Nanocluster formation and stabilization fundamental studies: Investigating "solvent-only" stabilization en route to discovering stabilization by the traditionally weakly coordinating anion BF4- plus high dielectric constant solvents

Inorganic Chemistry

Volumn 45, Issue 20, 2006, Pages 8382-8393

  Ott, Lisa Starkey ^a   Finke, Richard G ^a  

^a Department of Environmental and Radiological Health Sciences   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33750337236     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic060876s     Document Type: Article

References (126)

1. For, reviews of nanoclusters, see: (a) Astruc, D.; Lu, F.; Aranzes, J. R. Angew Chem., Int. Ed. 2005, 44, 7852.
2. (b) Burda, C.; Chen, X.; Narayanan, R.; El-Sayed, M. A. Chem. Rev. 2005, 105, 1025.
3. (c) Murphy, C. J.; Sau, T. K.; Gole, A. M.; Orendorff, C. J.; Gao, J.; Gou, L.; Hunyadi, S. E.; Li, T. J. Phys. Chem. B 2005, 109, 13857.
4. (d) Green, M. Chem. Commun. 2005, 24, 3002.
5. (e) Narayanan, R.; El-Sayed, M. A. J. Phys. Chem. B 2005, 109, 12663.
6. (f) Cushing, B. L.; Kolesnichenko, V. L.; O'Connor, C. J. Chem. Rev. 2004, 104, 3893.
7. (g) Shenhar, R.; Rotello, V. M. Acc. Chem. Res. 2003, 36, 549.
8. (h) Roucoux, A.; Schulz, J.; Patin, H. Chem. Rev. 2002, 102, 3757.
9. (i) Králik, M.; Biffis, A. J. Mol. Catal. A 2001, 177, 113.
10. (j) Rao, C. N. R.; Kulkarni, G. U.; Thomas, P. J.; Edwards, P. P. Chem. Soc. Rev. 2000, 29, 27.
11. (k) Schmid, G.; Baumle, M.; Geerkens, M.; Heim, I.; Osemann, C.; Sawitowski, T. Chem. Soc. Rev. 1999, 28, 179.
12. (l) Schmid, G.; Chi, L. F. Adv. Mater. 1998, 10, 515.
13. (m) Fendler, J. H., Ed. Nanoparticles and Nanostructured Films; Wiley-VCH: Weinheim, Germany, 1998.
14. (n) Fürstner, A., Ed. Active Metals: Preparation, Characterization, and Applications; VCH: Weinheim, Germany, 1996.
15. (o) Bradley, J. S. In Clusters and Colloids. From Theory to Applications; Schmid, G., Ed.; VCH: New York, 1994; p 459-544.
16. (p) Schmid, G. Chem. Rev. 1992, 92, 1709.
17. (q) A superb series of papers, complete with a record of the insightful comments by the experts attending the conference, is available in Faraday Discuss. 1991, 92, 1-300.
18. (r) Schmid, G. In Aspects of Homogeneous Catalysis; Ugo, R., Ed.; Kluwer: Dordrecht, The Netherlands, 1990; Chapter 1.
19. (s) Andres, R. P.; Averback, R. S.; Brown, W. L.; Brus, L. E.; Goddard, W. A., III; Kaldor, A.; Louie, S. G.; Moscovits, M.; Peercy, P. S.; Riley, S. J.; Siegel, R. W.; Spaepen, F.; Wang, Y. J. Mater. Res. 1989, 4, 704.
20. (t) Henglein, A. Chem. Rev. 1989, 89, 1861.
21. (u) Thomas, J. M. Pure Appl. Chem. 1988, 60, 1517.
22. (v) Jena, P.; Rao B. K.; Khanna, S. N. Physics and Chemistry of Small Clusters; Plenum: New York, 1987.
23. Elghanian, R.; Storhoff, J. J.; Mucic, R. C.; Letsinger, R. L.; Mirkin, C. A. Science 1997, 277, 1078.
24. Glanz, J. Science 1995, 269, 1363.
25. Finke, R. G. In Metal Nanoparticles: Synthesis, Characterization, and Applications; Feldheim, D. L., Foss, C. A., Jr., Eds.; Marcel Dekker: New York, 2002; Chapter 2, pp 17-54.
26. (a) Bönneman, H.; Korall, B. Angew. Chem., Int. Ed. 1992, 31, 1490.
27. (b) Franke, R.; Rothe, J.; Pollman, J.; Hormes, J.; Bonneman, H.; Brijoux, W.; Hindenburg, T. J. Am. Chem. Soc. 1996, 118, 12090.
