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13C NMR spectrum of PFP is available on http://www.sigmaaldrich.com/spectra/fnmr/FNMR000096.PDF). The presence of peaks outside this region is exclusively from the presence of luminol.
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74
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note
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Thanks to TGA, we can estimate that between 250 and 300 DHLA molecules were adsorbed on each gold particle. N/S ratio of Au@DHLA-luminol, determined by XPS, indicates that 10% of DHLA were modified, Therefore we can evaluate that the number of luminol per particle is around 25-30.
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75
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1242297737
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Roux, S.7
Tillement, O.8
Perriat, P.9
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