Light-driven machine prototypes based on dissociative excited states: Photoinduced decoordination and thermal recoordination of a ring in a ruthenium(II)-containing [2]catenane

Angewandte Chemie - International Edition

Volumn 43, Issue 18, 2004, Pages 2392-2395

  Mobian, Pierre ^a   Kern, Jean Marc ^a   Sauvage, Jean Pierre ^a  

^a UNIVERSITÉ DE STRASBOURG   (France)

Author keywords

Catenanes; Molecular devices; N ligands; Photochemistry; Ruthenium

Indexed keywords

PHOTOCHEMICAL REACTIONS; THERMOANALYSIS;

AMPLITUDE MOTIONS; DECOORDINATION PROCESSES;

RUTHENIUM COMPOUNDS;

CATENANE; RUTHENIUM COMPLEX;

ARTICLE; CHEMICAL REACTION; DISSOCIATION; PHOTOCHEMISTRY; THERMAL ANALYSIS;

EID: 4544259048     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200352522     Document Type: Article

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51. 2 was prepared by using the same strategy as the synthesis of 1.[10] Instead of using a 50-membered ring, a new 63-membered-ring macrocycle was prepared. The 63-membered ring was synthesized by treating a bisphenanthroline ligand[10] bearing two phenol-terminated functionalities with a long dibromide fragment under high dilution conditions. Its synthesis will be reported elsewhere: P. Mobian, J.-M. Kern, J.-P. Sauvage, Helv. Chim. Acta, 2003, 86, 4195-4213.
52. +] (calcd: 636).
53. 3CN molecules (P. Mobian, J.-M. Kern, J.-P. Sauvage, Helv. Chim. Acata, 2003, 86, 4195-4213).