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Volumn 122, Issue 40, 2000, Pages 9829-9835

Reductive cleavage of carbon tetrachloride in a polar solvent. An example of a dissociative electron transfer with significant attractive interaction between the caged product fragments

Author keywords

[No Author keywords available]

Indexed keywords

CARBON TETRACHLORIDE; CHLORIDE ION; N,N DIMETHYLFORMAMIDE; RADICAL; SOLVENT;

EID: 0034638393     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja001258s     Document Type: Article
Times cited : (125)

References (63)
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    • In agreement with a previously reported low-scan-rate voltammogram in the same medium at the same electrode.(12b)
  • 42
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    • Two other, more negative waves can be seen on the low-scan-rate voltammogram, corresponding to further reduction of chloroform in line with earlier polarographic and preparative-scale results.(12b)
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    • - competes with its protonation.(12e,f)
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    • note
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    • Ab initio quantum chemical calculation of D(R) (UHF-MP2, see the Methodology section) gave a value of 2.84 eV, in fair agreement with the experimental values of 2.86,(15b) 2.99,(15c) and 3.08.(15d)
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    • 4) = 0.381 eV at the temperature of the experiments, 21 °C, taking into account that the standard states refer to 1 mol/L
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    • note
  • 57
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    • This is obviously not the case with empirical methods such as PM3,(17b) thus showing the weakness of these methods in the study of dissociative electron-transfer dynamics


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.