Hemilabile phosphines by methyl acrylate insertion into the P-H bonds of palladium(I)-coordinated secondary phosphines. Labile anion (X = OTf) vs PO-chelate coordination (X = BF4) in Pd2(μ-PR2)(PR2R′)2(X) (R = But, R′ = CH2CH2COOMe; X = OTf, BF4)

Organometallics

Volumn 19, Issue 16, 2000, Pages 3062-3068

  Leoni, Piero ^a   Vichi, Elettra ^a   Lencioni, Solange ^a   Pasquali, Marco ^a   Chiarentin, Enea ^b   Albinati, Alberto ^b  

^a UNIVERSITY OF PISA   (Italy)

^b UNIVERSITY OF MILAN   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

CHELATION; CRYSTAL STRUCTURE; HYDROGEN BONDS; ISOMERS; MOLECULAR STRUCTURE; NEGATIVE IONS; PALLADIUM; PHOSPHORUS COMPOUNDS; X RAY CRYSTALLOGRAPHY;

CHELATE COORDINATION; LABILE ANION; PHOSPHINES;

ORGANOMETALLICS;

EID: 0034246695     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000294x     Document Type: Article

References (4)

1. (1)(a) Houben-Weyl. Metoden der Organischen Chemie; Georg Thieme Verlag: Stuttgart, 1982; Band El, p 113.
2. (b) Gilheany, D. G.; Mitchell, C. M. In The Chemistry of Organophosphorus Compounds; Hartley, F. R., Ed.; John Wiley & Sons: New York, 1990; Vol. 1, p 151.
3. (a) Bourumeau, K.; Gaumont, A. C.; Denis, J. M. J. Organomet. Chem. 1997, 529, 205.
4. (b) Bourumeau, K.; Gaumont, A. C.; Denis, J. M. Tetrahedron Lett. 1997, 1923.