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Volumn 44, Issue 18, 2005, Pages 6265-6276

One-dimensional and two-dimensional coordination polymers from self-assembling of trinuclear triangular cu(II) secondary building units

Author keywords

[No Author keywords available]

Indexed keywords

COPPER; POLYMER; PYRAZOLE; PYRAZOLE DERIVATIVE;

EID: 24944510399     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic050678l     Document Type: Article
Times cited : (142)

References (66)
  • 38
    • 0012039373 scopus 로고
    • National High Magnetic Field Laboratory, Los Alamos National Laboratory: Los Alamos, NM
    • Senko, M. W. IsoPro Isotopic Abundance Simulator, version 2.1; National High Magnetic Field Laboratory, Los Alamos National Laboratory: Los Alamos, NM, 1994.
    • (1994) IsoPro Isotopic Abundance Simulator, Version 2.1
    • Senko, M.W.1
  • 47
    • 24944516945 scopus 로고    scopus 로고
    • note
    • In Scheme 2, in the case of compound 3, the product obtained after recrystallization in methanol is indicated.
  • 54
    • 24944561861 scopus 로고    scopus 로고
    • note
    • -. One molecule of crystallization water for each trinuclear unit is present in both compounds.
  • 55
    • 24944559675 scopus 로고    scopus 로고
    • note
    • The analysis of these particular bonding features deserves a deeper examination and will be the subject of a forthcoming paper.
  • 57
    • 24944581576 scopus 로고    scopus 로고
    • see ref 7
    • It is noteworthy that the solid-state UV-vis spectra of 1-3 are almost identical to that of A (see ref 7).
  • 59
    • 24944591762 scopus 로고    scopus 로고
    • note
    • Even if this is strictly true for 2 and 3, the pentacoordination of Cu(3) in 1 involves a weakly bonded apical O(5) atom of an adjacent zigzag chain positioned at 2.772 Å from it.
  • 62
    • 24944539541 scopus 로고    scopus 로고
    • see ref 7
    • Hirshfeld charges of Cu(1), Cu(2), and Cu(3) are 0.43, 0.38, and 0.37, respectively, in 1; 0.44, 0.41, and 0.43, respectively, in 2; 0.42, 0.45, and 0.41, respectively, in 3; and 0.41, 0.41, and 0.39, respectively, in A (for the last compound see ref 7).
  • 65
    • 24944570020 scopus 로고    scopus 로고
    • note
    • Cu(1) in 2 and Cu(3) in 3 present a slightly distorted square planar tetracoordination, whereas for Cu(3) in 1, see Results and Discussion.
  • 66
    • 24944577381 scopus 로고    scopus 로고
    • see Figure 7a. see Figure 7b
    • The 28-membered macrocycles present in compound A form channels that are in large part obstructed by pyrazolate moieties (see Figure 7a). Possibly more interesting and, at the present, under examination are the interlayer voids present in the same compound (see Figure 7b).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.