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Volumn 9, Issue 16, 2003, Pages 3859-3866

Tropdad: A new ligand for the synthesis of water-stable paramagnetic [16 + 1]-electron rhodium and iridium complexes

Author keywords

EPR spectroscopy; HYSCORE spectroscopy; Iridium; N ligands; Rhodium

Indexed keywords

CHARGE TRANSFER; IRIDIUM ALLOYS; ORGANIC SOLVENTS; PARAMAGNETIC MATERIALS; POSITIVE IONS; SYNTHESIS (CHEMICAL);

EID: 0041864157     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200204700     Document Type: Article
Times cited : (20)

References (32)
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    • + complexes (M = Rh, Ir; NHchel=bipy, phen, and derivatives): g) G. Costa, C. Tavagnacco, G. Balducci, G. Mestoni, G. Zassinovich, J. Elektroanal. Chem. 1989, 261, 189-203, and references therein. 1,4-diazabutadienes: For a "classical" review see: h) G. van Koten, K. Vrieze, Adv. Organomet. Chem. 1982, 21, 151-239; for the recent use of dad in stabilizing low-valent [16 + 1] Nb and Ta complexes, see: i) P. J. Daff, M. Etienne, B. Donnadieu, S. Z. Knottenbelt, J. E. McGrady, J. Am. Chem. Soc. 2002, 124, 3818-3819, and references therein.
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    • + complexes (M = Rh, Ir; NHchel=bipy, phen, and derivatives): g) G. Costa, C. Tavagnacco, G. Balducci, G. Mestoni, G. Zassinovich, J. Elektroanal. Chem. 1989, 261, 189-203, and references therein. 1,4-diazabutadienes: For a "classical" review see: h) G. van Koten, K. Vrieze, Adv. Organomet. Chem. 1982, 21, 151-239; for the recent use of dad in stabilizing low-valent [16 + 1] Nb and Ta complexes, see: i) P. J. Daff, M. Etienne, B. Donnadieu, S. Z. Knottenbelt, J. E. McGrady, J. Am. Chem. Soc. 2002, 124, 3818-3819, and references therein.
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    • + complexes (M = Rh, Ir; NHchel=bipy, phen, and derivatives): g) G. Costa, C. Tavagnacco, G. Balducci, G. Mestoni, G. Zassinovich, J. Elektroanal. Chem. 1989, 261, 189-203, and references therein. 1,4-diazabutadienes: For a "classical" review see: h) G. van Koten, K. Vrieze, Adv. Organomet. Chem. 1982, 21, 151-239; for the recent use of dad in stabilizing low-valent [16 + 1] Nb and Ta complexes, see: i) P. J. Daff, M. Etienne, B. Donnadieu, S. Z. Knottenbelt, J. E. McGrady, J. Am. Chem. Soc. 2002, 124, 3818-3819, and references therein.
    • (1989) J. Elektroanal. Chem. , vol.261 , pp. 189-203
    • Costa, G.1    Tavagnacco, C.2    Balducci, G.3    Mestoni, G.4    Zassinovich, G.5
  • 8
    • 0037599872 scopus 로고
    • + complexes (M = Rh, Ir; NHchel=bipy, phen, and derivatives): g) G. Costa, C. Tavagnacco, G. Balducci, G. Mestoni, G. Zassinovich, J. Elektroanal. Chem. 1989, 261, 189-203, and references therein. 1,4-diazabutadienes: For a "classical" review see: h) G. van Koten, K. Vrieze, Adv. Organomet. Chem. 1982, 21, 151-239; for the recent use of dad in stabilizing low-valent [16 + 1] Nb and Ta complexes, see: i) P. J. Daff, M. Etienne, B. Donnadieu, S. Z. Knottenbelt, J. E. McGrady, J. Am. Chem. Soc. 2002, 124, 3818-3819, and references therein.
    • (1982) Adv. Organomet. Chem. , vol.21 , pp. 151-239
    • Van Koten, G.1    Vrieze, K.2
  • 9
    • 0037123169 scopus 로고    scopus 로고
    • and references therein
    • + complexes (M = Rh, Ir; NHchel=bipy, phen, and derivatives): g) G. Costa, C. Tavagnacco, G. Balducci, G. Mestoni, G. Zassinovich, J. Elektroanal. Chem. 1989, 261, 189-203, and references therein. 1,4-diazabutadienes: For a "classical" review see: h) G. van Koten, K. Vrieze, Adv. Organomet. Chem. 1982, 21, 151-239; for the recent use of dad in stabilizing low-valent [16 + 1] Nb and Ta complexes, see: i) P. J. Daff, M. Etienne, B. Donnadieu, S. Z. Knottenbelt, J. E. McGrady, J. Am. Chem. Soc. 2002, 124, 3818-3819, and references therein.
    • (2002) J. Am. Chem. Soc. , vol.124 , pp. 3818-3819
    • Daff, P.J.1    Etienne, M.2    Donnadieu, B.3    Knottenbelt, S.Z.4    McGrady, J.E.5
  • 12
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    • [1b] Stacking to give oligomeric units through metal-metal bonds has been reported also for 9,10-phenanthroquinonediiminerhodium and -iridium complexes: S.-S. Chern, G.-H. Lee, S.-M. Peng, J. Chem. Soc. Chem. Commun. 1994, 1645, and references therein.
    • (1994) J. Chem. Soc. Chem. Commun. , pp. 1645
    • Chern, S.-S.1    Lee, G.-H.2    Peng, S.-M.3
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    • a) H. Schönberg, S. Boulmaâz, M. Wörle, L. Liesum, A. Schweiger, H. Grtitzmacher, Angew. Chem. 1998, 109, 1492; Angew. Chem. Int., Ed. 1998, 37, 1423;
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  • 19
    • 0041403781 scopus 로고    scopus 로고
    • note
    • -3. CCDC-205265 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or e-mail: deposit@ccdc.cam.ac.uk).
  • 20
    • 0037123169 scopus 로고    scopus 로고
    • and references therein
    • Pentacoordinate complexes have been reported; for recent examples see: a) P. J. Daff, M. Etienne, B. Donnadieu, S. Z. Knottenbelt, J. E. McGrady, J. Am. Chem. Soc. 2002, 124, 3818-3819, and references therein; b) L. Gonsalvi, J. A. Gaunt, H. Adams, A. Castro, G. J. Sunley, A. Haynes, Organometallics 2003, 22, 1047-1054.
    • (2002) J. Am. Chem. Soc. , vol.124 , pp. 3818-3819
    • Daff, P.J.1    Etienne, M.2    Donnadieu, B.3    Knottenbelt, S.Z.4    McGrady, J.E.5
  • 21
    • 0037416420 scopus 로고    scopus 로고
    • Pentacoordinate complexes have been reported; for recent examples see: a) P. J. Daff, M. Etienne, B. Donnadieu, S. Z. Knottenbelt, J. E. McGrady, J. Am. Chem. Soc. 2002, 124, 3818-3819, and references therein; b) L. Gonsalvi, J. A. Gaunt, H. Adams, A. Castro, G. J. Sunley, A. Haynes, Organometallics 2003, 22, 1047-1054.
    • (2003) Organometallics , vol.22 , pp. 1047-1054
    • Gonsalvi, L.1    Gaunt, J.A.2    Adams, H.3    Castro, A.4    Sunley, G.J.5    Haynes, A.6
  • 31
    • 0041403780 scopus 로고    scopus 로고
    • see web site: http://www.esr.ethz.ch


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.