Iridium-imine and -amine complexes relevant to the (S)-metolachlor process: Structures, exchange kinetics, and C-H activation by IrI causing racemization

Chemistry - A European Journal

Volumn 10, Issue 18, 2004, Pages 4546-4555

  Dorta, Romano ^a   Broggini, Diego ^b   Kissner, Reinhard ^c   Togni, Antonio ^c  

^a UNIVERSIDAD SIMÓN BOLÍVAR   (Venezuela)

^b UNIVERSITY OF CALIFORNIA   (United States)

^c ETH ZURICH   (Switzerland)

Author keywords

C H activation; Exchange kinetics; Iridium; Metolachlor; N ligands

Indexed keywords

AMINES; DYNAMIC MECHANICAL ANALYSIS; HIGH TEMPERATURE EFFECTS; HYDROGENATION; HYDROLYSIS; SINGLE CRYSTALS; SUBSTRATES; X RAY ANALYSIS;

CATALYTIC CYCLES; CHIRAL AMINE COMPLEXES; IRIDIUM COMPLEXES;

IRIDIUM COMPOUNDS;

1,5 CYCLOOCTADIENE DERIVATIVE; 2,6 DIMETHYLANILINE DERIVATIVE; 2,6 DIMETHYLPHENYL 1' METHYL 2' METHOXYETHYLAMINE; 2,6 DIMETHYLPHENYL 1' METHYL 2' METHOXYETHYLIMINE; AMINE; ANILINE DERIVATIVE; CARBON; CYCLOOCTANE DERIVATIVE; HYDROGEN; IMINE; IRIDIUM COMPLEX; METOLACHLOR; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL ANALYSIS; CHEMICAL INTERACTION; CHEMICAL MODEL; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; CHIRALITY; COMPLEX FORMATION; DISSOLUTION; ENERGY; HYDROGENATION; HYDROLYSIS; OPTICAL ROTATION; RACEMIZATION; REACTION ANALYSIS; ROOM TEMPERATURE; STRUCTURE ANALYSIS; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

ACETAMIDES; AMINES; CRYSTALLOGRAPHY, X-RAY; IMINES; IRIDIUM; KINETICS; MODELS, MOLECULAR; MOLECULAR CONFORMATION; ORGANOMETALLIC COMPOUNDS; STEREOISOMERISM;

EID: 4744337518     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200306008     Document Type: Article

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