Novel preparation of palladium nanoclusters using metal nitrates and their catalysis for oxidative acetoxylation of toluene in the presence of molecular oxygen

Langmuir

Volumn 18, Issue 5, 2002, Pages 1849-1855

  Ebitani, Kohki ^a   Choi, Kwang Min ^a   Mizugaki, Tomoo ^a   Kaneda, Kiyotomi ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ION-CHROMATOGRAPHY;

ADSORPTION; CATALYSIS; CHROMATOGRAPHIC ANALYSIS; NEGATIVE IONS; NITRATES; OXIDATION; PALLADIUM COMPOUNDS; POSITIVE IONS; SCANNING ELECTRON MICROSCOPY; SURFACE CHEMISTRY; X RAY PHOTOELECTRON SPECTROSCOPY;

NANOSTRUCTURED MATERIALS;

EID: 0037023077     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la011359j     Document Type: Article

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88. 2.
89. 3 did not afford the Pd cluster.
90. + ions and for the oxidation of the surface Pd° species.
91. 2 under Ar instead of oxygen atmosphere.
92. The acetoxylation did not proceed when the reaction using the Pd cluster was carried out under Ar atmosphere instead of oxygen. This Pd cluster was also effective for the acetoxylation of p-methoxytoluene; p-methoxybenzyl acetate was formed with 85% yield at 90 °C for 24 h.
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