Structure, redox, pKa, spin. A golden tetrad for understanding metalloenzyme energetics and reaction pathways

Journal of Biological Inorganic Chemistry

Volumn 11, Issue 6, 2006, Pages 674-694

  Noodleman, Louis ^a   Han, Wen Ge ^a  

^a SCRIPPS RESEARCH INSTITUTE   (United States)

Author keywords

Broken symmetry; Density functional theory; Electron transfer; pKa; Proton transfer

Indexed keywords

IRON DERIVATIVE; IRON SULFUR PROTEIN; MANGANESE SUPEROXIDE DISMUTASE; METAL COMPLEX; METHANE MONOOXYGENASE; MOLYBDENUM IRON PROTEIN; NITROGENASE; RIBONUCLEOTIDE REDUCTASE; TRANSITION ELEMENT; ORGANOMETALLIC COMPOUND; OXYGENASE;

CHEMICAL PARAMETERS; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; CORRELATION ANALYSIS; DENSITY FUNCTIONAL THEORY; ELECTRON SPIN RESONANCE; ELECTRON TRANSPORT; ENERGY TRANSFER; ENZYME ACTIVE SITE; GEOMETRY; MATHEMATICAL ANALYSIS; MATHEMATICAL COMPUTING; OXIDATION REDUCTION POTENTIAL; OXIDATION REDUCTION REACTION; PKA; PRIORITY JOURNAL; PROTON TRANSPORT; REVIEW; SPECTROSCOPY; ARTICLE; BINDING SITE; CHEMISTRY; METABOLISM; PROTEIN CONFORMATION;

BINDING SITES; IRON-SULFUR PROTEINS; MODELS, MOLECULAR; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; OXYGENASES; PROTEIN CONFORMATION;

EID: 33746266964     PISSN: 09498257     EISSN: None     Source Type: Journal    
DOI: 10.1007/s00775-006-0136-3     Document Type: Review

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