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Another case of an isolated, coordinatively unsaturated ruthenium species featuring a sterically encumbered hydrotris(3,5-diisopropylpyrazolyl)borato ligand features an agostic C-H bond interaction occupying the sixth coordination site on Ru: (a) Takahashi, Y.; Hikichi, S.; Akita, M.; Moro-oka, Y. Organometallics 1999, 18, 2571. Related transiently stable species that feature agostic interactions have been studied: (b) Trimmel, G.; Slugovc, C.; Wiede, P.; Mereiter, K.; Sapunov, V. N.; Schmid, R.; Kirchner, K. Inorg. Chem. 1997, 36, 1076. (c) Tenorio, M. A. J.; Tenorio, M. J.; Puerta, M. C.; Valerga, P. J. Chem. Soc., Dalton Trans. 1998, 3601.
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Another case of an isolated, coordinatively unsaturated ruthenium species featuring a sterically encumbered hydrotris(3,5-diisopropylpyrazolyl)borato ligand features an agostic C-H bond interaction occupying the sixth coordination site on Ru: (a) Takahashi, Y.; Hikichi, S.; Akita, M.; Moro-oka, Y. Organometallics 1999, 18, 2571. Related transiently stable species that feature agostic interactions have been studied: (b) Trimmel, G.; Slugovc, C.; Wiede, P.; Mereiter, K.; Sapunov, V. N.; Schmid, R.; Kirchner, K. Inorg. Chem. 1997, 36, 1076. (c) Tenorio, M. A. J.; Tenorio, M. J.; Puerta, M. C.; Valerga, P. J. Chem. Soc., Dalton Trans. 1998, 3601.
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Another case of an isolated, coordinatively unsaturated ruthenium species featuring a sterically encumbered hydrotris(3,5-diisopropylpyrazolyl)borato ligand features an agostic C-H bond interaction occupying the sixth coordination site on Ru: (a) Takahashi, Y.; Hikichi, S.; Akita, M.; Moro-oka, Y. Organometallics 1999, 18, 2571. Related transiently stable species that feature agostic interactions have been studied: (b) Trimmel, G.; Slugovc, C.; Wiede, P.; Mereiter, K.; Sapunov, V. N.; Schmid, R.; Kirchner, K. Inorg. Chem. 1997, 36, 1076. (c) Tenorio, M. A. J.; Tenorio, M. J.; Puerta, M. C.; Valerga, P. J. Chem. Soc., Dalton Trans. 1998, 3601.
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Preparation and spectroscopic information included in the Supporting Information.
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33
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0041522958
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note
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3]CoBr(CO) were reported in the Supporting Information of ref 1a.
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