Reconstitution of apo-glucose oxidase on nitrospiropyran and FAD mixed monolayers on gold electrodes: Photostimulation of bioelectrocatalytic features of the biocatalyst

Journal of the American Chemical Society

Volumn 120, Issue 36, 1998, Pages 9335-9341

  Blonder, Ron ^a   Willner, Itamar ^a   Bückmann, Andreas F ^b  

^a HEBREW UNIVERSITY OF JERUSALEM   (Israel)

^b HELMHOLTZ CENTRE FOR INFECTION RESEARCH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

FLAVINE ADENINE NUCLEOTIDE; GLUCOSE OXIDASE; GOLD; N DIMETHYL 2 AMINOETHYLFERROCENE; N6 (2 AMINOETHYL)FLAVINE ADENINE NUCLEOTIDE; NITROSPIROPYRAN; PYRAN DERIVATIVE; UNCLASSIFIED DRUG;

AMPEROMETRY; ARTICLE; CATALYSIS; CHEMICAL MODIFICATION; COVALENT BOND; ELECTRICITY; ENZYME ACTIVE SITE; ENZYME KINETICS; GLUCOSE OXIDATION; METAL BINDING; PHOTOSTIMULATION; SIGNAL TRANSDUCTION;

EID: 0032538044     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja981126n     Document Type: Article

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33. +-monolayer electrodes, despite the positive charge associated with reduced 5. This can be attributed to the presence of surface defects in the monolayer assembly, which enables electrical communication between 5 and the electrode. Upon oxidation of 5, the electrostatic interactions are amplified as a result of the formation of a redox mediator bearing two positive charges.