Poly-hetero-ω-functionalized Alkanethiolate-stabilized gold cluster compounds

Journal of the American Chemical Society

Volumn 119, Issue 39, 1997, Pages 9175-9178

  Ingram, Roychelle S ^a   Hostetler, Michael J ^a   Murray, Royce W ^a  

^a UNIVERSITY OF NORTH CAROLINA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

GOLD DERIVATIVE;

ARTICLE; CYCLIC POTENTIOMETRY; DRUG STRUCTURE; DRUG SYNTHESIS; IN VITRO STUDY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

EID: 0030824139     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja971734n     Document Type: Article

References (22)

1. (a) Terrill, R. H.; Postlethwaite, T. A.; Chen, C.-H.; Poon, C.-D.; Terzis, A.; Chen, A.; Hutchison, J. E.; Clark, M. R.; Wignall, G.; Londono, J. D.; Superfine, R.; Falvo, M.; Johnson, C. S., Jr.; Samulski, E. T.; Murray, R. W. J. Am. Chem. Soc. 1995, 117, 12357-12548.
2. (b) Brust, M.; Walker, M.; Bethell, D.; Schiffrin, D. J.; Whyman, R. J. Chem. Soc., Chem. Commun. 1994, 801-802.
3. Weisbecker, C. S.; Merritt, M. V.; Whitesides, G. M. Langmuir 1996, 12, 3763-3772.
4. Whetten, R. L.; Khoury, J. T.; Alvarez, M. M.; Murthy, S.; Vezmar, I.; Wang, Z. L.; Stephens, P. W.; Cleveland, C. L.; Luedtke, W. D.; Landman U. Adv. Mater. 1996, 8, 428-433.
5. (e) Other references in Hostetler, M. J.; Murray, R. W. Curr. Opin. Colloid Interface Sci. 1997, 2, 42-50.
6. (a) Green, S. J.; Stokes, J. J; Hosteller, M. J.; Pietron, J. J.; Murray, R. W. J. Phys. Chem. 1997, 101, 2663-2668.
7. (b) Hostetler, M. J.; Green, S. J.; Stokes, J. J.; Murray, R. W. J. Am. Chem. Soc. 1996, 118, 4212-4213.
8. (a) Bar, G.; Rubin, S.; Cutts, R. W.; Taylor, T. N.; Zawodzinski, T. A. Langmuir 1996, 12, 1172-1179.
9. (b) Harris, C. H.; Ratner, M. A.; Shriver, D. F. Macromolecules 1987, 20, 1778.
10. Schmid, G. Chem. Rev. 1992, 92, 1709-1727.
11. Chidsey, C. E. D.; Bertozzi, C. R.; Putvinski, T. M.; Musjce, A. M. J. Am. Chem. Soc. 1990, 112, 4301.
12. Bain, C. D.; Troughton, E. B.; Tao, Y.; Evall, J.; Whitesides, G. M.; Nuzzo, R. G. J. Am. Chem. Soc. 1989, 111, 321-335.
13. Zhang, L.; Lu, T.; Gokel, G. W.; Kaifer, A. E. Langmuir 1993, 9, 786-791.
14. Hostetler, M. J.; Wingate, J. E.; Zhang, C.; Harris, J. E.; Vachet, R. W.; Clark, M. R.; Londono, D.; Green, S. J.; Stokes, J. J.; Wignall, G. D.; Glish, G. L.; Porter, M. D.; Evans, N. D.; Murray, R. W. Submitted.
15. Confirmed by small-angle X-ray scattering experiments: Hostetler, M. J.; Londono, J. D.; Murray, R. W. Unpublished results, 1996.
16. 1H-NMR linewidths were too broad to accurately assess product mole ratios.
17. -1.
18. Hosteller, M. J.; Murray, R. W. Manuscript in preparation.
19. SITES is the average number of redox sites per cluster.
20. 2/s, 28 Å, and 24 Å, respectively.
21. 1H NMR line width analysis as described in ref 8. The Au core diameter dispersity for this material was approximately ±20%.
22. Ingram, R. S.; Hostetler, M. J.; Murray, R. W.; Schaaf, G. T.; Khoury, J.; Whetten, R. L.; Bigioni, T. P.; Guthrie, D. K.; First, P. N. J. Am. Chem. Soc., in press.