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Volumn 606, Issue 1, 2000, Pages 16-25

Olefin-metathesis reactions using vinylideneruthenium(II) complexes as catalyst precursors

Author keywords

Molecular weight control; Ring closing metathesis (RCM); Ring opening metathesis polymerization (ROMP); Ruthenium; Vinylidene complexes

Indexed keywords


EID: 0001999197     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(00)00094-2     Document Type: Article
Times cited : (69)

References (72)
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    • Sanford, M.S.1    Henling, L.M.2    Grubbs, R.H.3
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    • 0032567497 scopus 로고    scopus 로고
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    • Kirkland, T.A.1    Lynn, D.M.2    Grubbs, R.H.3
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    • 0030994105 scopus 로고    scopus 로고
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    • 33646142047 scopus 로고    scopus 로고
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    • 0000897673 scopus 로고    scopus 로고
    • For further studies of Grubbs group, see: (a) M. Scholl, S. Ding, C.W. Lee, R.H. Grubbs, Org. Lett. 1 (1999) 953. (b) D.M. Lynn, B. Mohr, R.H. Grubbs, J. Am. Chem. Soc. 120 (1998) 1627. (c) E.L. Dias, R.H. Grubbs, Organometallics 17 (1998) 2758. (d) M.S. Sanford, L.M. Henling, R.H. Grubbs, Organometallics 17 (1998) 5384. (e) T.A. Kirkland, D.M. Lynn, R.H. Grubbs, J. Org. Chem. 63 (1998) 9904. (f) E.L. Dias, S.B.-T. Nguyen, R.H. Grubbs, J. Am. Chem. Soc. 119 (1997) 3887. (g) T.E. Wilhelm, T.R. Belderrain, S.N. Brown, R.H. Grubbs, Organometallics 16 (1997) 3867. (h) T.R. Belderrain, R.H. Grubbs, Organometallics 16 (1997) 4001. (i) M. Week, P. Schwab, R.H. Grubbs, Macromolecules 29 (1996) 1789.
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    • Belderrain, T.R.1    Grubbs, R.H.2
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    • 0001377632 scopus 로고    scopus 로고
    • For further studies of Grubbs group, see: (a) M. Scholl, S. Ding, C.W. Lee, R.H. Grubbs, Org. Lett. 1 (1999) 953. (b) D.M. Lynn, B. Mohr, R.H. Grubbs, J. Am. Chem. Soc. 120 (1998) 1627. (c) E.L. Dias, R.H. Grubbs, Organometallics 17 (1998) 2758. (d) M.S. Sanford, L.M. Henling, R.H. Grubbs, Organometallics 17 (1998) 5384. (e) T.A. Kirkland, D.M. Lynn, R.H. Grubbs, J. Org. Chem. 63 (1998) 9904. (f) E.L. Dias, S.B.-T. Nguyen, R.H. Grubbs, J. Am. Chem. Soc. 119 (1997) 3887. (g) T.E. Wilhelm, T.R. Belderrain, S.N. Brown, R.H. Grubbs, Organometallics 16 (1997) 3867. (h) T.R. Belderrain, R.H. Grubbs, Organometallics 16 (1997) 4001. (i) M. Week, P. Schwab, R.H. Grubbs, Macromolecules 29 (1996) 1789.
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    • Week, M.1    Schwab, P.2    Grubbs, R.H.3
  • 26
    • 0033547941 scopus 로고    scopus 로고
    • For other single-component ruthenium catalysts, see: (a) I. del Río, G. van Koten, Tetrahedron Lett. 40 (1999) 1401. (b) A. Fürstner, L. Ackermann, Chem. Commun. (1999) 95. (c) M. Bartz, J. Küther, R. Seshadri, W. Tremel, Angew. Chem. Int. Ed. Engl. 37 (1998) 2466. (d) E. Lindner, S. Pautz, R. Fawzi, M. Steimann, Organometallics 17 (1998) 3006. (e) B. Moreno, S. Sabo-Etienne, F. Dahan, B. Chaudret, J. Organomet. Chem. 498 (1995) 139. (f) W.J. Feast, D.B. Harrison, Polym. Bull. 25 (1991) 343. (g) B.M. Novak, R.H. Grubbs, J. Am. Chem. Soc. 110 (1988) 7542.
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    • Del Río, I.1    Van Koten, G.2
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    • For other single-component ruthenium catalysts, see: (a) I. del Río, G. van Koten, Tetrahedron Lett. 40 (1999) 1401. (b) A. Fürstner, L. Ackermann, Chem. Commun. (1999) 95. (c) M. Bartz, J. Küther, R. Seshadri, W. Tremel, Angew. Chem. Int. Ed. Engl. 37 (1998) 2466. (d) E. Lindner, S. Pautz, R. Fawzi, M. Steimann, Organometallics 17 (1998) 3006. (e) B. Moreno, S. Sabo-Etienne, F. Dahan, B. Chaudret, J. Organomet. Chem. 498 (1995) 139. (f) W.J. Feast, D.B. Harrison, Polym. Bull. 25 (1991) 343. (g) B.M. Novak, R.H. Grubbs, J. Am. Chem. Soc. 110 (1988) 7542.
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    • Fürstner, A.1    Ackermann, L.2
