Reaction between ruthenium(0) complexes and dihalo compounds. A new method for the synthesis of ruthenium olefin metathesis catalysts

Organometallics

Volumn 16, Issue 18, 1997, Pages 4001-4003

  Belderrain, Tomás R ^a   Grubbs, Robert H ^a  

^a California Institute of Technology ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000897673     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970514f     Document Type: Article

References (22)

1. (a) Grubbs, R. H.; Miller, S. J.; Fu, G. C. Acc. Chem. Res. 1995, 28, 446.
2. (b) Meng, D.; Su, D.-S.; Balog, A.; Bertinato, P.; Sorensen, E. J.; Danishefsky, S. J.; Zheng, Y.-H.; Chou, T.-C.; He, L.; Horwitz, S. B. J. Am. Chem. Soc. 1997,119, 2733.
3. (c) Snapper, M. L.; Tallarico, J. A.; Randall, M. L. J. Am. Chem. Soc. 1997,119, 1478.
4. (d) Miller, S. J.; Blackwell, H. E.; Grubbs, R. H. J. Am. Chem. Soc. 1996, 118, 9606.
5. (e) Hillmyer, M. A; Nguyen, S. T.; Grubbs, R. H. Macromolecules 1997, 30, 718.
6. (f) Maughon, B. R.; Grubbs, R. H. Macromolecules 1996, 29, 5765.
7. (a) Nguyen, S. T.; Johnson, L. K.; Grubbs, R. H.; Ziller, J. W. J. Am. Chem. Soc. 1992, 114, 3974.
8. (b) Nguyen, S. T.; Grubbs, R. H.; Ziller, J. W. J. Am. Chem. Soc. 1993, 115, 9858.
9. (a) Schwab, P.; France, M. B.; Miller, J. W.; Grubbs, R. H. Angew. Chem., Int. Ed. Engl. 1995, 34, 2039.
10. (b) Schwab, P.; Grubbs, R. H.; Ziller, J. W. J. Am. Chem. Soc. 1996, 118, 100.
11. Roper, W. R. J. Organomet. Chem. 1986, 300, 167.
12. This kind of process is well-known in the chemistry of Ru(0) compounds, see: (a) Seddon, E. A.; Seddon, K. R. The Chemistry of Ruthenium; Elsevier: Oxford, 1984. (b) Tsuji, Y.; Mukai, T.; Kondo, T.; Watanabe, Y. J. Organomet. Chem. 1989, 369, C51. (c) Minami, I.; Shimizu, I.; Tsuji, J. J. Organomet. Chem. 1985, 296, 269. (d) Komiya, S.; Kabashama, T.; Yamashita, K.; Hirano, M.; Fukuoka, A. J. Organomet. Chem. 1994, 471, C6.
13. This kind of process is well-known in the chemistry of Ru(0) compounds, see: (a) Seddon, E. A.; Seddon, K. R. The Chemistry of Ruthenium; Elsevier: Oxford, 1984. (b) Tsuji, Y.; Mukai, T.; Kondo, T.; Watanabe, Y. J. Organomet. Chem. 1989, 369, C51. (c) Minami, I.; Shimizu, I.; Tsuji, J. J. Organomet. Chem. 1985, 296, 269. (d) Komiya, S.; Kabashama, T.; Yamashita, K.; Hirano, M.; Fukuoka, A. J. Organomet. Chem. 1994, 471, C6.
14. This kind of process is well-known in the chemistry of Ru(0) compounds, see: (a) Seddon, E. A.; Seddon, K. R. The Chemistry of Ruthenium; Elsevier: Oxford, 1984. (b) Tsuji, Y.; Mukai, T.; Kondo, T.; Watanabe, Y. J. Organomet. Chem. 1989, 369, C51. (c) Minami, I.; Shimizu, I.; Tsuji, J. J. Organomet. Chem. 1985, 296, 269. (d) Komiya, S.; Kabashama, T.; Yamashita, K.; Hirano, M.; Fukuoka, A. J. Organomet. Chem. 1994, 471, C6.
15. This kind of process is well-known in the chemistry of Ru(0) compounds, see: (a) Seddon, E. A.; Seddon, K. R. The Chemistry of Ruthenium; Elsevier: Oxford, 1984. (b) Tsuji, Y.; Mukai, T.; Kondo, T.; Watanabe, Y. J. Organomet. Chem. 1989, 369, C51. (c) Minami, I.; Shimizu, I.; Tsuji, J. J. Organomet. Chem. 1985, 296, 269. (d) Komiya, S.; Kabashama, T.; Yamashita, K.; Hirano, M.; Fukuoka, A. J. Organomet. Chem. 1994, 471, C6.
16. Similar processes have been observed in studies developed recently in our group about the generation of carbenes by insertion of vinyl chloride into the Ru-H bond followed by α-chloro elimination, see: Wilhelm, T. E.; Brown, S. M.; Belderrain, T. R.; Grubbs, R. H. Organometallics 1997, 16, 3867.
17. (a) Itoh, K.; Nagashima, H.; Oshima, T.; Oshima, N.; Nishiyama, H. J. Organomet. Chem. 1984, 272, 179.
18. (b) Frosin, K. M.; Dahlenburg, L. Inorg. Chim. Acta 1990, 167, 83.
19. 3)] (B) see: (a) Christ, M. L.; Sabo-Etienne, S.; Chaudret, B. Organometallics 1995, 14, 1082. (b) Chaudret, B.; Devillers, J.; Poilblanc, R. Organometallics 1985, 4, 1722.
20. 3)] (B) see: (a) Christ, M. L.; Sabo-Etienne, S.; Chaudret, B. Organometallics 1995, 14, 1082. (b) Chaudret, B.; Devillers, J.; Poilblanc, R. Organometallics 1985, 4, 1722.
21. 2], 2, as s hydrogenation catalyst, see: Beatty, R. P.; Paciello, R. A. U.S. Pat. 5,555,778, 1996.
22. Borowski, A. F.; Sabo-Etienne, S,; Christ, M. L.; Donnadieu, B.; Chaudret, B. Organometallics 1996, 15, 1427.