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Volumn 44, Issue 25, 2005, Pages 3845-3848

A metal-organic framework with the zeolite MTN topology containing large cages of volume 2.5 nm3

Author keywords

Cadmium; Coordination polymers; Organic inorganic hybrid composites; Zeolite analogues

Indexed keywords

COMPLEXATION; MOLECULAR STRUCTURE; ZEOLITES;

EID: 21244476814     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200462260     Document Type: Article
Times cited : (210)

References (41)
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    • Non-hydrogen atoms were refined anisotropically. Hydrogen atoms were fixed at calculated positions and refined in a riding mode. Final R1 value 0.1891 (0.0799 after SQUEEZE) for 3121 independent reflections (I>2σ(I)). The solvent-accessible volume was assessed using the PLATON software (A. L. Spek, Acta Crystallogr., Sect. A 1990, 46, C34)
    • (1990) Acta Crystallogr., Sect. A , vol.46
    • Spek, A.L.1
  • 30
    • 84942435207 scopus 로고
    • and the contribution of the chlorine anions and the disordered solvent to the diffraction pattern was subtracted from the observed data by the "SQUEEZE" method as implemented in PLATON (P. van der Sluis, A. L. Spek, Acta Crystallogr., Sect. A 1990, 46, 194).
    • (1990) Acta Crystallogr., Sect. A , vol.46 , pp. 194
    • Van Der Sluis, P.1    Spek, A.L.2
  • 31
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    • The SQUEEZE-bypass method referred to therein is widely used in crystallographic analysis of compounds containing substantial amounts of disordered solvent that cannot be located precisely from diffraction data. CCDC-253194 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_ request/cif.
  • 35
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    • note
    • -4 mol of cadmium.
  • 36
    • 21244504143 scopus 로고    scopus 로고
    • note
    • -4 mol of chlorine per gram of complex.
  • 37
    • 21244506465 scopus 로고    scopus 로고
    • note
    • 68: C 22.61, H 6.05, N 11.72; found: C 22.53, H 6.11, N 11.65.
  • 38
    • 21244481990 scopus 로고    scopus 로고
    • note
    • C=O and the asymmetric stretching vibration of the methyl group of the guest DMF molecules, respectively.) Decomposition of 1 began above 300°C.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.