Coordination chemistry and reactivity of new zwitterionic rhodium and iridium complexes featuring the tripodal phosphine ligand [PhB(CH 2P iPr 2) 3] -. Activation of H-H, Si-H, and ligand B-C bonds

Organometallics

Volumn 23, Issue 10, 2004, Pages 2488-2502

  Turculet, Laura ^a   Feldman, Jay D ^a   Tilley, T Don ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COORDINATION CHEMISTRY; DEHYDROCOUPLING; LIGANDS; METAL-CATALYZED TRANSFORMATIONS;

ACTIVATION ANALYSIS; CATALYSIS; COORDINATION REACTIONS; DECOMPOSITION; DISSOCIATION; HYDROGEN BONDS; IRIDIUM COMPOUNDS; ISOMERIZATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOTOCHEMICAL REACTIONS; REACTION KINETICS; RESONANCE; RHODIUM COMPOUNDS; SOLVENTS; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

COMPLEXATION;

EID: 2542473311     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om030686e     Document Type: Article

References (62)

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10. For examples of transition metal silylene complexes prepared via α-hydride elimination routes, see: (a) Mitchell, G. P.; Tilley, T. D. J. Am. Chem. Soc. 1998, 120, 7635. (b) Mitchell, G. P.; Tilley, T. D. Angew. Chem., Int. Ed. 1998, 37, 2524. (c) Peters, J. C.; Feldman, J. D.; Tilley, T. D. J. Am. Chem. Soc. 1999, 121, 9871. (d) Klei, S. R.; Tilley, T. D.; Bergman, R. G. J. Am. Chem. Soc. 2000, 122, 1816. (e) Mork, B. V.; Tilley, T. D. J. Am. Chem. Soc. 2001, 123, 9702. (f) Feldman, J. D.; Peters, J. C.; Tilley, T. D. Organometallics 2002, 21, 4065.
11. For examples of transition metal silylene complexes prepared via α-hydride elimination routes, see: (a) Mitchell, G. P.; Tilley, T. D. J. Am. Chem. Soc. 1998, 120, 7635. (b) Mitchell, G. P.; Tilley, T. D. Angew. Chem., Int. Ed. 1998, 37, 2524. (c) Peters, J. C.; Feldman, J. D.; Tilley, T. D. J. Am. Chem. Soc. 1999, 121, 9871. (d) Klei, S. R.; Tilley, T. D.; Bergman, R. G. J. Am. Chem. Soc. 2000, 122, 1816. (e) Mork, B. V.; Tilley, T. D. J. Am. Chem. Soc. 2001, 123, 9702. (f) Feldman, J. D.; Peters, J. C.; Tilley, T. D. Organometallics 2002, 21, 4065.
12. For examples of transition metal silylene complexes prepared via α-hydride elimination routes, see: (a) Mitchell, G. P.; Tilley, T. D. J. Am. Chem. Soc. 1998, 120, 7635. (b) Mitchell, G. P.; Tilley, T. D. Angew. Chem., Int. Ed. 1998, 37, 2524. (c) Peters, J. C.; Feldman, J. D.; Tilley, T. D. J. Am. Chem. Soc. 1999, 121, 9871. (d) Klei, S. R.; Tilley, T. D.; Bergman, R. G. J. Am. Chem. Soc. 2000, 122, 1816. (e) Mork, B. V.; Tilley, T. D. J. Am. Chem. Soc. 2001, 123, 9702. (f) Feldman, J. D.; Peters, J. C.; Tilley, T. D. Organometallics 2002, 21, 4065.
13. For examples of transition metal silylene complexes prepared via α-hydride elimination routes, see: (a) Mitchell, G. P.; Tilley, T. D. J. Am. Chem. Soc. 1998, 120, 7635. (b) Mitchell, G. P.; Tilley, T. D. Angew. Chem., Int. Ed. 1998, 37, 2524. (c) Peters, J. C.; Feldman, J. D.; Tilley, T. D. J. Am. Chem. Soc. 1999, 121, 9871. (d) Klei, S. R.; Tilley, T. D.; Bergman, R. G. J. Am. Chem. Soc. 2000, 122, 1816. (e) Mork, B. V.; Tilley, T. D. J. Am. Chem. Soc. 2001, 123, 9702. (f) Feldman, J. D.; Peters, J. C.; Tilley, T. D. Organometallics 2002, 21, 4065.
14. For examples of transition metal silylene complexes prepared via α-hydride elimination routes, see: (a) Mitchell, G. P.; Tilley, T. D. J. Am. Chem. Soc. 1998, 120, 7635. (b) Mitchell, G. P.; Tilley, T. D. Angew. Chem., Int. Ed. 1998, 37, 2524. (c) Peters, J. C.; Feldman, J. D.; Tilley, T. D. J. Am. Chem. Soc. 1999, 121, 9871. (d) Klei, S. R.; Tilley, T. D.; Bergman, R. G. J. Am. Chem. Soc. 2000, 122, 1816. (e) Mork, B. V.; Tilley, T. D. J. Am. Chem. Soc. 2001, 123, 9702. (f) Feldman, J. D.; Peters, J. C.; Tilley, T. D. Organometallics 2002, 21, 4065.
