Nanocluster formation synthetic, kinetic, and mechanistic studies. The detection of, and the methods to avoid, hydrogen mass-transfer limitations in the synthesis of polyoxoanion- and tetrabutylammonium-stabilized, near- monodisperse 40 ± 6 Å Rh(0) nanoclusters

Journal of the American Chemical Society

Volumn 120, Issue 37, 1998, Pages 9545-9554

  Aiken III, John D ^a   Finke, Richard G ^a  

^a Department of Environmental and Radiological Health Sciences   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

NANOPARTICLE; POLYANION; TETRABUTYLAMMONIUM;

ARTICLE; CATALYSIS; DISPERSION; HYDROGENATION; ISOLATION PROCEDURE; PHASE TRANSITION; PROTON TRANSPORT; REACTION TIME; SYNTHESIS; TIME; TRANSMISSION ELECTRON MICROSCOPY;

EID: 0032560990     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9719485     Document Type: Article

References (13)

1. Reviews on nanoclusters: (a) Jena, P.; Rao B. K.; Khanna, S. N. Physics and Chemistry of Small Clusters; Plenum: New York, 1987. (b) Andres, R. P.; Averback, R. S.; Brown, W. L.; Brus, L. E.; Goddard, W. A.; Kaldor, A.; Louie S. G.; Moscovits, M.; Peercy, P. S.; Riley, S. J.; Siegel, R. W.; Spaepen, F.; Wang, Y. J. Mater. Res. 1989, 4, 704. This is a Panel Report from the United States Department of Energy, Council on Materials Science on "Research Opportunities on Clusters and Cluster-assembled Materials". (c) Thomas, J. M. Pure Appl. Chem. 1988, 60, 1517. (d) Henglein, A. Chem. Rev. 1989, 89, 1861. (e) A superb series of papers, complete with a record of the insightful comments by the experts attending the conference, is available in: Faraday Discuss. 1991, 92, 1-300. (f) Bradley, J. S. In Clusters and Colloids. From Theory to Applications; Schmid, G., Ed.; VCH: New York, 1994; pp 459-544. (g) Schmid, G. In Aspects of Homogeneous Catalysis; Ugo, R., Ed.; Kluwer: Dordrecht, 1990; Chapter 1. (h) Bönnemann, H.; Braun, G.; Brijoux, W.; Brinkmann, R.; Tilling, A. S.; Seevogel, K.; Siepen, K. J. Organomet. Chem. 1996, 520, 143-162 and the collection of "key publications" cited as refs 2-61 therein. (i) Active Metals: Preparation, Characterization, Applications; Fürstner, A., Ed.; VCH: Weinheim, 1996. (j) Schmid, G. in Applied Homogeneous Catalysis with Organometallic Compounds; Cornils, B., Herrmann, W. A., Eds.; VCH: Weinheim, 1996; Vol. 2.
2. Reviews on nanoclusters: (a) Jena, P.; Rao B. K.; Khanna, S. N. Physics and Chemistry of Small Clusters; Plenum: New York, 1987. (b) Andres, R. P.; Averback, R. S.; Brown, W. L.; Brus, L. E.; Goddard, W. A.; Kaldor, A.; Louie S. G.; Moscovits, M.; Peercy, P. S.; Riley, S. J.; Siegel, R. W.; Spaepen, F.; Wang, Y. J. Mater. Res. 1989, 4, 704. This is a Panel Report from the United States Department of Energy, Council on Materials Science on "Research Opportunities on Clusters and Cluster-assembled Materials". (c) Thomas, J. M. Pure Appl. Chem. 1988, 60, 1517. (d) Henglein, A. Chem. Rev. 1989, 89, 1861. (e) A superb series of papers, complete with a record of the insightful comments by the experts attending the conference, is available in: Faraday Discuss. 