; Scheidt, W. R.; Reed. C. A. Inorg. Chem. 1985, 24, 4325. (g) Yamamoto, Y.; Aoki, K.; Yamazaki, H. Inorg. Chem. Acta 1982, 68. 75. (h) Mattaon, B. M.; Graham, W. A. G. Inorg. Chem. 1981, 20, 3186. (i) Roulet, R.; Vouillamoz, R. Helv. Chim. Acta 1974, 57, 2139.
53. Stable transition metal complexes containing tetrafluoroborate or hexafluoroantimonate as weakly coordinating ligands have been isolated and characterized by X-ray crystallography and NMR and IR spectroscopy, e.g.: (a) Hersh, W. H. Inorg. Chem. 1990, 29, 713. (b) Honeychuck, R. V.; Hersh, W. H. Inorg. Chem. 1989, 28, 2869. (c) Beck, W.; Sünkel, K. Chem. Rev. 1988, 88, 1405. (d) Horn, E.; Snow, M. R.; Tiekink, E. Aust. J. Chem. 1987, 40, 761 (e) Hersh, W. H. J. Am. Chem. Soc. 1985, 107, 4599. (f) Shelly, K.; Bartczak, T.; Scheidt, W. R.; Reed. C. A. Inorg. Chem. 1985, 24, 4325. (g) Yamamoto, Y.; Aoki, K.; Yamazaki, H. Inorg. Chem. Acta 1982, 68. 75. (h) Mattaon, B. M.; Graham, W. A. G. Inorg. Chem. 1981, 20, 3186. (i) Roulet, R.; Vouillamoz, R. Helv. Chim. Acta 1974, 57, 2139.
54. Stable transition metal complexes containing tetrafluoroborate or hexafluoroantimonate as weakly coordinating ligands have been isolated and characterized by X-ray crystallography and NMR and IR spectroscopy, e.g.: (a) Hersh, W. H. Inorg. Chem. 1990, 29, 713. (b) Honeychuck, R. V.; Hersh, W. H. Inorg. Chem. 1989, 28, 2869. (c) Beck, W.; Sünkel, K. Chem. Rev. 1988, 88, 1405. (d) Horn, E.; Snow, M. R.; Tiekink, E. Aust. J. Chem. 1987, 40, 761 (e) Hersh, W. H. J. Am. Chem. Soc. 1985, 107, 4599. (f) Shelly, K.; Bartczak, T.; Scheidt, W. R.; Reed. C. A. Inorg. Chem. 1985, 24, 4325. (g) Yamamoto, Y.; Aoki, K.; Yamazaki, H. Inorg. Chem. Acta 1982, 68. 75. (h) Mattaon, B. M.; Graham, W. A. G. Inorg. Chem. 1981, 20, 3186. (i) Roulet, R.; Vouillamoz, R. Helv. Chim. Acta 1974, 57, 2139.
55. Stable transition metal complexes containing tetrafluoroborate or hexafluoroantimonate as weakly coordinating ligands have been isolated and characterized by X-ray crystallography and NMR and IR spectroscopy, e.g.: (a) Hersh, W. H. Inorg. Chem. 1990, 29, 713. (b) Honeychuck, R. V.; Hersh, W. H. Inorg. Chem. 1989, 28, 2869. (c) Beck, W.; Sünkel, K. Chem. Rev. 1988, 88, 1405. (d) Horn, E.; Snow, M. R.; Tiekink, E. Aust. J. Chem. 1987, 40, 761 (e) Hersh, W. H. J. Am. Chem. Soc. 1985, 107, 4599. (f) Shelly, K.; Bartczak, T.; Scheidt, W. R.; Reed. C. A. Inorg. Chem. 1985, 24, 4325. (g) Yamamoto, Y.; Aoki, K.; Yamazaki, H. Inorg. Chem. Acta 1982, 68. 75. (h) Mattaon, B. M.; Graham, W. A. G. Inorg. Chem. 1981, 20, 3186. (i) Roulet, R.; Vouillamoz, R. Helv. Chim. Acta 1974, 57, 2139.
56. Stable transition metal complexes containing tetrafluoroborate or hexafluoroantimonate as weakly coordinating ligands have been isolated and characterized by X-ray crystallography and NMR and IR spectroscopy, e.g.: (a) Hersh, W. H. Inorg. Chem. 1990, 29, 713. (b) Honeychuck, R. V.; Hersh, W. H. Inorg. Chem. 1989, 28, 2869. (c) Beck, W.; Sünkel, K. Chem. Rev. 1988, 88, 1405. (d) Horn, E.; Snow, M. R.; Tiekink, E. Aust. J. Chem. 1987, 40, 761 (e) Hersh, W. H. J. Am. Chem. Soc. 1985, 107, 4599. (f) Shelly, K.; Bartczak, T.; Scheidt, W. R.; Reed. C. A. Inorg. Chem. 1985, 24, 4325. (g) Yamamoto, Y.; Aoki, K.; Yamazaki, H. Inorg. Chem. Acta 1982, 68. 75. (h) Mattaon, B. M.; Graham, W. A. G. Inorg. Chem. 1981, 20, 3186. (i) Roulet, R.; Vouillamoz, R. Helv. Chim. Acta 1974, 57, 2139.
57. Stable transition metal complexes containing tetrafluoroborate or hexafluoroantimonate as weakly coordinating ligands have been isolated and characterized by X-ray crystallography and NMR and IR spectroscopy, e.g.: (a) Hersh, W. H. Inorg. Chem. 1990, 29, 713. (b) Honeychuck, R. V.; Hersh, W. H. Inorg. Chem. 1989, 28, 2869. (c) Beck, W.; Sünkel, K. Chem. Rev. 1988, 88, 1405. (d) Horn, E.; Snow, M. R.; Tiekink, E. Aust. J. Chem. 1987, 40, 761 (e) Hersh, W. H. J. Am. Chem. Soc. 1985, 107, 4599. (f) Shelly, K.; Bartczak, T.; Scheidt, W. R.; Reed. C. A. Inorg. Chem. 1985, 24, 4325. (g) Yamamoto, Y.; Aoki, K.; Yamazaki, H. Inorg. Chem. Acta 1982, 68. 75. (h) Mattaon, B. M.; Graham, W. A. G. Inorg. Chem. 1981, 20, 3186. (i) Roulet, R.; Vouillamoz, R. Helv. Chim. Acta 1974, 57, 2139.
58. Colsman, M. R.; Newbound, T. D.; Marahall, L. J.; Noirot, M. D.; Miller, M. M.; Wulfsberg, G. P.; Frye, J. S.; Anderson, O. P.; Strauss, S. H. J. Am. Chem. Soc. 1990, 112, 2349.
59. Fernándz, J. M.; Gladyaz, J. A. Inorg. Chem. 1986, 25, 2672.
60. Very high molecular weights, a higher stereoregularity, or a small amount of potential side reactions with the ester groups can be rasponsible for the low soludilitiy of copolyimers when the activity of catalyst IIa is not moderated.
61. 11 A nearly linear relationship between molecular weight and the mole ratio of monoamer to Pd catalyst wae found for polymerizations with the nitrile-based Pd catalysts. The polydispersities of poly-1a,b,f obtained with monomer to Pd catalyst ratios below 200/1 were in the range of 1-2-1.6.
62. n(GPC) of 55 000 (GPC calibrated with polystyrene).
63. Schramm, R. F.; Wayland, B. B. J. Chem. Soc., Chem. Commun. 1968, 898.
64. Dent, W. T.; Long, R.; Wilkinson, A. J. J. Chem. Soc. 1964, 1585.