Synthesis of novel interlocked systems utilizing a palladium complex with 2,6-pyridinedicarboxamide-based tridentate macrocyclic ligand

Tetrahedron Letters

Volumn 45, Issue 52, 2004, Pages 9593-9597

  Furusho, Yoshio ^c   Matsuyama, Takanori ^a   Takata, Toshikazu ^a   Moriuchi, Toshiyuki ^b   Hirao, Toshikazu ^b  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^b OSAKA UNIVERSITY   (Japan)

^c JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

Author keywords

2,6 Pyridinedicarboxamide; 2 Rotaxane; End capping; Macrocycle; Palladium

Indexed keywords

CARBON MONOXIDE; HYDROXYL GROUP; ISOCYANATE; LIGAND; MACROCYCLIC COMPOUND; PALLADIUM COMPLEX; PYRIDINE DERIVATIVE; ROTAXANE;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; INFRARED SPECTROMETRY; MASS SPECTROMETRY; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 9744235833     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2004.10.152     Document Type: Article

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30. int = 0.034], R = 0.0540, wR = 0.0740 for 10,995 observed data [I > 3σ(I)], GOF = 1.237
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34. 1H NMR spectrum was observed for all the signals down to -50°C. This indicates that the macrocyclic component moves along the dumbbell component with a high degree of freedom