1991, 92, 1-300. (f) Bradley, J. S. In Clusters and Colloids. From Theory to Applications; Schmid, G., Ed.; VCH: New York, 1994; pp 459-544. (g) Schmid, G. In Aspects of Homogeneous Catalysis; Ugo, R., Ed.; Kluwer: Dordrecht, 1990; Chapter 1. (h) Bönnemann, H.; Braun, G.; Brijoux, W.; Brinkmann, R.; Tilling, A. S.; Seevogel, K.; Siepen, K. J. Organomet. Chem. 1996, 520, 143-162 and the collection of "key publications" cited as refs 2-61 therein. (i) Active Metals: Preparation, Characterization, Applications; Fürstner, A., Ed.; VCH: Weinheim, 1996. (j) Schmid, G. in Applied Homogeneous Catalysis with Organometallic Compounds; Cornils, B., Herrmann, W. A., Eds.; VCH: Weinheim, 1996; Vol. 2.
3. Reviews on nanoclusters: (a) Jena, P.; Rao B. K.; Khanna, S. N. Physics and Chemistry of Small Clusters; Plenum: New York, 1987. (b) Andres, R. P.; Averback, R. S.; Brown, W. L.; Brus, L. E.; Goddard, W. A.; Kaldor, A.; Louie S. G.; Moscovits, M.; Peercy, P. S.; Riley, S. J.; Siegel, R. W.; Spaepen, F.; Wang, Y. J. Mater. Res. 1989, 4, 704. This is a Panel Report from the United States Department of Energy, Council on Materials Science on "Research Opportunities on Clusters and Cluster-assembled Materials". (c) Thomas, J. M. Pure Appl. Chem. 1988, 60, 1517. (d) Henglein, A. Chem. Rev. 1989, 89, 1861. (e) A superb series of papers, complete with a record of the insightful comments by the experts attending the conference, is available in: Faraday Discuss. 1991, 92, 1-300. (f) Bradley, J. S. In Clusters and Colloids. From Theory to Applications; Schmid, G., Ed.; VCH: New York, 1994; pp 459-544. (g) Schmid, G. In Aspects of Homogeneous Catalysis; Ugo, R., Ed.; Kluwer: Dordrecht, 1990; Chapter 1. (h) Bönnemann, H.; Braun, G.; Brijoux, W.; Brinkmann, R.; Tilling, A. S.; Seevogel, K.; Siepen, K. J. Organomet. Chem. 1996, 520, 143-162 and the collection of "key publications" cited as refs 2-61 therein. (i) Active Metals: Preparation, Characterization, Applications; Fürstner, A., Ed.; VCH: Weinheim, 1996. (j) Schmid, G. in Applied Homogeneous Catalysis with Organometallic Compounds; Cornils, B., Herrmann, W. A., Eds.; VCH: Weinheim, 1996; Vol. 2.
4. Reviews on nanoclusters: (a) Jena, P.; Rao B. K.; Khanna, S. N. Physics and Chemistry of Small Clusters; Plenum: New York, 1987. (b) Andres, R. P.; Averback, R. S.; Brown, W. L.; Brus, L. E.; Goddard, W. A.; Kaldor, A.; Louie S. G.; Moscovits, M.; Peercy, P. S.; Riley, S. J.; Siegel, R. W.; Spaepen, F.; Wang, Y. J. Mater. Res. 1989, 4, 704. This is a Panel Report from the United States Department of Energy, Council on Materials Science on "Research Opportunities on Clusters and Cluster-assembled Materials". (c) Thomas, J. M. Pure Appl. Chem. 1988, 60, 1517. (d) Henglein, A. Chem. Rev. 1989, 89, 1861. (e) A superb series of papers, complete with a record of the insightful comments by the experts attending the conference, is available in: Faraday Discuss. 