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Volumn 101, Issue 51, 1997, Pages 11152-11159

Fermi golden rule approach to evaluating outer-sphere electron-transfer rate constants at semiconductor/liquid interfaces

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE CARRIERS; ELECTROCHEMICAL ELECTRODES; ELECTROLYTES; FERMI LEVEL; GOLD; INTERFACES (MATERIALS); PHASE INTERFACES; REACTION KINETICS; REDOX REACTIONS; SEMICONDUCTOR DOPING;

EID: 0031378541     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp972222y     Document Type: Article
Times cited : (114)

References (49)
  • 22
    • 5844336239 scopus 로고    scopus 로고
    • note
    • 0′ is negative for a thermodynamically favorable reduction of the acceptor A by an electron in the conduction band of the semiconductor.
  • 23
    • 5844304313 scopus 로고    scopus 로고
    • note
    • -). This treatment allows recovery of the conventional Marcus-type or Butler-Volmer type current-potential relationships at a metal electrode and recovery of the standard exponential diode-like behavior of a semiconductor at various applied potentials from the equations presented herein; systems for which this Fermi level occupancy treatment do not apply are beyond the scope of this work and must be treated by a more sophisticated analysis than is available, to our knowledge, for any electrochemical system to date.
  • 31
    • 85087249796 scopus 로고    scopus 로고
    • note
    • sc in onter to obtain eq 23 and the relationships derived therefrom.
  • 32
    • 85087251024 scopus 로고    scopus 로고
    • note
    • 19
  • 40
    • 0001638713 scopus 로고    scopus 로고
    • 5 Also see: Bansal, A.; Tan, M. X.; Tufts, B. J.; Lewis, N. S. J. Phys. Chem. 1993, 97, 7309 and Nozik, A. J. Presented at the 211th National Meeting of the American Chemical Society; New Orleans, LA, March 1996, paper PHYS 11.
    • (1993) J. Phys. Chem. , vol.97 , pp. 7309
    • Bansal, A.1    Tan, M.X.2    Tufts, B.J.3    Lewis, N.S.4
  • 41
    • 0001638713 scopus 로고    scopus 로고
    • New Orleans, LA, March paper PHYS 11
    • 5 Also see: Bansal, A.; Tan, M. X.; Tufts, B. J.; Lewis, N. S. J. Phys. Chem. 1993, 97, 7309 and Nozik, A. J. Presented at the 211th National Meeting of the American Chemical Society; New Orleans, LA, March 1996, paper PHYS 11.
    • (1996) 211th National Meeting of the American Chemical Society
    • Nozik, A.J.1
  • 45
    • 5844230221 scopus 로고    scopus 로고
    • note
    • sc,max relative to those provided by these procedures and also to treat the transition region between the adiabatic and nonadiabatic situations in depth.
  • 49
    • 85087250042 scopus 로고    scopus 로고
    • note
    • 2/state, which is clearly nonphysical.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.