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    • For other single-component ruthenium catalysts, see: (a) I. del Río, G. van Koten, Tetrahedron Lett. 40 (1999) 1401. (b) A. Fürstner, L. Ackermann, Chem. Commun. (1999) 95. (c) M. Bartz, J. Küther, R. Seshadri, W. Tremel, Angew. Chem. Int. Ed. Engl. 37 (1998) 2466. (d) E. Lindner, S. Pautz, R. Fawzi, M. Steimann, Organometallics 17 (1998) 3006. (e) B. Moreno, S. Sabo-Etienne, F. Dahan, B. Chaudret, J. Organomet. Chem. 498 (1995) 139. (f) W.J. Feast, D.B. Harrison, Polym. Bull. 25 (1991) 343. (g) B.M. Novak, R.H. Grubbs, J. Am. Chem. Soc. 110 (1988) 7542.
    • (1998) Angew. Chem. Int. Ed. Engl. , vol.37 , pp. 2466
    • Bartz, M.1    Küther, J.2    Seshadri, R.3    Tremel, W.4
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    • For other single-component ruthenium catalysts, see: (a) I. del Río, G. van Koten, Tetrahedron Lett. 40 (1999) 1401. (b) A. Fürstner, L. Ackermann, Chem. Commun. (1999) 95. (c) M. Bartz, J. Küther, R. Seshadri, W. Tremel, Angew. Chem. Int. Ed. Engl. 37 (1998) 2466. (d) E. Lindner, S. Pautz, R. Fawzi, M. Steimann, Organometallics 17 (1998) 3006. (e) B. Moreno, S. Sabo-Etienne, F. Dahan, B. Chaudret, J. Organomet. Chem. 498 (1995) 139. (f) W.J. Feast, D.B. Harrison, Polym. Bull. 25 (1991) 343. (g) B.M. Novak, R.H. Grubbs, J. Am. Chem. Soc. 110 (1988) 7542.
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    • For other single-component ruthenium catalysts, see: (a) I. del Río, G. van Koten, Tetrahedron Lett. 40 (1999) 1401. (b) A. Fürstner, L. Ackermann, Chem. Commun. (1999) 95. (c) M. Bartz, J. Küther, R. Seshadri, W. Tremel, Angew. Chem. Int. Ed. Engl. 37 (1998) 2466. (d) E. Lindner, S. Pautz, R. Fawzi, M. Steimann, Organometallics 17 (1998) 3006. (e) B. Moreno, S. Sabo-Etienne, F. Dahan, B. Chaudret, J. Organomet. Chem. 498 (1995) 139. (f) W.J. Feast, D.B. Harrison, Polym. Bull. 25 (1991) 343. (g) B.M. Novak, R.H. Grubbs, J. Am. Chem. Soc. 110 (1988) 7542.
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    • For further studies of ruthenium-based metathesis catalysts, see: (a) A. Demonceau, A.W. Stumpf, E. Saive, A.F. Noels, Macromolecules 30 (1997) 3127. (b) W.A. Herrmann, W.C. Schattenmann, O. Nuyken, S.C. Glander, Angew. Chem. Int. Ed. Engl. 35 (1996) 1087. (c) L. Porri, P. Diversi, A. Lucherini, R. Rossi, Makromol. Chem. 176 (1975) 3121. (d) K. Hiraki, A. Kuroiwa, H. Hirai, J. Polym. Sci. A-1 9 (1971) 2323. (e) F.W. Michelotti, W.P. Keaveney, J. Polym. Sci. A 3 (1965) 895.
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    • For alternative synthetic routes to alkylidene complexes, see Refs. [3g] and [3h]
    • For alternative synthetic routes to alkylidene complexes, see Refs. [3g] and [3h].
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    • Portions of this work have been communicated: (a) H. Katayama, F. Ozawa, Chem. Lett. (1998) 67. (b) H. Katayama, H. Urushima, F. Ozawa, Chem. Lett. (1999) 369.
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    • note
    • 2 with 1,2-propadiene, has been briefly mentioned by Grubbs et al.: Ref. [2a].
  • 46
    • 33845375542 scopus 로고
    • n is known to be approximately half of the GPC value based on polystyrene standards: (a) L.R. Gilliom, R.H. Grubbs, J. Am. Chem. Soc. 108 (1986) 733. (b) T.J. Katz, S.J. Lee, N. Acton, Tetrahedron Lett. (1976) 4247. (c) T.J. Katz, N. Acton, Tetrahedron Lett. (1976) 4251.
    • (1986) J. Am. Chem. Soc. , vol.108 , pp. 733
    • Gilliom, L.R.1    Grubbs, R.H.2
  • 47
    • 0000714675 scopus 로고
    • n is known to be approximately half of the GPC value based on polystyrene standards: (a) L.R. Gilliom, R.H. Grubbs, J. Am. Chem. Soc. 108 (1986) 733. (b) T.J. Katz, S.J. Lee, N. Acton, Tetrahedron Lett. (1976) 4247. (c) T.J. Katz, N. Acton, Tetrahedron Lett. (1976) 4251.
    • (1976) Tetrahedron Lett. , pp. 4247
    • Katz, T.J.1    Lee, S.J.2    Acton, N.3
  • 48
    • 0001019095 scopus 로고
    • n is known to be approximately half of the GPC value based on polystyrene standards: (a) L.R. Gilliom, R.H. Grubbs, J. Am. Chem. Soc. 108 (1986) 733. (b) T.J. Katz, S.J. Lee, N. Acton, Tetrahedron Lett. (1976) 4247. (c) T.J. Katz, N. Acton, Tetrahedron Lett. (1976) 4251.
    • (1976) Tetrahedron Lett. , pp. 4251
    • Katz, T.J.1    Acton, N.2
  • 49
    • 85037457100 scopus 로고    scopus 로고
    • note
    • n = 1.55-1.99, > 98%).
  • 55
    • 85037480773 scopus 로고    scopus 로고
    • note
    • The higher stability of Fischer-type ruthenium carbenes than alkylidenerutheniums has been documented [2a].
  • 63
    • 85037450663 scopus 로고    scopus 로고
    • note
    • 1H-NMR spectrum.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.