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Volumn 127, Issue 6, 2005, Pages 1913-1923

Ground-state singlet L3Fe-(μ-N)-FeL3 and L 3Fe(NR) complexes featuring pseudotetrahedral Fe(II) centers

Author keywords

[No Author keywords available]

Indexed keywords

ANTIFERROMAGNETIC MATERIALS; CHEMICAL BONDS; ELECTRONIC STRUCTURE; GROUND STATE; ORGANOMETALLICS; PROBABILITY DENSITY FUNCTION; THERMAL EFFECTS;

EID: 13644259048     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0453073     Document Type: Article
Times cited : (168)

References (71)
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    • High-spin iron(V) terminal nitrides have been reported on the basis of spectroscopic data at low temperatures. See: (a) Meyer, K. M.; Eckhard, B.; Mienert, B.; Weyhermüller, T.; Wieghardt, K. J. Am. Chem. Soc. 1999, 121, 4859. (b) Wagner, W.-D.; Nakamoto, K. J. Am. Chem. Soc. 1989, 111, 1590.
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    • 3], see: (a) Jenkins, D. M.; Peters, J. C. J. Am. Chem. Soc. 2003, 125, 11162. (b) Jenkins, D. M.; Betley, T. A.; Peters, J. C. J. Am. Chem. Soc. 2002, 124, 11238. (c) Jenkins, D. M.; Di Bilio, A. J.; Allen, M. J.; Betley, T. A.; Peters, J. C. J. Am. Chem. Soc. 2002, 124, 15336. (d) Feldman, J. D.; Peters, J. C.; Tilley, T. D. Organometallics 2002, 21, 4065. (e) Feldman, J. D.; Peters, J. C.; Tilley, T. D. Organometallics 2002, 21, 4050.
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    • 3], see: (a) Jenkins, D. M.; Peters, J. C. J. Am. Chem. Soc. 2003, 125, 11162. (b) Jenkins, D. M.; Betley, T. A.; Peters, J. C. J. Am. Chem. Soc. 2002, 124, 11238. (c) Jenkins, D. M.; Di Bilio, A. J.; Allen, M. J.; Betley, T. A.; Peters, J. C. J. Am. Chem. Soc. 2002, 124, 15336. (d) Feldman, J. D.; Peters, J. C.; Tilley, T. D. Organometallics 2002, 21, 4065. (e) Feldman, J. D.; Peters, J. C.; Tilley, T. D. Organometallics 2002, 21, 4050.
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    • 6}.
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    • To the best of our knowledge, examples of μ-(1,3) bridging azide systems for iron have yet to be reported. For examples of μ-(1,1) systems, see: (a) Clemente-Juan, J. M.; Mackiewicz, C.; Verelst, M.; Dahan, F.; Bousseksou, A.; Sanakis, Y.; Tuchagues, J.-P. Inorg. Chem. 2002, 41, 1478. (b) Reddy, K. R.; Rajasekharan, M. V.; Tuchagues, J.-P. Inorg. Chem. 1998, 37, 5978. (c) De Munno, G.; Poerio, T.; Viau, G.; Juive, M.; Lloret, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 1459. (d) De Munno, G.; Poerio, T.; Viau, G.; Julve, M.; Lloret, F. Chem. Commun. 1996, 2587.
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  • 43
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    • To the best of our knowledge, examples of μ-(1,3) bridging azide systems for iron have yet to be reported. For examples of μ-(1,1) systems, see: (a) Clemente-Juan, J. M.; Mackiewicz, C.; Verelst, M.; Dahan, F.; Bousseksou, A.; Sanakis, Y.; Tuchagues, J.-P. Inorg. Chem. 2002, 41, 1478. (b) Reddy, K. R.; Rajasekharan, M. V.; Tuchagues, J.-P. Inorg. Chem. 1998, 37, 5978. (c) De Munno, G.; Poerio, T.; Viau, G.; Julve, M.; Lloret, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 1459. (d) De Munno, G.; Poerio, T.; Viau, G.; Julve, M.; Lloret, F. Chem. Commun. 1996, 2587.
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    • Reddy, K.R.1    Rajasekharan, M.V.2    Tuchagues, J.-P.3
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    • To the best of our knowledge, examples of μ-(1,3) bridging azide systems for iron have yet to be reported. For examples of μ-(1,1) systems, see: (a) Clemente-Juan, J. M.; Mackiewicz, C.; Verelst, M.; Dahan, F.; Bousseksou, A.; Sanakis, Y.; Tuchagues, J.-P. Inorg. Chem. 2002, 41, 1478. (b) Reddy, K. R.; Rajasekharan, M. V.; Tuchagues, J.-P. Inorg. Chem. 1998, 37, 5978. (c) De Munno, G.; Poerio, T.; Viau, G.; Julve, M.; Lloret, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 1459. (d) De Munno, G.; Poerio, T.; Viau, G.; Julve, M.; Lloret, F. Chem. Commun. 1996, 2587.
