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Volumn 21, Issue 11, 2002, Pages 2153-2164

Metathesis of electron-rich olefins: Structure and reactivity of electron-rich carbene complexes

Author keywords

[No Author keywords available]

Indexed keywords

METATHESIS;

EID: 0000559010     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om011037a     Document Type: Article
Times cited : (270)

References (67)
  • 37
    • 0001019095 scopus 로고
    • For some early-transition-metal Fischer-type carbenes that undergo metathesis, see: (a) Katz, T. J.; Acton, N. Tetrahedron Lett. 1976, 47, 4251-4254.
    • (1976) Tetrahedron Lett. , vol.47 , pp. 4251-4254
    • Katz, T.J.1    Acton, N.2
  • 42
    • 0034104085 scopus 로고    scopus 로고
    • (c) In addition, there has been one report that involves the use of a derviatized vinyl ether as a means to add an end cap to a metathesis polymer; see: Gordon, E. J.; Gestwicki, J. E.; Strong, L. E.; Kiessling, L. L. Chem. Biol. 2000, 7, 9-16.
    • (2000) Chem. Biol. , vol.7 , pp. 9-16
    • Gordon, E.J.1    Gestwicki, J.E.2    Strong, L.E.3    Kiessling, L.L.4
  • 64
    • 0038140229 scopus 로고    scopus 로고
    • note
    • The equilibrium exhibits an interesting thermochromic behavior which can be qualitatively assessed by visual inspection. Benzene solutions of 9 were purple at room temperature and gradually turned brown upon heating. Cooling the solutions back to room temperature returned the solution to a purple color, as expected.
  • 66
    • 0037802610 scopus 로고    scopus 로고
    • note
    • More concentrated conditions, addition of 0.01 M complex 8 to 0.22 M COD, led to 80% conversion at 65 °C in 10 h.
  • 67
    • 0038479134 scopus 로고    scopus 로고
    • note
    • Furthermore, More concentrated conditions, addition of 0.01 M complex 13 to 0.22 M COD, also led to complete conversion at room temperature in less than 1 h.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.