Electroreduction of a series of alkylcobalamins: Mechanism of stepwise reductive cleavage of the Co-C bond

Journal of the American Chemical Society

Volumn 128, Issue 6, 2006, Pages 1922-1936

  Birke, Ronald L ^a   Huang, Qingdong ^a   Spataru, Tudor ^a   Gosser Jr , David K ^a  

^a CITY COLLEGE OF NEW YORK   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; CHEMICAL BONDS; COBALT; COMPUTER SIMULATION; DISSOCIATION; ELECTROCHEMISTRY; ELECTRODES; ELECTROLYTIC REDUCTION; ENTHALPY; FREE RADICALS; NEGATIVE IONS; ORGANIC SOLVENTS; SODIUM COMPOUNDS;

ALKYLCOBALAMINS; DIGITAL SIMULATION; ELECTROREDUCTION;

ORGANIC COMPOUNDS;

BORIC ACID; CARBON; COBALAMIN DERIVATIVE; COBAMAMIDE; ETHYLCOBALAMIN; ISOBUTYLCOBALAMIN; MECOBALAMIN; METHANOL; N BUTYLCOBALAMIN; N PROPYLCOBALAMIN; N,N DIMETHYLFORMAMIDE; SILVER; SILVER CHLORIDE; SOLVENT; TETRABUTYLAMMONIUM; TETRABUTYLAMMONIUM FLUOROBORATE; UNCLASSIFIED DRUG;

AMPEROMETRY; ARTICLE; CHEMICAL BOND; DENSITY FUNCTIONAL THEORY; DISSOCIATION; ELECTROCHEMISTRY; ELECTRON TRANSPORT; ENTHALPY; OXIDATION REDUCTION POTENTIAL; POTENTIOMETRY; REACTION ANALYSIS; REDUCTION; TEMPERATURE;

COBALT; COMPUTER SIMULATION; ELECTROCHEMISTRY; OXIDATION-REDUCTION; THERMODYNAMICS; VITAMIN B 12;

EID: 33244469516     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja054479c     Document Type: Article

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