Synthesis of a new potentially hemilabile ligand: 1-[2-(diphenylphosphanyl)ethyl]-3,5-dimethylpyrazole, and comparison of its bonding properties with the related 1-[2-(ethylamino)ethyl]-3,5-dimethylpyrazole ligand toward RhI

European Journal of Inorganic Chemistry

Volumn , Issue 11, 2002, Pages 2999-3006

  Esquius, Glòria ^a,b   Pons, Josefina ^a   Yáñez, Ramón ^a   Ros, Josep ^a   Mathieu, René ^b   Donnadieu, Bruno ^b   Lugan, Noël ^b  

^a UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

^b LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

Author keywords

Hemilabile ligands; Hydroformylations; N ligands; P ligands; Rhodium

Indexed keywords

CARBON MONOXIDE; LIGANDS; RHODIUM COMPOUNDS; SINGLE CRYSTALS;

BONDING PROPERTY; HEMILABILE LIGAND; LATTER COMPLEXES; N LIGANDS; N-LIGANDS; P LIGANDS; SINGLE CRYSTAL X-RAY STRUCTURES;

CHELATION;

1 [2 (DIPHENYLPHOSPHANYL)ETHYL] 3,5 DIMETHYLPYRAZOLE; 1 [2 (ETHYLAMINO)ETHYL] 3,5 DIMETHYLPYRAZOLE; PYRAZOLE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; BINDING AFFINITY; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL REACTION; COMPLEX FORMATION; CRYSTAL STRUCTURE; LIGAND BINDING; OLIGOMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 0036840031     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200211)2002:11<2999::AID-EJIC2999>3.0.CO;2-A     Document Type: Article

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