1991, 92, 1-300. (f) Bradley, J. S. In Clusters and Colloids. From Theory to Applications; Schmid, G., Ed.; VCH: New York, 1994; pp 459-544. (g) Schmid, G. In Aspects of Homogeneous Catalysis; Ugo, R., Ed.; Kluwer: Dordrecht, 1990; Chapter 1. (h) Bönnemann, H.; Braun, G.; Brijoux, W.; Brinkmann, R.; Tilling, A. S.; Seevogel, K.; Siepen, K. J. Organomet. Chem. 1996, 520, 143-162 and the collection of "key publications" cited as refs 2-61 therein. (i) Active Metals: Preparation, Characterization, Applications; Fürstner, A., Ed.; VCH: Weinheim, 1996. (j) Schmid, G. in Applied Homogeneous Catalysis with Organometallic Compounds; Cornils, B., Herrmann, W. A., Eds.; VCH: Weinheim, 1996; Vol. 2.
5. Reviews on nanoclusters: (a) Jena, P.; Rao B. K.; Khanna, S. N. Physics and Chemistry of Small Clusters; Plenum: New York, 1987. (b) Andres, R. P.; Averback, R. S.; Brown, W. L.; Brus, L. E.; Goddard, W. A.; Kaldor, A.; Louie S. G.; Moscovits, M.; Peercy, P. S.; Riley, S. J.; Siegel, R. W.; Spaepen, F.; Wang, Y. J. Mater. Res. 1989, 4, 704. This is a Panel Report from the United States Department of Energy, Council on Materials Science on "Research Opportunities on Clusters and Cluster-assembled Materials". (c) Thomas, J. M. Pure Appl. Chem. 1988, 60, 1517. (d) Henglein, A. Chem. Rev. 1989, 89, 1861. (e) A superb series of papers, complete with a record of the insightful comments by the experts attending the conference, is available in: Faraday Discuss. 1991, 92, 1-300. (f) Bradley, J. S. In Clusters and Colloids. From Theory to Applications; Schmid, G., Ed.; VCH: New York, 1994; pp 459-544. (g) Schmid, G. In Aspects of Homogeneous Catalysis; Ugo, R., Ed.; Kluwer: Dordrecht, 1990; Chapter 1. (h) Bönnemann, H.; Braun, G.; Brijoux, W.; Brinkmann, R.; Tilling, A. S.; Seevogel, K.; Siepen, K. J. Organomet. Chem. 1996, 520, 143-162 and the collection of "key publications" cited as refs 2-61 therein. (i) Active Metals: Preparation, Characterization, Applications; Fürstner, A., Ed.; VCH: Weinheim, 1996. (j) Schmid, G. in Applied Homogeneous Catalysis with Organometallic Compounds; Cornils, B., Herrmann, W. A., Eds.; VCH: Weinheim, 1996; Vol. 2.
6. Reviews on nanoclusters: (a) Jena, P.; Rao B. K.; Khanna, S. N. Physics and Chemistry of Small Clusters; Plenum: New York, 1987. (b) Andres, R. P.; Averback, R. S.; Brown, W. L.; Brus, L. E.; Goddard, W. A.; Kaldor, A.; Louie S. G.; Moscovits, M.; Peercy, P. S.; Riley, S. J.; Siegel, R. W.; Spaepen, F.; Wang, Y. J. Mater. Res. 1989, 4, 704. This is a Panel Report from the United States Department of Energy, Council on Materials Science on "Research Opportunities on Clusters and Cluster-assembled Materials". (c) Thomas, J. M. Pure Appl. Chem. 1988, 60, 1517. (d) Henglein, A. Chem. Rev. 1989, 89, 1861. (e) A superb series of papers, complete with a record of the insightful comments by the experts attending the conference, is available in: Faraday Discuss. 1991, 92, 1-300. (f) Bradley, J. S. In Clusters and Colloids. From Theory to Applications; Schmid, G., Ed.; VCH: New York, 1994; pp 459-544. (g) Schmid, G. In Aspects of Homogeneous Catalysis; Ugo, R., Ed.; Kluwer: Dordrecht, 1990; Chapter 1. (h) Bönnemann, H.; Braun, G.; Brijoux, W.; Brinkmann, R.; Tilling, A. S.; Seevogel, K.; Siepen, K. J. Organomet. Chem. 1996, 520, 143-162 and the collection of "key publications" cited as refs 2-61 therein. (i) Active Metals: Preparation, Characterization, Applications; Fürstner, A., Ed.; VCH: Weinheim, 1996. (j) Schmid, G. in Applied Homogeneous Catalysis with Organometallic Compounds; Cornils, B., Herrmann, W. A., Eds.; VCH: Weinheim, 1996; Vol. 2.
