Dynamics of place-exchange reactions on monolayer-protected gold cluster molecules

Langmuir

Volumn 15, Issue 11, 1999, Pages 3782-3789

  Hostetler, Michael J ^a   Templeton, Allen C ^a   Murray, Royce W ^a  

^a UNIVERSITY OF NORTH CAROLINA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ASSOCIATION REACTIONS; CHROMATOGRAPHIC ANALYSIS; INFRARED SPECTROSCOPY; MONOLAYERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC SOLVENTS; REACTION KINETICS; SOLUBILITY; SULFUR COMPOUNDS; SYNTHESIS (CHEMICAL);

LIGANDS; PLACE EXCHANGE REACTIONS;

GOLD;

EID: 0032630577     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la981598f     Document Type: Article

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38. 2CC11SH had entered and remained at reactive vertice and edge sites, then it would be reasonable to expect these ligands to be most susceptible to subsequent exchange. This was not observed. One explanation is that cluster-bound ligands can slowly migrate onto the terrace surfaces; experiments are in progress that should help verify this hypothesis.
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