Mechanism of Asymmetric Hydrogenation of Ketones Catalyzed by BINAP/1,2-Diamine-Ruthenium(II) Complexes

Journal of the American Chemical Society

Volumn 125, Issue 44, 2003, Pages 13490-13503

  Sandoval, Christian A ^a   Ohkuma, Takeshi ^a   Muñiz, Kilian ^a   Noyori, Ryoji ^a  

^a NAGOYA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ORGANIC BASE;

ATMOSPHERIC PRESSURE; CATALYSIS; HYDROGENATION; SUBSTRATES;

KETONES;

1,1' BINAPHTHYL DERIVATIVE; 1,2 DIPHENYLETHYLENEDIAMINE; 2 PROPANOL; 2,2' BIS(DI 4 TOLYLPHOSPHINO) 1,1' BINAPHTHYL; ACETOPHENONE; DEUTERIUM; DIAMINE; ETHYLENEDIAMINE DERIVATIVE; HYDROGEN; KETONE; PHENETHYL ALCOHOL; RUTHENIUM COMPLEX; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; ENANTIOSELECTIVITY; HYDROGENATION; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PRESSURE; REACTION ANALYSIS;

EID: 0242270864     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja030272c     Document Type: Article

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128. 1H HMQC, DPFGSE-NOE) analysis and will be described elsewhere: Sandoval, C. A.; Ohkuma, T.; Yamaguchi, Y.; Kato, K.; Noyori, R. Manuscript in preparation.