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Volumn 127, Issue 20, 2005, Pages 7594-7600

Supramolecular layer-by-layer assembly: Alternating adsorptions of guest- and host-functionalized molecules and particles using multivalent supramolecular interactions

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; ATOMIC FORCE MICROSCOPY; DENDRIMERS; DEPOSITION; GOLD; MULTILAYERS; NANOSTRUCTURED MATERIALS;

EID: 19944366684     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja051093t     Document Type: Article
Times cited : (229)

References (91)
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    • note
    • For self-assembled monolayers on gold surfaces:
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    • (b) For a review, see: Decher, G. Science 1997, 277, 1232-1237.
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    • For a review on electrostatic LBL assembly: Hammond, P. T. Adv. Mater. 2004, 16, 1271-1293.
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    • For a general review on cyclodextrins, see: Chem. Rev. 1998, 98, volume 5.
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    • For a list with typical guest molecules, see: Rekharsky, M. V.; Inoue, Y. Chem. Rev. 1998, 98, 1880-1901.
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    • note
    • The lattice constant was calculated assuming monodisperse CD Au NPs of 2.8 nm in core diameter, adding twice the cyclodextrin cavity height of 0.8 nm. The total weight of the CD Au NPs is constituted of gold (62%), cyclodextrin(25%), and water (13%) (see ref 33). The hexagonal packing on the surface gives the maximal surface coverage possible for a well-packed self-assembled monolayer of a monodisperse sample of nanoparticles, assuming the formation of specific interactions only.


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