Selective Silylative Reduction of Pyridines Leading to Structurally Diverse Azacyclic Compounds with the Formation of sp3 C-Si Bonds

Journal of the American Chemical Society

Volumn 137, Issue 48, 2015, Pages 15176-15184

  Gandhamsetty, Narasimhulu ^a,b   Park, Sehoon ^a,b   Chang, Sukbok ^a,b  

^a Institute for Basic Science   (South Korea)

^b Korea Advanced Institute of Science and Technology (KAIST)   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; HYDROSILYLATION; PYRIDINE;

AZACYCLIC COMPOUNDS; DOUBLE BONDS; ENAMINES; HIGH SELECTIVITY; MECHANISTIC STUDIES; NITROGEN ATOM; TRIS(PENTAFLUOROPHENYL) BORANE;

REDUCTION;

1,4 DIHYDROPYRIDINE; AZACYCLIC COMPOUND; CARBON; ENAMINE; NITROGEN; ORGANOSILICON DERIVATIVE; PYRIDINE; PYRIDINE DERIVATIVE; QUINOLINE DERIVATIVE; SILICONE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL BOND; COLUMN CHROMATOGRAPHY; HYDROSILYLATION; NUCLEAR MAGNETIC RESONANCE; REDUCTION; SUBSTITUTION REACTION;

EID: 84949604664     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b09209     Document Type: Article

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