A monometric d9-rhodium(0) complex

Angewandte Chemie - International Edition

Volumn 37, Issue 10, 1998, Pages 1423-1426

  Schönberg, Hartmut ^a   Boulmaâz, Souad ^a   Wörle, Michael ^a   Liesum, Lorenz ^a   Schweiger, Arthur ^a   Grützmacher, Hansjörg ^a  

^a ETH ZURICH   (Switzerland)

Author keywords

Electrochemistry; ENDOR spectroscopy; EPR spectroscopy; P ligands; Rhodium

Indexed keywords

EID: 0343869597     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980605)37:10<1423::AID-ANIE1423>3.0.CO;2-X     Document Type: Article

References (24)

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16. This is confirmed by X-ray analyses of 3 and several analogous derivatives.
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18. 2) for 448 parameter and 3815 reflections with I > 2σ(I). All non-hydrogen atoms in 7 and 8 were refined with anisotropic, hydrogen atoms at calculated positions with common isotropic parameters (riding model). In addition to the complex 7, a THF molecule, and additional electron density were localized, probably due to the presence of further disordered solvent molecules corresponding to about six C atoms. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication nos. CCDC-100707 and CCDC-101085. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
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