Nanoparticles: Scaffolds and building blocks

Accounts of Chemical Research

Volumn 36, Issue 7, 2003, Pages 549-561

  Shenhar, Roy ^a   Rotello, Vincent M ^a  

^a UNIVERSITY OF MASSACHUSETTS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANALYTIC METHOD; ARTICLE; CHEMICAL STRUCTURE; COMPOSITE MATERIAL; DEVICE; FABRICATION; MOLECULAR MODEL; NANOPARTICLE; NANOTECHNOLOGY; PARTICLE SIZE; STRUCTURE ANALYSIS; SYNTHESIS; TOP DOWN FABRICATION;

BIOCOMPATIBLE MATERIALS; CATALYSIS; EQUIPMENT AND SUPPLIES; METALS; MICELLES; NANOTECHNOLOGY; POLYMERS;

EID: 0038168314     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar020083j     Document Type: Article

References (45)

1. Jager, E. W. H.; Smela, E.; Inganas, O. Microfabricating Conjugated Polymer Actuators. Science 2000, 290, 1540-1545. Craighead, H. G. Nanoelectromechanical Systems. Science 2000, 290, 1532-1535. Wallraff, G. M.; Hinsberg, W. D. Lithographic Imaging Techniques for the Formation of Nanoscopic Features. Chem. Rev. 1999, 99, 1801-1821.
2. Jager, E. W. H.; Smela, E.; Inganas, O. Microfabricating Conjugated Polymer Actuators. Science 2000, 290, 1540-1545. Craighead, H. G. Nanoelectromechanical Systems. Science 2000, 290, 1532-1535. Wallraff, G. M.; Hinsberg, W. D. Lithographic Imaging Techniques for the Formation of Nanoscopic Features. Chem. Rev. 1999, 99, 1801-1821.
3. Jager, E. W. H.; Smela, E.; Inganas, O. Microfabricating Conjugated Polymer Actuators. Science 2000, 290, 1540-1545. Craighead, H. G. Nanoelectromechanical Systems. Science 2000, 290, 1532-1535. Wallraff, G. M.; Hinsberg, W. D. Lithographic Imaging Techniques for the Formation of Nanoscopic Features. Chem. Rev. 1999, 99, 1801-1821.
4. Feldheim, D.; Grabar, K. C.; Natan, M. J.; Mallouk, T. E. Electron Transfer in Self-Assembled Inorganic Polyelectrolyte/Metal Nanoparticle Heterostructure. J. Am. Chem. Soc. 1996, 118, 7640-7641, and references therein.
5. Templeton, A. C.; Wuelfing, M. P.; Murray, R. W. Monolayer Protected Cluster Molecules. Acc. Chem. Res. 2000, 33, 27-36.
6. Brust, M.; Walker, M.; Bethell, D.; Schiffrin, D. J.; Whyman, R. Synthesis of Thiol-Derivatized Gold Nanoparticles in a 2-Phase Liquid-Liquid System. J. Chem. Soc., Chem. Commun. 1994, 801-802.
7. Hostetler, M. J.; Wingate, J. E.; Zhong, C.-J.; Harris, J. E.; Vachet, R. W.; Clark, M. R.; Londono, J. D.; Green, S. J.; Stokes, J. J.; Wignall, G. D.; Glish, G. L.; Porter, M. D.; Evans, N. D.; Murray, R. W. Alkanethiolate Gold Cluster Molecules with Core Diameters from 1.5 to 5.2 nm: Core and Monolayer Properties as a Function of Core Size. Langmuir 1998, 14, 17-30.
8. Templeton, A. C.; Hostetler, M. J.; Warmoth, E. K.; Chen, S. W.; Hartshorn, C. M.; Krishnamurthy, V. M.; Forbes, M. D. E.; Murray, R. W. Gateway Reactions to Diverse, Polyfunctional Monolayer-Protected Gold Clusters. J. Am. Chem. Soc. 1998, 120, 4845-4849.
