Dynamic resolution and stereoinversion of secondary alcohols by chemo-enzymatic processes

Current Opinion in Biotechnology

Volumn 11, Issue 6, 2000, Pages 565-571

  Azerad, Robert ^a   Buisson, Didier ^a  

^a UNIVERSITÉ PARIS DESCARTES   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL;

ACETYLATION; ALCOHOL METABOLISM; CATALYSIS; ENZYME MECHANISM; HYDROXYLATION; OXIDATION REDUCTION REACTION; PRIORITY JOURNAL; RACEMIC MIXTURE; REACTION ANALYSIS; REVIEW; STEREOCHEMISTRY;

EID: 0033637451     PISSN: 09581669     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0958-1669(00)00144-0     Document Type: Review

References (39)

1. Biocatalytic deracemization techniques: Dynamic resolutions and stereoinversions
2. Biocatalytic transformation of racemates into chiral building blocks in 100% chemical yield and 100% enantiomeric excess
3. Deracemization of compounds possessing a sec-alcohol or -amino group through a cyclic oxidation-reduction sequence: A kinetic treatment
4. Dynamic kinetic resolution
5. Stereoinversions using microbial redox-reactions
6. Deracemization of (+/-)-mandelic acid using a lipase-mandelate racemase two-enzyme system
7. Stabilization and activity-enhancement of mandelate racemase from Pseudomonas putida ATCC 12336 by immobilization
8. Controlled racemization of optically active organic compounds: Prospects for asymmetric transformation
9. One-pot synthesis of optically active cyanohydrin acetates from aldehydes via lipase-catalyzed kinetic resolution coupled with in situ formation and racemization of cyanohydrins
10. Production of R-(-)-mandelic acid from mandelonitrile by Alcaligenes faecalis
11. Conversion of a cyanhydrin compound into S-(-)-3-phenyllactic acid by enantioselective hydrolytic activity of Pseudomonas sp BC-18
12. Chemoenzymatic synthesis of (4S,5R)-5-hydroxy-gamma-decalactone
13. Stereocontrolled reduction of β-ketoesters with Geotrichum candidum
14. Ruthenium- and enzyme-catalyzed dynamic kinetic resolution of secondary alcohols
15. Dynamic kinetic resolution of secondary diols via coupled ruthenium and enzyme catalysis
16. Dynamic kinetic resolution of alpha-hydroxy acid esters
17. Enzymatic resolution of secondary alcohols coupled with ruthenium-catalyzed racemization without hydrogen mediator
18. Dynamic kinetic resolution with enzyme and palladium combinations
19. Dynamic kinetic resolution of acyclic allylic acetates using lipase and palladium
20. Concurrent resolution and oxidation of an allylic acetate and its utilization in the diastereocontrolled synthesis of some cyclopentanoid monoterpenes
21. Oxidation with Bacillus stearothermophilus in heptane
22. R-(-)-mandelic acid production from racemic mandelic acids by Pseudomonas polycolor with asymmetric degrading activity
23. Reductions of 3-oxoesters by baker's yeast: Current status
24. Asymmetric synthesis of beta-hydroxy esters and alpha-alkyl-beta-hydroxy esters by recombinant Escherichia coil expressing enzymes from baker's yeast
25. Improving the stereoselectivity of baker's yeast reductions by genetic engineering
26. + specific formate dehydrogenase
27. Deracemization of racemic 1,2-diol by biocatalytic stereoinversion
28. Stereoinversion of optically active 3 pentyn-2-ol by Nocardia species
29. Production of (R)-3-pentyn-2-ol through stereoinversion of racemic 3-pentyn-2-ol by Nocardia fusca AKU 2123
30. NAD(+)-dependent (S)-specific secondary alcohol dehydrogenase involved in stereoinversion of 3-pentyn-2-ol catalyzed by Nocardia fusca AKU 2123
31. The biotransformation of manoyl oxide derivatives by Gibberella fujikuroi: The fungal epimerization of an alcohol group
32. Deracemization of racemic 4-pyridyl-1-ethanol by Catharanthus roseus cell cultures
33. Biocatalytic dediastereomerization of dibenzylbutanolides by plant cell cultures
34. Yeast-catalyzed asymmetric reduction of benzil and benzoin to hydrobenzoin
35. Preparation of optically active cyclohexanediols and (+)-alpha-hydroxycycloheptanone by an enzyme catalysed stereoinversion/oxidation process
36. Biocatalysis of deracemization in 1,2-diols
37. High-yield production of optically active 1,2-diols from the corresponding racemates by microbial stereoinversion
38. A study of the stereocontrolled reduction of aliphatic β-ketoesters by Geotrichum candidum
39. Dynamic kinetic resolution of allylic alcohols mediated by ruthenium- and lipase-based catalysts