28. Vidoni, O.; Philippot, K.; Amiens, C.; Chaudret, B.; Balmes, O.; Malam, J.-O.; Bovin, J.-O.; Senocq, F.; Casanove, M.-J. Angew. Chem., Int. Ed. 1999, 38, 3736.
29. Collier, P. J.; Iggo, J. A.; Whyman, R. J. Mol. Catal. A 1999, 146, 149.
30. Wang, Y.; Ren, J.; Deng, K.; Gi, L.; Tang, Y. Chem. Mater. 2000, 12, 1622.
31. Curtis, A. C.; Duff, D. G.; Edwards, P. P.; Jefferson, D. A.; Johnson, B. F. G.; Kirkland, A. I.; Wallace, A. S. J. Phys. Chem. 1988, 92, 2270.
32. Pelzer, K.; Vidoni, O.; Philippot, K.; Chaudret, B.; Colliere, V. Adv. Funct. Mater. 2003, 13, 118.
33. Reetz, M. T.; Lohmer, G. Chem. Commun. 1996, 16, 1921.
34. Cardenas-Trivino, G.; Klabunde, K. J.; Dale, E. B. Langmuir 1987, 3, 986.
35. Esumi, K.; Tano, T.; Meguro, K. Langmuir 1989, 5, 268.
36. He, B.; Chen, Y.; Liu, H.; Liu, Y. J. Nanosci. Nanotech. 2005, 5, 266.
37. Toshima, N.; Shiraishi, Y.; Teranishi, T.; Miyake, M.; Tominaga, T.; Watanabe, H.; Brijoux, W.; Bönnemann, H.; Schmid, G. Appl. Organomet. Chem. 2001, 15, 178.
38. Özkar, S.; Finke, R. G. J. Am. Chem. Soc. 2002, 124, 5796.
39. Özkar, S.; Finke, R. G. Langmuir 2002, 18, 7653.
40. Aiken, J. D., III; Finke, R. G. J. Mol. Catal. A 1999, 145, 1.
41. Verwey, E. J. W.; Overbeek, J. T. G. Theory of the Stability of Lyophobic Colloids, 2 ed.; Dover Publications: Mineola, New York, 1999.
42. Ninham, B. W. Adv. Coll. Int. Sci. 1999, 83, 1.
43. 19
44. Evans, D. F.; Wennerström, H. The Colloidal Domain, 2nd ed.; Wiley-VCH: New York, 1999.
45. 20
46. Ott, L. S.; Hornstein, B. J.; Finke, R. G. A Test of the Transition-Metal Nanocluster Formation and Stabilization Ability of the Most Common Polymeric Stabilizer, Poly(vinylpyrrolidone), As Well As Four Other Polymeric Protectants. Langmuir, in press.
47. Besson, C.; Finney, E. E.; Finke, R. G. J. Am. Chem. Soc. 2005, 127, 8179.
48. Enüstün, B. V.; Turkevich, J. J. Am. Chem. Soc. 1963, 85, 3317.
49. Zsigmondy, R. Z. Anal. Chem. 1901, 697.
50. Theile, H.; von Levern, H. S. J. Coll. Sci. 1965, 20, 679.
51. Meakin, P. Adv. Coll. Int. Sci. 1988, 28, 249.
52. 4], or with Varying Temperature? manuscript in preparation.
53. 25 that supports the general notion of particle-size-dependent stabilization effects.
54. 32e Ni(1,5-COD)2, with stabilizing but displaceable ligands are what is needed here. (b) Ozkar, S.; Graham, C. R.; Finke, R. G. Unpublished results and experiments in progress.
55. 2 treatments were unsucessful. Kim, F.; Connor, S.; Song, H.; Kuykendall, T.; Yang, P. Angew. Chem., Int. Ed. 2004, 43, 3673;
56. Song, H.; Kim, F.; Connor, S.; Somorjai, G. A.; Yang, P. J. Phys. Chem. B 2005, 109, 188;
57. Rioux, R. M.; Song, H.; Hoefelmeyer, J. D.; Yang, P.; Somorjai, G. A. J. Phys. Chem. B 2005, 109, 2192;
58. Song, H.; Rioux, R. M.; Hoefelmeyer, J. D.; Komor, R.; Niesz, K.; Grass, M.; Yang, P.; Somorjai, G. A. J. Am. Chem. Soc. 2006, 128, 3027.