    • (1997) Angew. Chem., Int. Ed. Engl. , vol.36 , pp. 1459
    • De Munno, G.1    Poerio, T.2    Viau, G.3    Julve, M.4    Lloret, F.5
  • 45
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    • To the best of our knowledge, examples of μ-(1,3) bridging azide systems for iron have yet to be reported. For examples of μ-(1,1) systems, see: (a) Clemente-Juan, J. M.; Mackiewicz, C.; Verelst, M.; Dahan, F.; Bousseksou, A.; Sanakis, Y.; Tuchagues, J.-P. Inorg. Chem. 2002, 41, 1478. (b) Reddy, K. R.; Rajasekharan, M. V.; Tuchagues, J.-P. Inorg. Chem. 1998, 37, 5978. (c) De Munno, G.; Poerio, T.; Viau, G.; Julve, M.; Lloret, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 1459. (d) De Munno, G.; Poerio, T.; Viau, G.; Julve, M.; Lloret, F. Chem. Commun. 1996, 2587.
    • (1996) Chem. Commun. , pp. 2587
    • De Munno, G.1    Poerio, T.2    Viau, G.3    Julve, M.4    Lloret, F.5
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    • 2, which features a ferromagnetically coupled S = 4 electronic configuration, was also attributed to zero-field splitting. See: Shores, M. P.; Sokol, J. J.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 2279. For a more detailed discussion concerning the magnetism of differous bridged systems, see: Hendrich, M. P.; Day, E. P.; Wang, C.-P.; Synder, B. S.; Holm, R. H.; Münck, E. Inorg. Chem. 1994, 55, 2848 and references therein.
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    • and references therein
    • 2, which features a ferromagnetically coupled S = 4 electronic configuration, was also attributed to zero-field splitting. See: Shores, M. P.; Sokol, J. J.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 2279. For a more detailed discussion concerning the magnetism of differous bridged systems, see: Hendrich, M. P.; Day, E. P.; Wang, C.-P.; Synder, B. S.; Holm, R. H.; Münck, E. Inorg. Chem. 1994, 55, 2848 and references therein.
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    • note
    • We have considered the presence of a (μ-NH) functionality instead of a (μ-N) ligand. However, IR studies of 3 as both a solution (THF) and a solid (Nujol, KBr pellet) provide no evidence for an N-H vibration. Additionally, it is not possible to assign formal iron oxidation states with a (μ-NH) ligand and still maintain a diamagnetic manifold while accounting for all charges.
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    • See, for example: (a) Cherry, J.-P. F.; Stephens, F. H.; Johnson, M. J. A.; Diaconescu, P. L.; Cummins, C. C. Inorg. Chem. 2001, 40, 6860. (b) Tsai, Y.-C.; Johnson, M. J. A.; Mindiola, D. J.; Cummins, C. C. J. Am. Chem. Soc. 1999, 121, 10426. (c) Banaszak Holl, M. M.; Kersting, M.; Pendley, B. D.; Wolczanski, P. T. Inorg. Chem. 1990, 29, 1518.
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    • See, for example: (a) Cherry, J.-P. F.; Stephens, F. H.; Johnson, M. J. A.; Diaconescu, P. L.; Cummins, C. C. Inorg. Chem. 2001, 40, 6860. (b) Tsai, Y.-C.; Johnson, M. J. A.; Mindiola, D. J.; Cummins, C. C. J. Am. Chem. Soc. 1999, 121, 10426. (c) Banaszak Holl, M. M.; Kersting, M.; Pendley, B. D.; Wolczanski, P. T. Inorg. Chem. 1990, 29, 1518.
    • (1999) J. Am. Chem. Soc. , vol.121 , pp. 10426
    • Tsai, Y.-C.1    Johnson, M.J.A.2    Mindiola, D.J.3    Cummins, C.C.4
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    • See, for example: (a) Cherry, J.-P. F.; Stephens, F. H.; Johnson, M. J. A.; Diaconescu, P. L.; Cummins, C. C. Inorg. Chem. 2001, 40, 6860. (b) Tsai, Y.-C.; Johnson, M. J. A.; Mindiola, D. J.; Cummins, C. C. J. Am. Chem. Soc. 1999, 121, 10426. (c) Banaszak Holl, M. M.; Kersting, M.; Pendley, B. D.; Wolczanski, P. T. Inorg. Chem. 1990, 29, 1518.
    • (1990) Inorg. Chem. , vol.29 , pp. 1518
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    • note
    • 3]Feequiv;N will be elaborated in due course.
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