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Volumn 124, Issue 38, 2002, Pages 11238-11239

Oxidative group transfer to Co(I) affords a terminal Co(III) imido complex

Author keywords

[No Author keywords available]

Indexed keywords

COBALT COMPLEX;

EID: 0037174375     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja026852b     Document Type: Article
Times cited : (202)

References (45)
  • 5
  • 33
    • 0010390037 scopus 로고    scopus 로고
    • note
    • 1 = 0.00415 [1 > 2δ(1)], GOF = 1.670.
  • 36
    • 0010345772 scopus 로고    scopus 로고
    • note
    • These studies will be elaborated in a forthcoming full paper. Briefly, a geometry optimization was carried out with the program JAGUAR (B3LYP/LACVP**) using the complete crystal coordinates of complex 4. Convergence was achieved, and the theoretical structure obtained for 4 was in fair agreement with that determined experimentally (Figure 2a).
  • 37
    • 0010345178 scopus 로고    scopus 로고
    • note
    • 0.
  • 42
    • 0010343787 scopus 로고    scopus 로고
    • note
    • 1 = 0.0466 [> 2δ(I)], GOF = 1.572.
  • 45
    • 0010415947 scopus 로고    scopus 로고
    • note
    • 1H NMR (∼45%), which presumably arises from thermal isocyanate degradation during the course of the reaction.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.