7. Reviews on nanoclusters: (a) Jena, P.; Rao B. K.; Khanna, S. N. Physics and Chemistry of Small Clusters; Plenum: New York, 1987. (b) Andres, R. P.; Averback, R. S.; Brown, W. L.; Brus, L. E.; Goddard, W. A.; Kaldor, A.; Louie S. G.; Moscovits, M.; Peercy, P. S.; Riley, S. J.; Siegel, R. W.; Spaepen, F.; Wang, Y. J. Mater. Res. 1989, 4, 704. This is a Panel Report from the United States Department of Energy, Council on Materials Science on "Research Opportunities on Clusters and Cluster-assembled Materials". (c) Thomas, J. M. Pure Appl. Chem. 1988, 60, 1517. (d) Henglein, A. Chem. Rev. 1989, 89, 1861. (e) A superb series of papers, complete with a record of the insightful comments by the experts attending the conference, is available in: Faraday Discuss. 1991, 92, 1-300. (f) Bradley, J. S. In Clusters and Colloids. From Theory to Applications; Schmid, G., Ed.; VCH: New York, 1994; pp 459-544. (g) Schmid, G. In Aspects of Homogeneous Catalysis; Ugo, R., Ed.; Kluwer: Dordrecht, 1990; Chapter 1. (h) Bönnemann, H.; Braun, G.; Brijoux, W.; Brinkmann, R.; Tilling, A. S.; Seevogel, K.; Siepen, K. J. Organomet. Chem. 1996, 520, 143-162 and the collection of "key publications" cited as refs 2-61 therein. (i) Active Metals: Preparation, Characterization, Applications; Fürstner, A., Ed.; VCH: Weinheim, 1996. (j) Schmid, G. in Applied Homogeneous Catalysis with Organometallic Compounds; Cornils, B., Herrmann, W. A., Eds.; VCH: Weinheim, 1996; Vol. 2.
8. Reviews on nanoclusters: (a) Jena, P.; Rao B. K.; Khanna, S. N. Physics and Chemistry of Small Clusters; Plenum: New York, 1987. (b) Andres, R. P.; Averback, R. S.; Brown, W. L.; Brus, L. E.; Goddard, W. A.; Kaldor, A.; Louie S. G.; Moscovits, M.; Peercy, P. S.; Riley, S. J.; Siegel, R. W.; Spaepen, F.; Wang, Y. J. Mater. Res. 1989, 4, 704. This is a Panel Report from the United States Department of Energy, Council on Materials Science on "Research Opportunities on Clusters and Cluster-assembled Materials". (c) Thomas, J. M. Pure Appl. Chem. 1988, 60, 1517. (d) Henglein, A. Chem. Rev. 1989, 89, 1861. (e) A superb series of papers, complete with a record of the insightful comments by the experts attending the conference, is available in: Faraday Discuss. 1991, 92, 1-300. (f) Bradley, J. S. In Clusters and Colloids. From Theory to Applications; Schmid, G., Ed.; VCH: New York, 1994; pp 459-544. (g) Schmid, G. In Aspects of Homogeneous Catalysis; Ugo, R., Ed.; Kluwer: Dordrecht, 1990; Chapter 1. (h) Bönnemann, H.; Braun, G.; Brijoux, W.; Brinkmann, R.; Tilling, A. S.; Seevogel, K.; Siepen, K. J. Organomet. Chem. 1996, 520, 143-162 and the collection of "key publications" cited as refs 2-61 therein. (i) Active Metals: Preparation, Characterization, Applications; Fürstner, A., Ed.; VCH: Weinheim, 1996. (j) Schmid, G. in Applied Homogeneous Catalysis with Organometallic Compounds; Cornils, B., Herrmann, W. A., Eds.; VCH: Weinheim, 1996; Vol. 2.
