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Volumn 24, Issue 13, 2005, Pages 3207-3218

Chiral rhodium(I) and iridium(I) amino-olefin complexes: pKa, N-H bond dissociation energy, and catalytic transfer hydrogenation

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; AMINES; CATALYSIS; COMPLEXATION; DISSOCIATION; HYDROGEN BONDS; HYDROGENATION; IRIDIUM COMPOUNDS; ISOMERS; KETONES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OLEFINS; OXIDATION;

EID: 23144439606     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0500927     Document Type: Article
Times cited : (65)

References (98)
  • 7
    • 4744337518 scopus 로고    scopus 로고
    • and literature cited therein
    • There are too many references to cite here. For a recent paper discussing the displacement of an amine by an imine in an iridium cod complex as a key step in the catalytic cycle for imine hydrogenations see: (a) Dorta, R.; Broggini, D.; Kissner, R. Togni, A. Chem. Eur. J. 2004, 10, 4546 and literature cited therein. For early investigations relevant to our work see:
    • (2004) Chem. Eur. J. , vol.10 , pp. 4546
    • Dorta, R.1    Broggini, D.2    Kissner, R.3    Togni, A.4
  • 20
    • 0346148353 scopus 로고    scopus 로고
    • and literature cited therein
    • 2(tacn)(coe)]Cl (tacn = triazacyclononane): Iimura, M.; Evans, D. R.; Flood, T. C. Organometallics 2003, 22, 5370 and literature cited therein.
    • (2003) Organometallics , vol.22 , pp. 5370
    • Iimura, M.1    Evans, D.R.2    Flood, T.C.3
  • 28
    • 0001687271 scopus 로고
    • (c) For examples of bridging amides in binuclear rhodium complexes relevant to imine hydrogenation see: Fryzuk, M. D.; Piers, W. E. Organometallics 1990, 9, 986.
    • (1990) Organometallics , vol.9 , pp. 986
    • Fryzuk, M.D.1    Piers, W.E.2
  • 29
    • 4444223466 scopus 로고    scopus 로고
    • and literature cited therein
    • 3)]: Rais, D.; Bergman, G. R. Chem. Eur. J. 2004, 10, 3970 and literature cited therein.
    • (2004) Chem. Eur. J. , vol.10 , pp. 3970
    • Rais, D.1    Bergman, G.R.2
  • 44
    • 0001038733 scopus 로고    scopus 로고
    • Recent original papers
    • (d) Buchwald, S. L. Acc. Chem. Res. 1998, 31, 805. Recent original papers:
    • (1998) Acc. Chem. Res. , vol.31 , pp. 805
    • Buchwald, S.L.1
  • 64
  • 71
    • 23144441670 scopus 로고    scopus 로고
    • Grützmacher, H.; Deblon, S.; Maire, P.; Schönberg, H. Ger, Offen. DE 101 59 015.6, 2002
    • (a) Grützmacher, H.; Deblon, S.; Maire, P.; Schönberg, H. Ger, Offen. DE 101 59 015.6, 2002.
  • 83
    • 0002221472 scopus 로고
    • Synthesis and racemate separation of 1,2-diphenyl-1,2-ethyl-enediamine: Pikul, S.; Corey, E. J. Org. Synth. 1993, 71, 22.
    • (1993) Org. Synth. , vol.71 , pp. 22
    • Pikul, S.1    Corey, E.J.2
  • 89
    • 23144454572 scopus 로고    scopus 로고
    • Frison, G.; Grützmacher, H.; Frenking, G. Unpublished results
    • (b) Frison, G.; Grützmacher, H.; Frenking, G. Unpublished results.
  • 95
    • 23144468149 scopus 로고    scopus 로고
    • note
    • + are especially stabilized with respect to the reduced neutral complexes and with respect to the redox couples involving rhodium trop-phosphanes. However, because phosphanes certainly act as stronger binding ligands and stabilize a tetracoordinated rhodium(I) complex better than an amine, we consider this situation as less likely.
  • 97


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.