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For recent work using chiral Rh(I) diamine complexes in asymmetric hydrogenations, see: (a) Jones, M. D.; Raja, R.; Thomas, J. M.; Johnson, B. F. G.; Lewis, D. W.; Rouzaud, J.; Harris, K. D. M. Angew. Chem., Int. Ed. 2003, 42, 4326, and literature cited therein.
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In contrast, amine rhodium complexes can be used in oxygenation chemistry; for recent examples see: (a) de Bruin, B.; Kicken, R. J. N. A. M.; Suos, N. F. A.; Donners, M. P. J.; den Reijer, C. J.; Sandee, A. J.; de Gelder, R. Smits, J. M. M.; Gal, A. W.; Spek, A. L. Eur. J. Inorg. Chem. 1999, 1581 and literature cited therein.
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(b) de Bruin, B.; Brands, J. A.; Suos, N. F. A.; Donners, J. J. J. M.; Donners, M. P. J.; de Gelder, R.; Smits, J. M. M.; Gal, A. W.; Spek, A. L. Chem. Eur. J. 1999, 5, 2921 and literature cited therein.
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There are too many references to cite here. For a recent paper discussing the displacement of an amine by an imine in an iridium cod complex as a key step in the catalytic cycle for imine hydrogenations see: (a) Dorta, R.; Broggini, D.; Kissner, R. Togni, A. Chem. Eur. J. 2004, 10, 4546 and literature cited therein. For early investigations relevant to our work see:
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+ are especially stabilized with respect to the reduced neutral complexes and with respect to the redox couples involving rhodium trop-phosphanes. However, because phosphanes certainly act as stronger binding ligands and stabilize a tetracoordinated rhodium(I) complex better than an amine, we consider this situation as less likely.
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