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Volumn 18, Issue 15, 2002, Pages 5851-5860

Kinetics of electrochemical derivatization of the silicon surface by grignards

Author keywords

[No Author keywords available]

Indexed keywords

ELECTROCHEMISTRY; HALOGENATION; HYDROGENATION; INFRARED SPECTROSCOPY; INTERFACES (MATERIALS); RATE CONSTANTS; X RAY PHOTOELECTRON SPECTROSCOPY;

EID: 0037162614     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la0203739     Document Type: Article
Times cited : (63)

References (31)
  • 3
    • 0033591711 scopus 로고    scopus 로고
    • and references therein
    • Buriak, J.M. Chem. Commun. 1999, 1051 and references therein.
    • (1999) Chem. Commun. , pp. 1051
    • Buriak, J.M.1
  • 28
    • 0011721327 scopus 로고    scopus 로고
    • note
    • The low generation rate of halogen radicals in the case of chlorine may also account for the significantly faster kinetics observed as compared to the case of bromine and iodine (see Table 1): an increased concentration of halogen radicals (the case of Br and I, especially for methyl Grignards) may lead to a parallel recombination pathway for the alkyl radicals, effectively increasing the value of K.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.