9. Reviews on nanoclusters: (a) Jena, P.; Rao B. K.; Khanna, S. N. Physics and Chemistry of Small Clusters; Plenum: New York, 1987. (b) Andres, R. P.; Averback, R. S.; Brown, W. L.; Brus, L. E.; Goddard, W. A.; Kaldor, A.; Louie S. G.; Moscovits, M.; Peercy, P. S.; Riley, S. J.; Siegel, R. W.; Spaepen, F.; Wang, Y. J. Mater. Res. 1989, 4, 704. This is a Panel Report from the United States Department of Energy, Council on Materials Science on "Research Opportunities on Clusters and Cluster-assembled Materials". (c) Thomas, J. M. Pure Appl. Chem. 1988, 60, 1517. (d) Henglein, A. Chem. Rev. 1989, 89, 1861. (e) A superb series of papers, complete with a record of the insightful comments by the experts attending the conference, is available in: Faraday Discuss. 1991, 92, 1-300. (f) Bradley, J. S. In Clusters and Colloids. From Theory to Applications; Schmid, G., Ed.; VCH: New York, 1994; pp 459-544. (g) Schmid, G. In Aspects of Homogeneous Catalysis; Ugo, R., Ed.; Kluwer: Dordrecht, 1990; Chapter 1. (h) Bönnemann, H.; Braun, G.; Brijoux, W.; Brinkmann, R.; Tilling, A. S.; Seevogel, K.; Siepen, K. J. Organomet. Chem. 1996, 520, 143-162 and the collection of "key publications" cited as refs 2-61 therein. (i) Active Metals: Preparation, Characterization, Applications; Fürstner, A., Ed.; VCH: Weinheim, 1996. (j) Schmid, G. in Applied Homogeneous Catalysis with Organometallic Compounds; Cornils, B., Herrmann, W. A., Eds.; VCH: Weinheim, 1996; Vol. 2.
10. Reviews on nanoclusters: (a) Jena, P.; Rao B. K.; Khanna, S. N. Physics and Chemistry of Small Clusters; Plenum: New York, 1987. (b) Andres, R. P.; Averback, R. S.; Brown, W. L.; Brus, L. E.; Goddard, W. A.; Kaldor, A.; Louie S. G.; Moscovits, M.; Peercy, P. S.; Riley, S. J.; Siegel, R. W.; Spaepen, F.; Wang, Y. J. Mater. Res. 1989, 4, 704. This is a Panel Report from the United States Department of Energy, Council on Materials Science on "Research Opportunities on Clusters and Cluster-assembled Materials". (c) Thomas, J. M. Pure Appl. Chem. 1988, 60, 1517. (d) Henglein, A. Chem. Rev. 1989, 89, 1861. (e) A superb series of papers, complete with a record of the insightful comments by the experts attending the conference, is available in: Faraday Discuss. 1991, 92, 1-300. (f) Bradley, J. S. In Clusters and Colloids. From Theory to Applications; Schmid, G., Ed.; VCH: New York, 1994; pp 459-544. (g) Schmid, G. In Aspects of Homogeneous Catalysis; Ugo, R., Ed.; Kluwer: Dordrecht, 1990; Chapter 1. (h) Bönnemann, H.; Braun, G.; Brijoux, W.; Brinkmann, R.; Tilling, A. S.; Seevogel, K.; Siepen, K. J. Organomet. Chem. 1996, 520, 143-162 and the collection of "key publications" cited as refs 2-61 therein. (i) Active Metals: Preparation, Characterization, Applications; Fürstner, A., Ed.; VCH: Weinheim, 1996. (j) Schmid, G. in Applied Homogeneous Catalysis with Organometallic Compounds; Cornils, B., Herrmann, W. A., Eds.; VCH: Weinheim, 1996; Vol. 2.
11. 2b
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