9. Boal, A.; Rotello, V. Intra- and Inter-Monolayer Hydrogen bonding in Amide Functionalized Alkanethiol SAMs on Gold Nanoparticles. Langmuir 2000, 16, 9527-9532.
10. Paulini, R.; Frankamp, B. L.; Rotello, V. M. Effects of Branched Ligands on the Structure and Stability of Monolayers on Gold Nanoparticles. Langmuir 2002, 18, 2368-2373.
11. Templeton, A. C.; Hostetler, M. J.; Kraft, C. T.; Murray, R. W. Reactivity of Monolayer-Protected Gold Cluster Molecules: Steric Effects. J. Am. Chem. Soc. 1998, 120, 1906-1911. Weisbecker, C. S.; Merritt, M. V.; Whitesides, G. M. Molecular Self-Assembly of Aliphatic Thiols on Gold Colloids. Langmuir 1996, 12, 3763-3772.
12. Templeton, A. C.; Hostetler, M. J.; Kraft, C. T.; Murray, R. W. Reactivity of Monolayer-Protected Gold Cluster Molecules: Steric Effects. J. Am. Chem. Soc. 1998, 120, 1906-1911. Weisbecker, C. S.; Merritt, M. V.; Whitesides, G. M. Molecular Self-Assembly of Aliphatic Thiols on Gold Colloids. Langmuir 1996, 12, 3763-3772.
13. 2SH. Langmuir 1995, 11, 4371-4382. Clegg, R. S.; Hutchison, J. E. Control of Monolayer Assembly Structure by Hydrogen Bonding Rather Than by Adsorbate-Substrate Templating. J. Am. Chem. Soc. 1999, 121, 5319-5327.
14. 2SH. Langmuir 1995, 11, 4371-4382. Clegg, R. S.; Hutchison, J. E. Control of Monolayer Assembly Structure by Hydrogen Bonding Rather Than by Adsorbate-Substrate Templating. J. Am. Chem. Soc. 1999, 121, 5319-5327.
15. Hostetler, M. J.; Templeton, A. C.; Murray, R. W. Dynamics of Place-Exchange Reactions on Monolayer-Protected Gold Cluster Molecules. Langmuir 1999, 15, 3782-3789.
16. Briggs, C.; Norsten, T. B.; Rotello, V. M. Inhibition and Acceleration of Deuterium Exchange in Amide-Functionalized Monolayer-Protected Gold Clusters. Chem. Commun. 2002, 1890-1891.
17. Kirby, A. J.; Percy, J. M. The Hydrogen-Bond as a Key Factor in Efficient Intramolecular Proton-Transfer Catalysis. J. Chem. Soc., Chem. Commun. 1987, 1774-1775.
18. Boal, A. K.; Rotello, V. M. Redox-Modulated Recognition of Flavin by Functionalized Gold Nanoparticles. J. Am. Chem. Soc. 1999, 121, 4914-4915. For a previous example of recognition at a gold nanoparticle surface using a diaminopyridine-imide dyad, see: Aherne D.; Rao S. N.; Fitzmaurice D. Programming a gold nanocrystal to recognize and selectively bind a molecular substrate in solution J. Phys. Chem. B 1999, 103, 1821-1825.
19. Boal, A. K.; Rotello, V. M. Redox-Modulated Recognition of Flavin by Functionalized Gold Nanoparticles. J. Am. Chem. Soc. 1999, 121, 4914-4915. For a previous example of recognition at a gold nanoparticle surface using a diaminopyridine-imide dyad, see: Aherne D.; Rao S. N.; Fitzmaurice D. Programming a gold nanocrystal to recognize and selectively bind a molecular substrate in solution J. Phys. Chem. B 1999, 103, 1821-1825.
20. Niemz, A.; Rotello, V. M. From Enzyme to Molecular Device. Exploring the Interdependence of Redox and Molecular Recognition. Acc. Chem. Res. 1999, 32, 44-52.
