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Volumn 46, Issue 1, 2007, Pages 221-230

Supramolecular assemblies of trinuclear triangular copper(II) secondary building units through hydrogen bonds. Generation of different metal-organic frameworks, valuable catalysts for peroxidative oxidation of alkanes

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EID: 33846412925     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic061595n     Document Type: Article
Times cited : (185)

References (83)
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    • Figure 1 has been obtained by using the CIF file supplied as Supporting Information in ref 8b, to which are also referred the here used atom labels.
    • Figure 1 has been obtained by using the CIF file supplied as Supporting Information in ref 8b, to which are also referred the here used atom labels.
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    • In compounds reported in refs 8 Cu(II) ions display mostly the penta-and sometime hexacoordination, reached through supramolecular interactions of carboxylates of nearby trinuclear units or through the coordination of water or alcohols.
    • In compounds reported in refs 8 Cu(II) ions display mostly the penta-and sometime hexacoordination, reached through supramolecular interactions of carboxylates of nearby trinuclear units or through the coordination of water or alcohols.
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    • Indicated values don't take into account v.d.W radii of involved atoms.
    • Indicated values don't take into account v.d.W radii of involved atoms.
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    • It is noteworthy that if compound 1b is dissolved in water and the solution left to evaporate at ca. 18°C, dark blue crystals of 1c are obtained. It is likely that at ca. 12°C, one molecule of water remains frozen into the crystal lattice, with the help of above described H-bonds.
    • It is noteworthy that if compound 1b is dissolved in water and the solution left to evaporate at ca. 18°C, dark blue crystals of 1c are obtained. It is likely that at ca. 12°C, one molecule of water remains "frozen" into the crystal lattice, with the help of above described H-bonds.
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    • In the description of the dimensionalities of all reported MOFs here, the trinuclear triangular moieties are considered a 0-D cluster
    • In the description of the dimensionalities of all reported MOFs here, the trinuclear triangular moieties are considered a 0-D cluster.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.