59. (d) Yang, G. K.; Peters, K. S.; Vaida, V. Chem. Phys. Lett. 1986, 125, 566;
60. Simon, J. D.; Xie, X. J. Phys. Chem. 1989, 93, 291-293;
61. Morse, J. M., Jr.; Parker, G. H.; Burkey, T. J. Organometallics 1989, 8, 2471.
62. (e) Fischer, K.; Jonas, K.; Misbach, P.; Stabba, R.; Wilke, G. Angew. Chem., Int. Ed. Engl. 1973, 12, 943;
63. Wilke, G. Angew. Chem., Int. Ed. Engl. 1988, 27, 185.
64. Platt, J. Science 1965, 146, 347.
65. Bucher, S.; Hormes, J.; Modrow, H.; Brinkman, R.; Waldöfner, N.; Bönnemann, H.; Beuermann, L.; Krischok, S.; Maus-Friedrichs, W.; Kempter, V. Surf. Sci. 2002, 497, 321.
66. Modrow, H.; Bucher, S.; Hormes, J.; Brinkmann, R.; Bönnemann, H. J. Phys. Chem. B. 2003, 107, 3684.
67. Pez, G. P.; Armor, J. N. Adv. Organomet. Chem. 1981, 19, 1.
68. Pery, T.; Pelzer, K.; Buntkowsky, G.; Philippot, K.; Limbach, H.-H.; Chaudret, B. ChemPhysChem 2005, 6, 605.
69. Pan, C.; Pelzer, K.; Philippot, K.; Chaudret, B.; Dassenoy, F.; Lecante, P.; Casanove, M.-J. J. Am. Chem. Soc. 2001, 123, 7584.
70. Dhas, N. A.; Cohen, H.; Gedanken, A. J. Phys. Chem. B 1997, 101, 6834.
71. 19 remains the only predictive tool for colloidal stability (and predicts solvent effects based solely on ε), we initially chose for study the solvents in Table 1 herein because of their widely varying dielectric constants.
72. Gutmann, V. Coord. Chem. Rev. 1976, 18, 225.
73. 2 (see Figure S1 of the Supporting Information).
74. Watzky, M. A.; Finke, R. G. J. Am. Chem. Soc. 1997, 119, 10382.
75. Widegren, J. A.; Aiken, J. D., III; Özkar, S.; Finke, R. G. Chem. Mater. 2001, 13, 312.
76. Creighton, J. A.; Eadon, D. G. J. Chem. Soc., Faraday Trans. 1991, 87, 3881.
77. Umpierre, A. P.; Machado, G.; Fecher, G. H.; Morais, J.; Dupont, J. Adv. Synth. Catal. 2005, 347, 1404.
78. Özkar, S.; Finke, R. G. Coord. Chem. Rev. 2004, 248, 135.
79. Parks, E. K.; Nieman, G. C.; Kerns, K. P.; Riley, S. J. J. Chem. Phys. 1998, 108, 3731.
80. 1 ratio, TEM, and visual observation and because PC is more amenable to work with than NMA (NMA has an inconveniently high melting point of 28°C and thus frequently crystallizes in syringe needles).
81. Lin, Y.; Finke, R. G. J. Am. Chem. Soc. 1994, 116, 8335.
82. For a homogeneous Ir-F complex, the Ir-F bond is observed at -219.3 ppm. Gorol, M.; Mösch-Zaetti, N. C.; Roesky, H. W.; Noltemeyer, M.; Schmidt, H.-D. Eur. J. Inorg. Chem. 2004, 13, 2678
83. Pelzer, K.; Laleu, B.; Lefebvre, F.; Philippot, K.; Chaudret, B.; Candy, J. P.; Basset, J. M. Chem. Mater. 2004, 16, 4937.
84. Reed, C. A. Acc. Chem. Res. 1998, 31, 133.
85. Strauss, S. H. Chem. Rev. 1993, 93, 927.
86. Köhler, J. U.; Bradley, J. S. Catal. Lett. 1997, 45, 203.
87. Ott, L. S.; Cline, M. L.; Deetlefs, M.; Seddon, K. R.; Finke, R. G. J. Am. Chem. Soc. 2005, 127, 5758.
88. Rampino, L. D.; Nord, F. F. J. Am. Chem. Soc. 1941, 63, 2745.
89. (b) Rampino, L. D.; Nord, F. F. J. Am. Chem. Soc. 1941, 63, 3268.
90. 60
91. Chisholm, M. H.; Navarro-Llobet, D.; Zhou, Z. Macromolecules 2002, 35, 6494.
92. Zhu, Q.; Meng, Y. Z.; Tjong, S. C.; Zhao, X. S.; Chen, Y. L. Polym. Int. 2002, 51, 1079.
93. Hanton, S. D. Chem. Rev. 2001, 101, 527.
94. 4 demonstrating the energetic nature of small metal(0) nanoclusters). (a) Cheetham, A. K., Day, P., eds. Solid State Chemistry Techniques; Clarendon Press: Oxford, U. K., 1987.