21. 1/2 (unbound)].
22. Boal, A. K.; Rotello, V. M. Fabrication and Self-Optimization of Multivalent Receptors on Nanoparticle Scaffolds. J. Am. Chem. Soc. 2000, 122, 734-735.
23. Boal, A. K.; Rotello, V. M. Radial Control of Recognition and Redox Processes with Multivalent Nanoparticle Hosts. J. Am. Chem. Soc. 2002, 124, 5019-5024.
24. Badia, A.; Cuccia, L.; Demers, L.; Morin, F.; Lennox, R. B. Structure and Dynamics in Alkanethiolate Monolayers Self-Assembled on Gold Nanoparticles: A DSC, FT-IR and 2H-NMR Study. J. Am. Chem. Soc. 1997, 119, 2682-2692.
25. McIntosh, C. M.; Esposito, E. A.; Boal, A. K.; Simard, J. M.; Martin, C. T.; Rotello, V. M. Inhibition of DNA Transcription Using Cationic Mixed Monolayer Protected Gold Clusters. J. Am. Chem. Soc. 2001, 123, 7626-7629.
26. Fischer N. O., McIntosh C. M., Simard J. M., Rotello V. M. Inhibition of Chymotrypsin Through Surface Binding Using Nanoparticle-Based Receptors. P. Natl. Acad. Sci. U.S.A. 2002, 99, 5018-5023.
27. Loweth, C. J.; Caldwell, W. B.; Peng, X. G.; Alivisatos, A. P.; Schultz, P. G. DNA-Based Assembly of Gold Nanocrystals. Angew. Chem., Int. Ed. Engl. 1999, 38, 1808-1812. Mirkin, C. A.; Letsinger, R. L.; Mucic, R. C.; Storhoff, J. J. A DNA-Based Method for Rationally Assembling Nanoparticles into Macroscopic Materials. Nature 1996, 382, 607-609. Shenton, W.; Davis, S. A.; Mann, S. Directed Self-Assembly of Nanoparticles into Macroscopic Materials using Antibody-Antigen Recognition. Adv. Mater. 1999, 11, 449-453.
28. Loweth, C. J.; Caldwell, W. B.; Peng, X. G.; Alivisatos, A. P.; Schultz, P. G. DNA-Based Assembly of Gold Nanocrystals. Angew. Chem., Int. Ed. Engl. 1999, 38, 1808-1812. Mirkin, C. A.; Letsinger, R. L.; Mucic, R. C.; Storhoff, J. J. A DNA-Based Method for Rationally Assembling Nanoparticles into Macroscopic Materials. Nature 1996, 382, 607-609. Shenton, W.; Davis, S. A.; Mann, S. Directed Self-Assembly of Nanoparticles into Macroscopic Materials using Antibody-Antigen Recognition. Adv. Mater. 1999, 11, 449-453.
29. Loweth, C. J.; Caldwell, W. B.; Peng, X. G.; Alivisatos, A. P.; Schultz, P. G. DNA-Based Assembly of Gold Nanocrystals. Angew. Chem., Int. Ed. Engl. 1999, 38, 1808-1812. Mirkin, C. A.; Letsinger, R. L.; Mucic, R. C.; Storhoff, J. J. A DNA-Based Method for Rationally Assembling Nanoparticles into Macroscopic Materials. Nature 1996, 382, 607-609. Shenton, W.; Davis, S. A.; Mann, S. Directed Self-Assembly of Nanoparticles into Macroscopic Materials using Antibody-Antigen Recognition. Adv. Mater. 1999, 11, 449-453.
30. (a) Thomas, J. M.; Johnson, B. F. G.; Raja, R.; Sankar, G.; Midgley, P. A. High-Performance Nanocatalysts for Single-Step Hydrogenations Acc. Chem. Res. 2003, 36, 20-30.
31. (b) Aiken, J. D.; Finke, R. G. A Review of Modern Transition-Metal Nanoclusters: Their Synthesis, Characterization, and Applications in Catalysis. J. Mol. Catal. A: Chem. 1999, 145, 1-44.
