Synthesis of trisubstituted alkenes via olefin cross-metathesis

Organic Letters

Volumn 1, Issue 11, 1999, Pages 1751-1753

  Chatterjee, Arnab K ^a   Grubbs, Robert H ^a  

^a California Institute of Technology ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE; IMIDAZOLE DERIVATIVE; RUTHENIUM;

ARTICLE; CATALYSIS; CHEMISTRY; SYNTHESIS;

ALKENES; CATALYSIS; IMIDAZOLES; RUTHENIUM;

EID: 0033518063     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol991023p     Document Type: Article

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61. + 282.2559, found 282.2556.
62. In the reaction shown in Table 1. entry 1, the vinyldioxolane component (3 equiv) was added in four equal parts over a 6 h period. This maintained a low concentration of dioxolane homodimer and increased the isolated yield of cross-metathesis product by 10%.