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To the best of our knowledge, examples of μ-(1,3) bridging azide systems for iron have yet to be reported. For examples of μ-(1,1) systems, see: (a) Clemente-Juan, J. M.; Mackiewicz, C.; Verelst, M.; Dahan, F.; Bousseksou, A.; Sanakis, Y.; Tuchagues, J.-P. Inorg. Chem. 2002, 41, 1478. (b) Reddy, K. R.; Rajasekharan, M. V.; Tuchagues, J.-P. Inorg. Chem. 1998, 37, 5978. (c) De Munno, G.; Poerio, T.; Viau, G.; Juive, M.; Lloret, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 1459. (d) De Munno, G.; Poerio, T.; Viau, G.; Julve, M.; Lloret, F. Chem. Commun. 1996, 2587.
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1842790734
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To the best of our knowledge, examples of μ-(1,3) bridging azide systems for iron have yet to be reported. For examples of μ-(1,1) systems, see: (a) Clemente-Juan, J. M.; Mackiewicz, C.; Verelst, M.; Dahan, F.; Bousseksou, A.; Sanakis, Y.; Tuchagues, J.-P. Inorg. Chem. 2002, 41, 1478. (b) Reddy, K. R.; Rajasekharan, M. V.; Tuchagues, J.-P. Inorg. Chem. 1998, 37, 5978. (c) De Munno, G.; Poerio, T.; Viau, G.; Julve, M.; Lloret, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 1459. (d) De Munno, G.; Poerio, T.; Viau, G.; Julve, M.; Lloret, F. Chem. Commun. 1996, 2587.
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To the best of our knowledge, examples of μ-(1,3) bridging azide systems for iron have yet to be reported. For examples of μ-(1,1) systems, see: (a) Clemente-Juan, J. M.; Mackiewicz, C.; Verelst, M.; Dahan, F.; Bousseksou, A.; Sanakis, Y.; Tuchagues, J.-P. Inorg. Chem. 2002, 41, 1478. (b) Reddy, K. R.; Rajasekharan, M. V.; Tuchagues, J.-P. Inorg. Chem. 1998, 37, 5978. (c) De Munno, G.; Poerio, T.; Viau, G.; Julve, M.; Lloret, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 1459. (d) De Munno, G.; Poerio, T.; Viau, G.; Julve, M.; Lloret, F. Chem. Commun. 1996, 2587.
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To the best of our knowledge, examples of μ-(1,3) bridging azide systems for iron have yet to be reported. For examples of μ-(1,1) systems, see: (a) Clemente-Juan, J. M.; Mackiewicz, C.; Verelst, M.; Dahan, F.; Bousseksou, A.; Sanakis, Y.; Tuchagues, J.-P. Inorg. Chem. 2002, 41, 1478. (b) Reddy, K. R.; Rajasekharan, M. V.; Tuchagues, J.-P. Inorg. Chem. 1998, 37, 5978. (c) De Munno, G.; Poerio, T.; Viau, G.; Julve, M.; Lloret, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 1459. (d) De Munno, G.; Poerio, T.; Viau, G.; Julve, M.; Lloret, F. Chem. Commun. 1996, 2587.
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A τ value of 1 corresponds to an ideal trigonal bipyramidal geometry, while a τ value of O corresponds to an ideal square pyramidal geometry. See: Addison, A. W.; Rao, T. N.; Reedijk, J.; van Rin, J.; Verschoor, G. C. J. Chem. Soc., Dalton Trans. 1984, 1349.
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2, which features a ferromagnetically coupled S = 4 electronic configuration, was also attributed to zero-field splitting. See: Shores, M. P.; Sokol, J. J.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 2279. For a more detailed discussion concerning the magnetism of differous bridged systems, see: Hendrich, M. P.; Day, E. P.; Wang, C.-P.; Synder, B. S.; Holm, R. H.; Münck, E. Inorg. Chem. 1994, 55, 2848 and references therein.
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and references therein
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2, which features a ferromagnetically coupled S = 4 electronic configuration, was also attributed to zero-field splitting. See: Shores, M. P.; Sokol, J. J.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 2279. For a more detailed discussion concerning the magnetism of differous bridged systems, see: Hendrich, M. P.; Day, E. P.; Wang, C.-P.; Synder, B. S.; Holm, R. H.; Münck, E. Inorg. Chem. 1994, 55, 2848 and references therein.
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We have considered the presence of a (μ-NH) functionality instead of a (μ-N) ligand. However, IR studies of 3 as both a solution (THF) and a solid (Nujol, KBr pellet) provide no evidence for an N-H vibration. Additionally, it is not possible to assign formal iron oxidation states with a (μ-NH) ligand and still maintain a diamagnetic manifold while accounting for all charges.
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