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Volumn 111, Issue 24, 1999, Pages 11117-11137

Theory of nonadiabatic electron transfer at electrode/liquid interfaces: Role of quantum effects

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0011162381     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.480471     Document Type: Article
Times cited : (21)

References (78)
  • 33
    • 85034136793 scopus 로고    scopus 로고
    • note
    • In the literature (Refs. 11 and 12) a quantum theory was formulated for the electron transfer reactions at electrode/liquid interfaces in a formal way, whereas any accurate quantum-mechanical expression for the rate constant such as given in the present paper was not derived explicitly.
  • 38
    • 85034122754 scopus 로고    scopus 로고
    • note
    • 2/s is the diffusion coefficient of water. However, such a diffusive mode of solvent molecules can be recovered in the theory through the correspondence between the spectral density and the dielectric functions of solvent and electrode formulated later in Sec. II D.
  • 48
    • 85034154607 scopus 로고    scopus 로고
    • note
    • The contribution of (small) work terms (Refs. 8,9,12,37,49) is ignored in the present model.
  • 61
    • 85034128246 scopus 로고    scopus 로고
    • note
    • 1(ω)}, in Eq. (2.92) is a response function, that is, it is analytic in the upper half of the complex ω plane (Ref. 60).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.