32. Galow, T. H.; Boal, A. K.; Rotello, V. M. A 'Building Block' Approach to Mixed-Colloid Systems through Electrostatic Self-Organization. Adv. Mater. 2000, 12, 576-579.
33. Boal, A. K.; Galow, T. H.; Ilhan, F.; Rotello, V. M. Binary and Ternary Polymer-Mediated 'Bricks and Mortar' Self-Assembly of Gold and Silica Nanoparticles. Adv. Funct. Mater. 2001, 11, 461-465.
34. Galow, T. H.; Drechsler, U.; Hanson, J. A.; Rotello, V. M. Highly Reactive Heterogeneous Heck and Hydrogenation Catalysts Constructed through 'Bottom-Up' Nanoparticle Self-Assembly. Chem. Commun. 2002, 1076-1077.
35. Increasing polymer fraction in the process of making the catalysts was found to lower the TOF (7600 h-1 for the 1:1:5 system), consistent with a denser structures observed with such systems.
36. Shipway, A. N.; Katz, E.; Willner, I. Nanoparticle Arrays on Surfaces for Electronic, Optical and Sensor Applications. Chem-PhysChem 2000, 1, 18-52. Murray, C. B.; Kagan, C. R.; Bawendi, M. G. Synthesis and Characterization of Monodisperse Nanocrystals and Close-Packed Nanocrystal Assemblies. Annu. Rev. Mater. Sci. 2000, 30, 545-610.
37. Shipway, A. N.; Katz, E.; Willner, I. Nanoparticle Arrays on Surfaces for Electronic, Optical and Sensor Applications. Chem-PhysChem 2000, 1, 18-52. Murray, C. B.; Kagan, C. R.; Bawendi, M. G. Synthesis and Characterization of Monodisperse Nanocrystals and Close-Packed Nanocrystal Assemblies. Annu. Rev. Mater. Sci. 2000, 30, 545-610.
38. Boal, A. K.; Ilhan, F.; DeRouchey, J. E.; Thurn-Albrecht, T.; Russell, T. P.; Rotello, V. M. Self-Assembly of Nanoparticles into Structured Spherical and Network Aggregates. Nature 2000, 404, 746-748.
39. Deans, R.; Ilhan, F.; Rotello, V. M. Recognition-Mediated Unfolding of a Self-Assembled Polymeric Globule. Macromolecules 1999, 32, 4956-4960.
40. Frankamp, B. L.; Uzun, O.; Ilhan, F.; Boal, A. K.; Rotello, V. M. Recognition-Mediated Assembly of Nanoparticles into Micellar Structures with Diblock Copolymers. J. Am. Chem. Soc. 2002, 124, 892-893.
41. Frankamp, B. L.; Boal, A. K.; Rotello, V. M. Controlled Interparticle Spacing through Self-Assembly of Au Nanoparticles and Poly-(amidoamine) Dendrimers. J. Am. Chem. Soc. 2002, 124, 15146-15147.
42. Zheng, L.; Waddon, A. J.; Farris, R. J.; Coughlin, E. B. X-ray Characterizations of Polyethylene Polyhedral Oligomeric Silsesquioxane Copolymers. Macromolecules 2002, 35, 2375-2379.
43. Carroll, J. B.; Frankamp, B. L.; Rotello, V. M. Self-Assembly of Gold Nanoparticles through Tandem Hydrogen bonding and POSS-POSS Recognition Processes. Chem. Commun. 2002, 1892-1893.
44. Boal, A. K.; Gray, M.; Ilhan, F.; Clavier, G. M.; Kapitzky, L.; Rotello, V. M. Bricks and Mortar Self-Assembly of Nanoparticles. Tetrahedron 2002, 58, 765-770.
45. 3 Nanoparticles. Chem. Mater. 2002, 14, 2628-2636.