15. For additional examples of base-free transition metal dialkyl and diaryl silylene complexes prepared by routes other than α-hydride elimination, see: (a) Grumbine, S. K.; Mitchell, G. P.; Straus, D. A.; Tilley, T. D.; Rheingold, A. L. Organometallics 1998, 17, 5607. (b) Wanandi, P. W.; Glaser, P. B.; Tilley, T. D. J. Am. Chem. Soc. 2000, 122, 972. (c) Feldman, J. D.; Mitchell, G. P.; Nolte, J.-O.; Tilley, T. D. J. Am. Chem. Soc. 1998, 120, 11184.
16. For additional examples of base-free transition metal dialkyl and diaryl silylene complexes prepared by routes other than α-hydride elimination, see: (a) Grumbine, S. K.; Mitchell, G. P.; Straus, D. A.; Tilley, T. D.; Rheingold, A. L. Organometallics 1998, 17, 5607. (b) Wanandi, P. W.; Glaser, P. B.; Tilley, T. D. J. Am. Chem. Soc. 2000, 122, 972. (c) Feldman, J. D.; Mitchell, G. P.; Nolte, J.-O.; Tilley, T. D. J. Am. Chem. Soc. 1998, 120, 11184.
17. For additional examples of base-free transition metal dialkyl and diaryl silylene complexes prepared by routes other than α-hydride elimination, see: (a) Grumbine, S. K.; Mitchell, G. P.; Straus, D. A.; Tilley, T. D.; Rheingold, A. L. Organometallics 1998, 17, 5607. (b) Wanandi, P. W.; Glaser, P. B.; Tilley, T. D. J. Am. Chem. Soc. 2000, 122, 972. (c) Feldman, J. D.; Mitchell, G. P.; Nolte, J.-O.; Tilley, T. D. J. Am. Chem. Soc. 1998, 120, 11184.
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28. 3 have also been reported. Representative examples include: (a) Knorr, M.; Gilvert, S.; Schubert, U. J. Organomet. Chem. 1988, 347, C17-C20. (b) Kono, H.; Wakao, N.; Ito, K; Nagai, Y. J. Organomet. Chem. 1977, 132, 53. (c) Procopio, L. J.; Berry. D. H. J. Am. Chem. Soc. 1991, 113, 4039. (d) Bull, M.; Espinet, P.; Esteruelas, M. A.; Lahoz, F. J.; Lledós, A.; Martinez-Ilarduya, J. M.; Maaeras, F.; Modrego, J.; Oñate, E.; Oro, L. A.; Sola, E.; Valero, C. Inorg. Chem. 1996, 35, 1250. (e) Rickard, C. E. F.; Roper, W. H.; Woodgate, S. D.; Wright, L. J. J. Organomet. Chem. 2000, 609, 177.
29. 3 have also been reported. Representative examples include: (a) Knorr, M.; Gilvert, S.; Schubert, U. J. Organomet. Chem. 1988, 347, C17-C20. (b) Kono, H.; Wakao, N.; Ito, K; Nagai, Y. J. Organomet. Chem. 1977, 132, 53. (c) Procopio, L. J.; Berry. D. H. J. Am. Chem. Soc. 1991, 113, 4039. (d) Bull, M.; Espinet, P.; Esteruelas, M. A.; Lahoz, F. J.; Lledós, A.; Martinez-Ilarduya, J. M.; Maaeras, F.; Modrego, J.; Oñate, E.; Oro, L. A.; Sola, E.; Valero, C. Inorg. Chem. 1996, 35, 1250. (e) Rickard, C. E. F.; Roper, W. H.; Woodgate, S. D.; Wright, L. J. J. Organomet. Chem. 2000, 609, 177.
30. 3 have also been reported. Representative examples include: (a) Knorr, M.; Gilvert, S.; Schubert, U. J. Organomet. Chem. 1988, 347, C17-C20. (b) Kono, H.; Wakao, N.; Ito, K; Nagai, Y. J. Organomet. Chem. 1977, 132, 53. (c) Procopio, L. J.; Berry. D. H. J. Am. Chem. Soc. 1991, 113, 4039. (d) Bull, M.; Espinet, P.; Esteruelas, M. A.; Lahoz, F. J.; Lledós, A.; Martinez-Ilarduya, J. M.; Maaeras, F.; Modrego, J.; Oñate, E.; Oro, L. A.; Sola, E.; Valero, C. Inorg. Chem. 1996, 35, 1250. (e) Rickard, C. E. F.; Roper, W. H.; Woodgate, S. D.; Wright, L. J. J. Organomet. Chem. 2000, 609, 177.
31. 3 have also been reported. Representative examples include: (a) Knorr, M.; Gilvert, S.; Schubert, U. J. Organomet. Chem. 1988, 347, C17-C20. (b) Kono, H.; Wakao, N.; Ito, K; Nagai, Y. J. Organomet. Chem. 1977, 132, 53. (c) Procopio, L. J.; Berry. D. H. J. Am. Chem. Soc. 1991, 113, 4039. (d) Bull, M.; Espinet, P.; Esteruelas, M. A.; Lahoz, F. J.; Lledós, A.; Martinez-Ilarduya, J. M.; Maaeras, F.; Modrego, J.; Oñate, E.; Oro, L. A.; Sola, E.; Valero, C. Inorg. Chem. 1996, 35, 1250. (e) Rickard, C. E. F.; Roper, W. H.; Woodgate, S. D.; Wright, L. J. J. Organomet. Chem. 2000, 609, 177.
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