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Volumn 10, Issue 1, 1999, Pages 107-117

Biocatalytic transformation of racemates into chiral building blocks in 100% chemical yield and 100% enantiomeric excess

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL DERIVATIVE; AMINE; EPOXIDE;

EID: 0033556602     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0957-4166(98)00490-X     Document Type: Article
Times cited : (201)

References (65)
  • 1
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    • September 28
    • (a) The enantiopure drug market has been estimated as US $18 billion worldwide. See: Stinson, S. C. Chem. Eng. News 1992, September 28, 46-78;
    • (1992) Chem. Eng. News , pp. 46-78
    • Stinson, S.C.1
  • 8
    • 28844436100 scopus 로고
    • (a) Horeau, A. Tetrahedron 1975, 31, 1307-1309;
    • (1975) Tetrahedron , vol.31 , pp. 1307-1309
    • Horeau, A.1
  • 12
    • 0345647810 scopus 로고    scopus 로고
    • note
    • For biocatalyzed reactions, data from database Faber, ∼9000 entries, July 1998.
  • 24
    • 0001322821 scopus 로고
    • For the mathematical treatment of dynamic kinetic resolutions see: Kitamura, M.; Tokunaga, M.; Noyori, R. J. Am. Chem. Soc. 1993, 115, 144-152; Kitamura, M.; Tokunaga, M.; Noyori, R. Tetrahedron 1993, 49, 1853-1860.
    • (1993) J. Am. Chem. Soc. , vol.115 , pp. 144-152
    • Kitamura, M.1    Tokunaga, M.2    Noyori, R.3
  • 25
    • 0027400239 scopus 로고
    • For the mathematical treatment of dynamic kinetic resolutions see: Kitamura, M.; Tokunaga, M.; Noyori, R. J. Am. Chem. Soc. 1993, 115, 144-152; Kitamura, M.; Tokunaga, M.; Noyori, R. Tetrahedron 1993, 49, 1853-1860.
    • (1993) Tetrahedron , vol.49 , pp. 1853-1860
    • Kitamura, M.1    Tokunaga, M.2    Noyori, R.3
  • 26
    • 0345647801 scopus 로고    scopus 로고
    • note
    • S.
  • 33
    • 0344353208 scopus 로고    scopus 로고
    • note
    • For small-scale reactions, Mitsunobu conditions may likewise be employed.
  • 45
    • 84949070047 scopus 로고
    • +-linked dehydrogenase and an (S)-specific NADPH-dependent reductase. Although no detailed data were given, the latter step was claimed to be irreversible: Hasegawa, J.; Ogura, M.; Tsuda, S.; Maemoto, S.; Kutsuki, H.; Ohashi, T. Agric. Biol. Chem. 1990, 54, 1819-1827. On the other hand, observations on the fungus Geotrichum candidum prove the requirement of molecular oxygen, which would suggest the involvement of an alcohol oxidase rather than an alcohol dehydrogenase: Azerad, R.; Buisson, D. In Microbial Reagents in Organic Synthesis; Servi, S. (Ed.), NATO ASI Series C, Kluwer: Dordrecht, 1992; vol. 381, pp. 421-440.
    • (1990) Agric. Biol. Chem. , vol.54 , pp. 1819-1827
    • Hasegawa, J.1    Ogura, M.2    Tsuda, S.3    Maemoto, S.4    Kutsuki, H.5    Ohashi, T.6
  • 46
    • 0005530024 scopus 로고
    • Servi, S. (Ed.), NATO ASI Series C, Kluwer: Dordrecht
    • +-linked dehydrogenase and an (S)-specific NADPH-dependent reductase. Although no detailed data were given, the latter step was claimed to be irreversible: Hasegawa, J.; Ogura, M.; Tsuda, S.; Maemoto, S.; Kutsuki, H.; Ohashi, T. Agric. Biol. Chem. 1990, 54, 1819-1827. On the other hand, observations on the fungus Geotrichum candidum prove the requirement of molecular oxygen, which would suggest the involvement of an alcohol oxidase rather than an alcohol dehydrogenase: Azerad, R.; Buisson, D. In Microbial Reagents in Organic Synthesis; Servi, S. (Ed.), NATO ASI Series C, Kluwer: Dordrecht, 1992; vol. 381, pp. 421-440.
    • (1992) Microbial Reagents in Organic Synthesis , vol.381 , pp. 421-440
    • Azerad, R.1    Buisson, D.2
  • 63
    • 0344785065 scopus 로고    scopus 로고
    • note
    • A free shareware program ('Cyclo') running under Windows is available via the Internet at http://www-orgc.tu-graz.ac.at or directly from the authors (Kroutil, W.; Faber, K. © 1998). A description of how to use the program is given in the help file which accompanies the program. A program version for Macintosh will be released soon.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.