Enantioselective Synthesis of Pyrrole-Based Spiro- and Polycyclic Derivatives by Iridium-Catalyzed Asymmetric Allylic Dearomatization and Controllable Migration Reactions

Angewandte Chemie - International Edition

Volumn 54, Issue 29, 2015, Pages 8475-8479

  Zhuo, Chun Xiang ^a   Cheng, Qiang ^a   Liu, Wen Bo ^a   Zhao, Qiang ^a   You, Shu Li ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

asymmetric catalysis; dearomatization; enantioselectivity; iridium; stereospecific migration

Indexed keywords

AROMATIC COMPOUNDS; AROMATIZATION; CATALYSIS; CHLORINE COMPOUNDS; IRIDIUM; IRIDIUM COMPOUNDS; POTASSIUM COMPOUNDS;

1 ,5-CYCLOOCTADIENE; ASYMMETRIC CATALYSIS; DEAROMATIZATION; DIASTEREO- AND ENANTIOSELECTIVITY; ENANTIOSELECTIVE SYNTHESIS; MIGRATION REACTION; PYRROLE DERIVATIVES; STEREOSPECIFIC;

ENANTIOSELECTIVITY;

1,5-CYCLOOCTADIENE; ALKADIENE; ALLYL COMPOUND; IRIDIUM; PYRROLE DERIVATIVE; SPIRO COMPOUND;

CATALYSIS; CHEMISTRY; STEREOISOMERISM;

ALKADIENES; ALLYL COMPOUNDS; CATALYSIS; IRIDIUM; PYRROLES; SPIRO COMPOUNDS; STEREOISOMERISM;

EID: 84947869605     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201502259     Document Type: Article

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