Silane-promoted cycloisomerization of functionalized 1,6-dienes catalyzed by a cationic (π-allyl)palladium complex

Organic Letters

Volumn 1, Issue 7, 1999, Pages 1103-1105

  Widenhoefer, Ross A ^a   Perch, Nicholas S ^a  

^a DUKE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001461972     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol9908981     Document Type: Article

References (33)

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27. 14c Because no ether is present in the boronate salt, the exact structure of the cationic species generated from 1c and 1d is unknown.
28. 2, 12:1 hexane -EtOAc) to give 3 (89 mg, 89%) as a colorless oil.
29. For example, dimethyl-tert-butylsilane failed to promote cycloisomerization, while employment of dimethylphenylsilane led to 58% yield for conversion of 2 to 3.
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