95. (b) Hornstein, B. J.; Finke, R. G. Chem. Mater. 2003, 15, 899.
96. Ott, L. S.; Finke, R. G. Coord. Chem. Rev. 2006, in press.
97. Özkar, S.; Finke, R. G. Langmuir 2003, 19, 6247.
98. n nanoclusters. This order of mixing, which promotes the formation of a 1:1 metal/polyanion complex, is also corroborated by our earlier work on supported organometallics. For example, see: Pohl, M.; Lyon, D. K.; Mizuno, N.; Nomiya, K.; Finke, R. G. Inorg. Chem. 1995, 34, 1413 and references therein.
99. Freas, R. B. J. Am. Chem. Soc. 1986, 108, 4659.
100. (b) Reetz, M. T.; Quaiser, S. A.; Winter, M.; Becker, J. A.; Schäfer, R.; Slimming, U.; Marmann, A.; Vogel, R.; Konno, T. Angew. Chem., Int. Ed. Engl. 1996, 35, 2092.
101. (c) Rothe, J.; Pollmann, J.; Franke, R.; Hormes, J.; Bönnemann, H.; Brijoux, W.; Siepen, K.; Richter, J. Fresenius' J. Anal. Chem. 1996, 355, 372.
102. (d) Kolb, U.; Quaiser, S. A.; Winter, M.; Reetz, M. T. Chem. Mater. 1996, 8, 1889.
103. (e) Stein, J.; Lewis, L. N.; Gao, Y.; Scott, R. A. J. Am. Chem. Soc. 1999, 121, 3693.
104. (f) Aiken, J. D., III; Finke, R. G. J. Mol. Catal. A 1999, 145, 1.
105. (g) Siepen, K.; Bönnemann, H.; Brijoux, W.; Rothe, J.; Hormes, J. Appl. Organomet. Chem. 2000, 14, 549.
106. (h) Ebitani, K.; Choi, K.-M.; Mizugaki, T.; Kaneda, K. Langmuir, 2002, 18, 1849.
107. Catalysis by heterogeneous metal oxide catalysts is well-known, see: (a) Maxted, E. B. Adv. Catal. 1951, 3, 129.
108. (b) Kiwi, J. Isr. J. Chem. 1979, 18, 369.
109. (c) Shannon, R. D.; Gier, T. E.; Carcia, P. F.; Bierstedt, P. E.; Flippen, R. B.; Vega, A. J. Inorg. Chem. 1982, 21, 3372.
110. (d) Lamber, R.; Romanowski, W. J. Catal. 1987, 105, 213.
111. (e) Naito, S.; Tanimoto, M. J. Chem. Soc., Chem. Commun. 1988, 832.
112. (f) Logan, A. D.; Sharoudi, K.; Datye, A. K. J. Phys. Chem. 1991, 95, 5568.
113. (g) Gai-Boyes, P. L. Catal. Rev. - Sci. Eng. 1992, 34, 1.
114. (h) Guo, X.-C.; Madix, R. J. J. Am. Chem. Soc. 1995, 117, 5523.
115. (i) Pal, T.; Sau, T. K.; Jana, N. R. Langmuir 1997, 13, 1481.
116. (j) Fuente, A. M.; Pulgar, G.; González, F.; Pesquera, C.; Blanco, C. Appl. Catal. A 2001, 208, 35.
117. Knecht, L. A.; Kolthoff, I. M. Inorg. Chem. 1962, 1, 195.
118. Perrin, D. D.; Armargo, W. L. F.; Perrin, D. R. Purification of Laboratory Chemicals, 2 ed.; Pergamon Press: Elmsford, New York, 1980.
119. Day, V. W.; Klemperer, W. G.; Main, D. J. Inorg. Chem. 1990, 29, 2345
120. Hornstein, B. J.; Finke, R. G. Inorg. Chem. 2002, 41, 2720.
121. Watzky, M. A.; Finke, R. G. Chem. Mater. 1997, 9, 3083.
122. Aiken, J. D., III; Finke, R. G. Chem. Mater. 1999, 11, 1035.
123. Aiken, J. D., III; Finke, R. G. J. Am. Chem. Soc. 1998, 120, 9545.
124. Widegren, J. A.; Finke, R. G. Inorg. Chem. 2002, 41, 1558.
125. Ivanov, S. V.; Rockwell, J. J.; Polyakov, O. G.; Gaudinski, C. M.; Anderson, O. P.; Solntsev, K. A.; Strauss, S. H. J. Am. Chem. Soc. 1998, 120, 4224.
126. 25 Also see: Besson, C.; Finney, E. E.; Finke, R. G. Chem. Mater. 2005, 17, 4925.